A novel dicobalt-substituted tungstoantimonate polyoxometalate:Synthesis, characterization, and photocatalytic water oxidation properties

doi:10.1016/S1872-2067(19)63358-9

Chinese Journal of Catalysis ›› 2019, Vol. 40 ›› Issue (6): 953-958.DOI: 10.1016/S1872-2067(19)63358-9

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A novel dicobalt-substituted tungstoantimonate polyoxometalate:Synthesis, characterization, and photocatalytic water oxidation properties

Qing Han^a, Di Sun^c, Junwei Zhao^d, Xiangming Liang^a, Yong Ding^a,b

a State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, Gansu, China;
b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China;
c Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China;
d Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China

Received:2019-01-23 Revised:2019-03-25 Online:2019-06-18 Published:2019-04-26
Contact: S1872-2067(19)63358-9
Supported by:
This research was financially supported by the National Natural Science Foundation of China (21773096), the Fundamental Research Funds for the Central Universities (lzujbky-2018-k08), and the Natural Science Foundation of Gansu Province (17JR5RA186).

Abstract

Abstract:

The one-pot assembly reaction of a trilacunary, lone-pair-containing[B-α-SbW₉O₃₃]^9- precursor with Co²⁺ ions in an aqueous medium led to the isolation of a novel {SbO₃(H₂O)₃} bridging, dicobalt-substituted, sandwich-type tungstoantimonate {Co₂Sb₂(H₂O)₁₀[B-β-SbW₉O₃₃]₂}^4- (1a). This compound was structurally characterized in the solid state by single-crystal X-ray diffraction, elemental analyses, thermogravimetric analysis, and IR spectroscopy. The most remarkable feature was that 1a comprises two trilacunary[B-β-SbW₉O₃₃]^9- fragments trapping a novel, centrally symmetric, rhomb-like {Co₂Sb₂} belt with 10 terminal water molecules. When combined with the photosensitizer [Ru(bpy)₃]²⁺ and the sacrificial electron acceptor S₂O₈^2-, 1a exhibited efficient catalytic activity for water oxidation with a remarkable turnover number (TON) of 193, initial turnover frequency (TOF_initial) of 5.3 s^-1, O₂ yield of 30.8%, and quantum yield (Ф_QY) of 36.2% under light-driven conditions.

Key words: Light-driven water oxidation, Tungstoantimonate, Self-assembly

Qing Han, Di Sun, Junwei Zhao, Xiangming Liang, Yong Ding. A novel dicobalt-substituted tungstoantimonate polyoxometalate:Synthesis, characterization, and photocatalytic water oxidation properties[J]. Chinese Journal of Catalysis, 2019, 40(6): 953-958.

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A novel dicobalt-substituted tungstoantimonate polyoxometalate:Synthesis, characterization, and photocatalytic water oxidation properties

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