Preparation, Characterization, and Photocatalytic Properties of Pt/BiOCl Nanoplates

doi:10.3724/SP.J.1088.2012.20904

Abstract

Abstract: A series of novel Pt/BiOCl nanoplate photocatalysts were synthesized by a photodeposition method. The as-synthesized products were characterized by N₂physical adsorption, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, photoluminescence (PL) emission spectroscopy, and UV-Vis diffuse reflectance spectroscopy (DRS). The photocatalytic activity of the samples was evaluated by photocatalytic degradation of acid orange II under both UV light (λ = 254 nm) and visible light irradiation. The N₂ physical adsorption test showed that the deposition of Pt nanoparticles could not produce obvious change in the specific surface area of the catalyst. The UV-Vis DRS results indicated that the presence of Pt nanoparticles could effectively increase the visible light absorption ability of Pt/BiOCl. The PL spectra indicated that Pt could effectively suppress the recombination of photogenerated hole-electron pairs of Pt/BiOCl. Activity tests showed that the deposition of Pt (1%–2%, mass fraction) greatly promotes the UV right photocatalytic activity. Pt also brought about an obvious visible light activity, which could be attributed to the visible light absorption and plasmon photocatalysis role of deposited Pt nanoparticles.

Key words: platinum nanoparticle, bismuth oxychloride, photocatalysis, visible light, acid orange II

YU Chang-Lin, CHEN Jian-Chai, CAO Fang-Fang, LI Xin, FAN Qi-Zhe, YU Jimmy C, WEI Long-Fu. Preparation, Characterization, and Photocatalytic Properties of Pt/BiOCl Nanoplates[J]. Chinese Journal of Catalysis, 2013, 34(2): 385-390.

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References

1 向全军, 余家国. 催化学报 (Xiang Q J, Yu J G. Chin J Catal), 2011, 32: 525
2 许蕾蕾, 倪磊, 施伟东, 官建国. 催化学报 (Xu L L, Ni L, Shi W D, Guan J G. Chin J Catal), 2012, 33: 1011
3 余长林, 杨凯, 舒庆, Yu J C, 操芳芳, 李鑫. 催化学报 (Yu Ch L, Yang K, Shu Q, Yu J C, Cao F F, Li X. Chin J Catal), 2011, 32: 555
4 刘晓霞, 樊彩梅, 王韵芳, 王雅文, 张小超, 梁镇海. 中国科学: 化学 (Lui X X, Fan C M, Wang Y F, Wang Y W, Zhang X Ch, Liang Zh H. Sci Sin Chim), 2012, 42: 1145
5 Yu Ch L, Yang K, Shu Q, Yu J C, Cao F F, Li X, Zhou X C. Sci China: Chem, 2012, 55: 1807
6 Yu Ch L, Fan Q Zh, Xie Y, Chen J Ch, Shu Q, Yu J C. J Hazard Mater, 2012, 237-238: 38
7 张寅, 邵芸, 陈欢, 万海勤, 万玉秋, 郑寿荣. 环境科学 (Zhang Y, Shao Y, Chen H, Wan H Q, Wan Y Q, Zheng Sh R. Enviren Sci), 2012, 33: 88
8 陈淑海, 徐耀, 吕宝亮, 吴东. 物理化学学报 (Chen Sh H, Xu Y, Lü B L, Wu D. Acta Phys-Chim Sin), 2011, 27: 2933
9 Asiltürk M, Sayilkan F, Arpaç E. J Photochem Photobiol A, 2009, 203: 64
10 Yu J G, Yu J C, Cheng B, Zhao X J. J Sol-Gel Sci Technol, 2002, 24: 39
11 余长林, 杨凯, Yu J C, 操芳芳, 李鑫, 周晓春. 无机材料学报 (Yu Ch L, Yang K, Yu J C, Cao F F, Li X , Zhou X Ch. J Inorg Mater), 2011, 26: 1158
12 刘阳, 王晟, 王騊, 许章炼, 陈文兴, 蒋杰, 韦坚红. 催化学报 (Liu Y, Wang Sh, Wang T, Xu Zh L, Chen W X, Jiang J, Wei J H. Chin J Catal), 2010, 31: 485
13 Jiang J, Zhao K, Xiao X Y, Zhang L Zh. J Am Chem Soc, 2012, 134: 4473
14 Ai Z H, Ho W K, Lee S C. J Phys Chem C, 2011, 115: 25330
15 Zhang D Q, Wen M Ch, Jiang B, Li G Sh, Yu J C. J Hazard Mater, 2012, 211/212: 104
16 Yu Ch L, Zhou W Q, Yu J C, Cao F F, Li X. Chin J Chem, 2012, 30: 721
17 Yu Ch L, Fan C F, Yu J C, Zhou W Q, Yang K. Mater Res Bull, 2011, 46:140
18 Wang W D, Huang F Q, Lin X P, Yang J H. Catal Commun, 2008, 9: 8
19 Shenawi-Khalil S, Uvarov V, Kritsman Y, Menes E, Popov I, Sasson Y. Catal Commun, 2011, 12: 1136
20 Xia J X, Yin Sh, Li H M, Xu H, Yan Y Sh, Zhang Q. Langmuir, 2011, 27: 1200
21 Dong F, Sun Y J, Fu M, Wu Zh B, Lee S C. J Hazard Mater, 2012, 219/220: 26
22 Cao J, Xu B Y, Lin H L, Luo B D, Chen Sh F. Chem Engin J, 2012, 185/186: 91
23 Liu H, Cao W R, Su Y, Wang Y, Wang X H. Appl Catal B, 2012, 111/112: 271
24 Yu Ch L, Fan C F, Meng X J, Yang K, Cao F F, Li X. Reac Kinet, Mech Catal, 2011, 103: 141
25 余长林, 操芳芳, 舒庆, 包玉龙, 谢志鹏, 余济美, 杨凯. 物理化学学报 (Yu Ch L, Cao F F, Shu Q, Bao Y L, Xie Zh P, Yu J M, Yang K. Acta Phys-Chim Sin), 2012, 28: 647
26 Klare M, Scheen J, Vogelsang K, Jacobs H, Broekaert J A C. Chemosphere, 2000, 41: 353
27 Einaga H, Futamura S, Ibusuki T. Environ Sci Technol, 2001, 35: 1880
28 Sun B, Vorontsov A V, Smirniotis P G. Langmuir, 2003, 19: 3151
29 Teoh W Y, Mädler L, Amal R. J Catal, 2007, 251: 271
30 Fleisch T H, Zajac G W, Schreiner J O, Mains G J. Appl Surf Sci, 1986, 26: 488
31 Langhammer C, Yuan Zh, Zori? I, Kasemo B. Nano Lett, 2006, 6: 833
32 Xiong Y J, Chen J Y, Wiley B, Xia Y N, Yin Y D, Li Zh Y. Nano Lett, 2005, 5: 1237
33 Chen J Y, Wiley B, McLellan J, Xiong Y J, Li Zh Y, Xia Y N. Nano Lett, 2005, 5: 2058
34 Kim Y I, Atherton S J, Brigham E S, Mallouk T E. J Phys Chem, 1993, 97: 11802
35 Dai G P, Yu J G, Liu G. J Phys Chem C, 2011, 115: 7339
36 高濂, 郑珊, 张青红. 纳米氧化钛光催化材料及应用. 北京: 化学工业出版社 (Gao L, Zheng Sh, Zhang Q H. Nano TiO2 Photocatalytic Materials and Their Application. Beijing: Chem Ind Press), 2002. 110

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