Influence of the metal sites of M-N-C (M = Co, Fe, Mn) catalysts derived from metalloporphyrins in ethylbenzene oxidation

doi:10.1016/S1872-2067(15)61029-4

Abstract

Abstract:

Transition metal catalysts M-N-C (M = Co, Fe, Mn) were synthesized by a template-free method by heating meso-tetraphenyl porphyrins (i.e. CoTPP, FeTPPCl, MnTPPCl) precursors. The catalysts were characterized by N₂ adsorption-desorption, thermogravimetry, high-resolution transmission electron microscopy, and Raman and X-ray photoelectron spectroscopy. The selective oxidation of ethylbenzene with molecular oxygen under a solvent-free condition was carried out to explore the catalytic performance of the M-N-Cs, which exhibited different catalytic performance. That was ascribed to the difference in M (Co, Fe, Mn) and different graphitization degree forming during the heating process, in which M (Co, Fe, Mn) might have different catalytic activity on the formation of the M-N-C catalyst. All the M-N-C composites had remarkable recyclability in the selective oxidation of ethylbenzene.

Key words: M(cobalt, iron, manganese)-N-C, Transition metal, Nitrogen-doped carbon, Porphyrin, Ethylbenzene oxidation

Lingling Fu, Yijuan Lu, Zhigang Liu, Runliang Zhu. Influence of the metal sites of M-N-C (M = Co, Fe, Mn) catalysts derived from metalloporphyrins in ethylbenzene oxidation[J]. Chinese Journal of Catalysis, 2016, 37(3): 398-404.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61029-4

https://www.cjcatal.com/EN/Y2016/V37/I3/398

References

[1] K. A. Kuttiyiel, Y. M. Choi, S. M. Hwang, G. G. Park, T. H. Yang, D. Su, K. Sasaki, P. Liu, R. R. Adzic, Nano Energy, 2015, 13, 442-449.
[2] X. C. Wang, X. R. Liu, Y. Xu, G. M. Peng, Q. Cao, X. D. Mu, Chin. J. Catal., 2015, 36, 1614-1622.
[3] J. C. Zhang, J. X. Guo, W. Liu, S. P. Wang, A. R. Xie, X. F. Liu, J. Wang, Y. Z. Yang, Eur. J. Inorg. Chem., 2015, 2015, 969-976.
[4] C. Domínguez, F. J. Pérez-Alonso, M. Abdel Salam, J. L. G. de la Fuente, S. A. Al-Thabaiti, S. N. Basahel, M. A. Peña, J. L. G. Fierro, S. Rojas, Int. J. Hydrogen Energy, 2014, 39, 5309-5318.
[5] H. Y. Jin, J. Wang, D. F. Su, Z. F. Wei, Z. F. Pang, Y. Wang, J. Am. Chem. Soc., 2015, 137, 2688-2694.
[6] R. V. Jagadeesh, H. Junge, M. M. Pohl, J. Radnik, A. Brückner, M. Beller, J. Am. Chem. Soc., 2013, 135, 10776-10782.
[7] I. Matanovic, S. Babanova, A. Perry III, A. Serov, K. Artyushkovaa, P. Atanassov, Phys. Chem. Chem. Phys., 2015, 17, 13235-13244.
[8] J. Masa, W. Xia, I. Sinev, A. Q. Zhao, Z. Y. Sun, S. Grutzke, P. Weide, M. Muhler, W. Schuhmann, Angew. Chem. Int. Ed., 2014, 53, 8508-8512.
[9] R. Othman, A. L. Dicks, Z. H. Zhu, Int. J. Hydrogen Energy, 2012, 37, 357-372.
[10] D. F. Su, J. Wang, H. Y. Jin, Y. T. Gong, M. M. Li, Z. F. Pang, Y. Wang, J. Mater. Chem. A, 2015, 3, 11756-11761.
[11] I. Herrmann, U. I. Kramm, S. Fiechter, P. Bogdanoff, Electrochim. Acta, 2009, 54, 4275-4287.
[12] S. L. Gojkovic, S. Gupta, R. F. Savinell, Electrochim. Acta, 1999, 45, 889-897.
[13] Z. G. Liu, L. T. Ji, X. L. Dong, Z. Li, L. L. Fu, Q. A. Wang, RSC Adv., 2015, 5, 6259-6264.
[14] Z. G. Liu, L. T. Ji, J. Liu, L. L. Fu, S. F. Zhao, J. Mol. Catal. A, 2014, 395, 315-321.
[15] D. H. Shen, L. T. Ji, Z. G. Liu, W. B. Sheng, C. C. Guo, J. Mol. Catal. A, 2013, 379, 15-20.
[16] H. Jin, H. M. Zhang, H. X. Zhong, J. L. Zhang, Energy Environ. Sci., 2011, 4, 3389-3394.
[17] L. L. Fu, Y. Chen, Z. G. Liu, J. Mol. Catal. A, 2015, 408, 91-97.
[18] A. A. Costa, G. F. Ghesti, J. L. de Macedo, V. S. Braga, M. M. Santos, J. A. Dias, S. C. L. Dias, J. Mol. Catal. A, 2008, 282, 149-157.
[19] F. Yang, S. Y. Gao, C. R. Xiong, H. Q. Wang, J. Chen, Y. Kong, Chin. J. Catal., 2015, 36, 1035-1041.
[20] Y. J. Gao, G. Hu, J. Zhong, Z. J. Shi, Y. S. Zhu, D. S. Su, J. G. Wang, X. H. Bao, D. Ma, Angew. Chem. Int. Ed., 2013, 52, 2109-2113.
[21] Y. L. Li, J. J. Wang, X. F. Li, J. Liu, D. S. Geng, J. L. Yang, Electrochem. Commun., 2011, 13, 668-672.
[22] Y. H. Su, Y. H. Zhu, H. L. Jiang, J. H. Shen, X. L. Yang, W. J. Zou, J. D. Chen, C. Z. Li, Nanoscale, 2014, 6, 15080-15089.
[23] J. Wang, G. X. Wang, S. Miao, X. L. Jiang, J. Y. Li, X. H. Bao, Carbon, 2014, 75, 381-389.
[24] H. S. Oh, H. Kim, J. Power Sources, 2012, 212, 220-225.
[25] C. V. Schenck, J. G. Dillard, J. W. Murray, J. Colloid Interface Sci., 1983, 95, 398-409.
[26] E. Puello-Polo, J. L. Brito, J. Mol. Catal. A, 2008, 281, 85-92.
[27] Y. Chen, S. F. Zhao, Z. G. Liu, Phys. Chem. Chem. Phys., 2015, 17, 14012-14020.
[28] Y. Yao, B. Q. Zhang, J. Y. Shi, Q. H. Yang, ACS Appl. Mater. Interfaces, 2015, 7, 7413-7420.
[29] L. L. Geng, M. Zhang, W. X. Zhang, M. J. Jia, W. Yan, G. Liu, Catal. Sci. Technol., 2015, 5, 3097-3102.
[30] L. L. Geng, X. Y. Zhang, W. X. Zhang, M. J. Jia, G. Liu, Chem. Commun., 2014, 50, 2965-2967.
[31] S. Pylypenko, S. Mukherjee, T. S. Olson, P. Atanassov, Electrochim. Acta, 2008, 53, 7875-7883.