Chinese Journal of Catalysis ›› 2026, Vol. 89: 102-126.DOI: 10.1016/S1872-2067(26)65142-X
• Review • Previous Articles Next Articles
Guangjian Liao, Wenbo Lv, Zhichao Wang, Zhuqi Chen, Guochuan Yin(
)
Received:2026-03-10
Accepted:2026-04-16
Online:2026-10-18
Published:2026-09-01
Contact:
*E-mail:gyin@hust.edu.cn(G. Yin).
About author:Dr. Guochuan Yin (School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology) received B.S. degree from Zhejiang University in 1990, and Ph.D. from Dalian Institute of Chemical Physics, Chinese Academy of Sciences in 1998. He joined Kyushu University in Japan as a JSPS follow in 1999, worked as a postdoc in University of Kansas, USA in 2001, and finally back to China in 2008 as a professor in Huazhong University of Science and Technology. His research covers homogeneous catalytic oxidations, C-H activation, biomass utilizations, and wastewater treatment, and most recently focuses on Lewis acid promoted catalysis by redox metal ions and complexes for homogeneous oxidation and C-H activation. He has published more than 120 peer-reviewed papers.
Supported by:Guangjian Liao, Wenbo Lv, Zhichao Wang, Zhuqi Chen, Guochuan Yin. Modulating the oxidative reactivity of the metal active oxygen moieties by Lewis acid for catalysis[J]. Chinese Journal of Catalysis, 2026, 89: 102-126.
Add to citation manager EndNote|Ris|BibTeX
URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(26)65142-X
| LA | t/min | Products (%) | ||
|---|---|---|---|---|
| cyclohexanone | cyclohexanol | cyclohexylchloride | ||
| -b | 240 | 60 | n.d. | n.d. |
| ZnCl2 | 5 | 65 | 3 | 3 |
| Zn(OAc)2 | 210 | 60 | n.d. | — |
| FeCl3 | 5 | 60 | 3.5 | 0.5 |
| AlCl3 | 2 | n.d. | n.d. | 3 |
| LiCl | 60 | 69 | n.d. | 2 |
| Li(OAc)2 | 240 | 64 | 6 | — |
| BF3·HOAc | 5 | 50 | n.d. | — |
| PPh4Cl | 480 | 65 | n.d. | 1.5 |
Table 1 The influence of LA on cyclohexane oxidation by BaRu(O)2(OH)3a.
| LA | t/min | Products (%) | ||
|---|---|---|---|---|
| cyclohexanone | cyclohexanol | cyclohexylchloride | ||
| -b | 240 | 60 | n.d. | n.d. |
| ZnCl2 | 5 | 65 | 3 | 3 |
| Zn(OAc)2 | 210 | 60 | n.d. | — |
| FeCl3 | 5 | 60 | 3.5 | 0.5 |
| AlCl3 | 2 | n.d. | n.d. | 3 |
| LiCl | 60 | 69 | n.d. | 2 |
| Li(OAc)2 | 240 | 64 | 6 | — |
| BF3·HOAc | 5 | 50 | n.d. | — |
| PPh4Cl | 480 | 65 | n.d. | 1.5 |
Fig. 1. Plot of logk vs. BDE of the C-H bond for BF3-promoted oxidation by MnO4- in CH3CN at 298 K. Reprinted with permission from Ref. [49]. Copyright 2006, American Chemical Society.
Fig. 2. The structure of the active form of MnO4-/HOAc/Ca2+ for oxidation. Reprinted with permission from Ref. [55]. Copyright 2022, Royal Society of Chemistry.
Fig. 3. The structure of MnV(O)(TAMAL) complex. Reprinted with permission from Ref. [63]. Copyright 1998, American Chemical Society.
Scheme 1. LA-accelerated electron transfer by the iron(IV) oxo complex. Reprinted with permission from Ref. [65]. Copyright 2011, American Chemical Society.
Fig. 4. Plots of log k1 (red circles) and log k2 (blue squares) vs. ?E for electron transfer from Fc to the [(N4Py)FeIV(O)]2+ complex. Reprinted with permission from Ref. [65]. Copyright 2011, American Chemical Society.
Scheme 2. LA-modulated mechanism shift for thioaniosole oxygenation (DOT: direct oxygen transfer, ETOT: electron transfer followed by oxygen transfer). Reprinted with permission from Ref. [68]. Copyright 2011, American Chemical Society.
Scheme 3. Mechanism shift by Sc3+-modulated 2,5-dimethoxybenzyl alcohol oxidation by the [(N4Py)FeIV(O)]2+ complex (ET: electron transfer, PT: proton transfer, HAT: hydrogen atom transfer). Reprinted with permission from Ref. [70]. Copyright 2012, American Chemical Society.
Scheme 4. LA-modulated mechanism shift for thioanisole oxidation by MnIV(O)(N4Py) complex (DOT: direct oxygen transfer, ET: electron transfer, OT: oxygen transfer). Reprinted with permission from Ref. [73]. Copyright 2013, American Chemical Society.
Fig. 5. pH dependent net charge and functional group of the MnIV(Me2EBC)(OH)22+ complex. Reprinted with permission from Ref. [77]. Copyright 2012, American Chemical Society.
| Temperature (K) | k23+ | k22+ | k23+/k22+ |
|---|---|---|---|
| 293 | (9.09 ± 0.07) × 10-4 | (8.68 ± 0.08) × 10-4 | 1.05 |
| 303 | (1.73 ± 0.08) × 10-3 | (1.52 ± 0.01) × 10-3 | 1.14 |
| 313 | (2.86 ± 0.09) × 10-3 | (2.90 ± 0.09) × 10-3 | 0.99 |
Table 2 The influence of the net charge on the hydrogen atom abstract rate of the MnIV-OH moiety.
| Temperature (K) | k23+ | k22+ | k23+/k22+ |
|---|---|---|---|
| 293 | (9.09 ± 0.07) × 10-4 | (8.68 ± 0.08) × 10-4 | 1.05 |
| 303 | (1.73 ± 0.08) × 10-3 | (1.52 ± 0.01) × 10-3 | 1.14 |
| 313 | (2.86 ± 0.09) × 10-3 | (2.90 ± 0.09) × 10-3 | 0.99 |
Fig. 6. Manganese(V) nitride complexes appended with a crown ether to contain LA, and their thermodynamic cycle to determine the BDFE of the N-H bond. Reprinted with permission from Ref. [80]. Copyright 2022, American Chemical Society.
| Complex | E1/2a (V vs. Fc) | pKab | N-H BDEc |
|---|---|---|---|
| MnV≡N(salen) | 0.43 | 8.0-9.4 | 73-75 |
| MnV≡N(salen)-Na+ | 0.59 | 6.2-8.0 | 75-77 |
| MnV≡N(salen)-K+ | 0.62 | 6.2-8.0 | 75-78 |
| MnV≡N(salen)-Ba2+ | 0.80 | 0.2-2.6 | 71-75 |
| MnV≡N(salen)-Sr2+ | 0.88 | 0.2-2.6 | 73-76 |
| MnV≡N(salen)-La3+ | 1.02 | < 0.2 | < 76 |
| MnV≡N(salen)-Eu3+ | 1.13 | < 0.2 | < 79 |
Table 3 The influence of the net charge on the redox potential, pKa, and the BDFE of the N-H bond.
| Complex | E1/2a (V vs. Fc) | pKab | N-H BDEc |
|---|---|---|---|
| MnV≡N(salen) | 0.43 | 8.0-9.4 | 73-75 |
| MnV≡N(salen)-Na+ | 0.59 | 6.2-8.0 | 75-77 |
| MnV≡N(salen)-K+ | 0.62 | 6.2-8.0 | 75-78 |
| MnV≡N(salen)-Ba2+ | 0.80 | 0.2-2.6 | 71-75 |
| MnV≡N(salen)-Sr2+ | 0.88 | 0.2-2.6 | 73-76 |
| MnV≡N(salen)-La3+ | 1.02 | < 0.2 | < 76 |
| MnV≡N(salen)-Eu3+ | 1.13 | < 0.2 | < 79 |
Fig. 7. LA-modulated oxygenation kinetics for PPh3 by Mn(Me2EBC)(OH)2 complex in acetone at 293 K. Reprinted with permission from Ref. [82]. Copyright 2013, American Chemical Society.
Scheme 5. Zn2+-induced valence tautomerization of the (TBP8Cz)MnV(O) complex. Reprinted with permission from Ref. [83]. Copyright 2012, American Chemical Society.
| Substrate | Lewis acid | k2 (L/(mol·s)) | k2LA/k2none |
|---|---|---|---|
| 2,4-DTPB | Zn2+ | 17 ± 1 | 5.9 |
| B(C6F5)3 | 107 ± 8 | 37 | |
| none | 2.9 ± 0.1 | — | |
| 2,4,6-TTBP | Zn2+ | 0.157 ± 0.008 | 2.1 |
| B(C6F5)3 | 9.5 ± 0.7 | 130 | |
| none | 0.074 ± 0.007 | — |
Table 4 Comparing the rate constants for oxidation of phenol substrates by the (TBP8Cz)MnV(O) complex.
| Substrate | Lewis acid | k2 (L/(mol·s)) | k2LA/k2none |
|---|---|---|---|
| 2,4-DTPB | Zn2+ | 17 ± 1 | 5.9 |
| B(C6F5)3 | 107 ± 8 | 37 | |
| none | 2.9 ± 0.1 | — | |
| 2,4,6-TTBP | Zn2+ | 0.157 ± 0.008 | 2.1 |
| B(C6F5)3 | 9.5 ± 0.7 | 130 | |
| none | 0.074 ± 0.007 | — |
Scheme 6. Proton or Zn2+-induced valence tautomerization of the (tpfc)MnV(O) complex. Reprinted with permission from Ref. [90]. Copyright 2016, John Wiley and Sons.
Scheme 7. Synthesis of Sc3+ ion-bound MnV(O)(TAML) complex. Reprinted with permission from Ref. [91]. Copyright 2016, American Chemical Society.
Scheme 8. Synthesis and reactivity of the {[(TAML+?)CrV(O)]-Sc3+}3+ complex. Reprinted with permission from Ref. [92]. Copyright 2021, American Chemical Society.
Scheme 9. Temperature dependent Co-OH(LA) TAML intermediate. Reprinted with permission from Ref. [94]. Copyright 2024, American Chemical Society.
Fig. 8. LA-bound MnV(O)(HMPAB) complex. Reprinted with permission from Ref. [96]. Copyright 2021, American Chemical Society.
Fig. 9. DFT optimized structure of the [(dpaq)MnIV(O)]+-Sc(OTf)3 complex. Reprinted with permission from Ref. [98]. Copyright 2019, American Chemical Society.
Fig. 10. Plot of logarithm of the second-order rate constants in oxygen atom transfer (red line), electron transfer (blue line) and hydrogen atom abstract (green line) vs. a quantitative measure of Lewis acidity of metal ions (ΔE). Reprinted with permission from Ref. [98]. Copyright 2019, American Chemical Society.
Fig. 11. Identified FeIV-O-CeIV unit in (MCP)FeII complex catalyzed water oxidation with CAN. Reprinted with permission from Ref. [100]. Copyright 2015, Springer Nature.
Scheme 10. Equilibrium between [LFeIV=O]2+ and [LFeIII-O-CeIV]2+ moieties trough [LFeIV=O···CeIII]2+ intermediate. Reprinted with permission from Ref. [101]. Copyright 2017, John Wiley and Sons.
Fig. 12. Structure of μ-O bridged (TPA)MnIV=O with CeIV complex. Reprinted with permission from Ref. [102]. Copyright 2024, American Chemical Society.
Fig. 13. Cyclic voltammograms of the CoII/I couples of Co(Salen-OMe) and Co(Salen)/LAs in 0.5 mol/L tetrabutylammonium hexafluorophosphate in DMF under N2. Reprinted with permission from Ref. [103]. Copyright 2017, American Chemical Society.
Scheme 11. Synthesis of LAs bound NiII(Salen) complexes with acyclic “tiera”. Reprinted with permission from Ref. [105]. Copyright 2024, American Chemical Society.
Fig. 14. Plot of the formal NiII/I couple of the LA bound NiII(Salen) complexes vs the pKa of the relevant NiII(Salen)(aqua) complexes. Reprinted with permission from Ref. [105]. Copyright 2024, American Chemical Society.
Fig. 15. The structures of the full manganese cubane and its Ca2+ incorporated cubane. Reprinted with permission from Ref. [106]. Copyright 2011, The American Association for the Advancement of Science.
Fig. 16. Cyclic voltammograms of [MnIV2MnIII2O4]6+ (solid trace, DMA solution) and [MnIV3CaO4]6+ (dashed trace, DMF solution) with 0.1 M nBu4NPF6. Reprinted with permission from Ref. [106]. Copyright 2011, The American Association for the Advancement of Science.
Fig. 17. Structure of LA incorporated Mn3LA(μ4-O)(μ2-O) core. Reprinted with permission from Ref. [109]. Copyright 2013, Springer Nature.
Fig. 18. The correlation of the redox potentials of the Mn3LA(μ4-O)(μ2-O) and Mn3LA(μ3-O)4 complexes with the Lewis acidity of LA, M(aqua)n+. Reprinted with permission from Ref. [108]. Copyright 2013, National Academy of Sciences.
Fig. 19. Exampled heterobimetallic complexes composed of VIV=O→FeIIPy5Me2 unit. Reprinted with permission from Ref. [112]. Copyright 2015, American Chemical Society.
Scheme 12. Proposed mechanism for LA-assisted dioxygen activation by iron(II) complex toward the iron(IV) oxo formation. Reprinted with permission from Ref. [117]. Copyright 2013, American Chemical Society.
Fig. 20. Structure of the LA bound [(TMC)FeIII(O2)]+ complexes. Reprinted with permission from Ref. [125]. Copyright 2016, John Wiley and Sons.
Fig. 21. Plots of logk2 values of electron transfer from BrFc, hydrogen atom abstract from 1,4-cyclohexadiene (CHD), deformylation from 2-PPA and CCA by the LA bound [(TMC)FeIII(O2)]+ complexes. Reprinted with permission from Ref. [125]. Copyright 2016, John Wiley and Sons.
Fig. 22. The structure of alkali metal ions side-on bound CuII2(μ-η1:η1-O2) complexes. Reprinted with permission from Ref. [128]. Copyright 2021, American Chemical Society.
Fig. 23. Ca2+ binding mediated interconversion of cis and trans-peroxo dicopper cores. Reprinted with permission from Ref. [129]. Copyright 2021, John Wiley and Sons.
Scheme 13. LA-modulated cleavage of the bis(μ-peroxo) bridge in the [(MeAN)2CuII2(O22-)]2+ toward LA bound dicopper(III) bis(μ-oxo) species. Reprinted with permission from Ref. [130]. Copyright 2017, American Chemical Society.
Fig. 24. DFT structure of the [Cu(iPr2-tren-C(CH3)2O2)]+ complex. Reprinted with permission from Ref. [131]. Copyright 2020, American Chemical Society.
Fig. 25. Plot of logk2 values of the deformylation reaction of the [Cu(iPr2-tren-C(CH3)2O2)]+ complex with CCA in the presence of LA. Reprinted with permission from Ref. [131]. Copyright 2020, American Chemical Society.
Scheme 14. LA modulated oxidative reactivity of the [CoIII(TBDAP)(O2)]+ complex. Reprinted with permission from Ref. [132]. Copyright 2021, American Chemical Society.
Fig. 26. Plot of logkobs vs the Lewis acidity of metal ions (ΔE) for the reaction of the [CoIII(TBDAP)(O2)]+ with acetonitrile. Reprinted with permission from Ref. [132]. Copyright 2021, American Chemical Society.
Fig. 27. Plot of logk2 vs Lewis acidity (ΔE) of the redox-inactive metal ions. Reprinted with permission from Ref. [137]. Copyright 2020, American Chemical Society.
Fig. 28. Proposed precursor complex prior to indole oxygenation by (TPP)iron(III) superoxo complex. Reprinted with permission from Ref. [138]. Copyright 2024, John Wiley and Sons.
Fig. 29. LA-accelerated sulfide oxygenation by Mn(Me2EBC)Cl2 with PhIO. Reprinted with permission from Ref. [82]. Copyright 2013, American Chemical Society.
| LA | Conv. (%) | Epoxide (%) |
|---|---|---|
| — | 7.6 | 6.4 |
| Na+ | 9.9 | 6.0 |
| Mg2+ | 92.6 | 80.5 |
| Ca2+ | 93.5 | 77.4 |
| Yb3+ | 100 | 67.1 |
| Al3+ | 100 | 79.7 |
| Sc3+ | 100 | 94.4 |
Table 5 LA-modulated cyclooctene epoxidation by Mn(BPMEN)Cl2 catalyst with PhI(OAc)2.
| LA | Conv. (%) | Epoxide (%) |
|---|---|---|
| — | 7.6 | 6.4 |
| Na+ | 9.9 | 6.0 |
| Mg2+ | 92.6 | 80.5 |
| Ca2+ | 93.5 | 77.4 |
| Yb3+ | 100 | 67.1 |
| Al3+ | 100 | 79.7 |
| Sc3+ | 100 | 94.4 |
| Additives | Con. (%) | Epoxide (%) | |
|---|---|---|---|
| none | 9.9 | 4.1 | |
| BA | HOAc | 23.7 | 5.9 |
| HCl | 28.1 | 10.5 | |
| HClO4 | 59.0 | 36.3 | |
| HOTf | 61.9 | 40.3 | |
| LA | NaOTf | 33.3 | 24.7 |
| Mg(OTf)2 | 46.2 | 41.8 | |
| Zn(OTf)2 | 66.6 | 63.3 | |
| Y(OTf)3 | 98.8 | 84.4 | |
| Yb(OTf)3 | 90.1 | 81.2 | |
| Al(OTf)3 | 97.8 | 91.4 | |
| LA with H2O | Al(OTf)3 + H2O (10 μL) | 87.0 | 76.1 |
| Al(OTf)3 + H2O (20 μL) | 53.9 | 44.6 | |
| Al(OTf)3 + H2O (40 μL) | 29.6 | 18.0 | |
Table 6 LA and BA-modulated olefin oxygenation by Mn(TPA)Cl2 complex with PhI(OAc)2.
| Additives | Con. (%) | Epoxide (%) | |
|---|---|---|---|
| none | 9.9 | 4.1 | |
| BA | HOAc | 23.7 | 5.9 |
| HCl | 28.1 | 10.5 | |
| HClO4 | 59.0 | 36.3 | |
| HOTf | 61.9 | 40.3 | |
| LA | NaOTf | 33.3 | 24.7 |
| Mg(OTf)2 | 46.2 | 41.8 | |
| Zn(OTf)2 | 66.6 | 63.3 | |
| Y(OTf)3 | 98.8 | 84.4 | |
| Yb(OTf)3 | 90.1 | 81.2 | |
| Al(OTf)3 | 97.8 | 91.4 | |
| LA with H2O | Al(OTf)3 + H2O (10 μL) | 87.0 | 76.1 |
| Al(OTf)3 + H2O (20 μL) | 53.9 | 44.6 | |
| Al(OTf)3 + H2O (40 μL) | 29.6 | 18.0 | |
| LA | Conv. (%) | Epoxide (%) |
|---|---|---|
| none | 38.0 | 20.2 |
| NaOTf | 49.7 | 21.2 |
| Mg(OTf)2 | 44.1 | 24.1 |
| Ca(OTf)2 | 45.3 | 31.1 |
| Zn(OTf)2 | 70.1 | 42.3 |
| Ba(OTf)2 | 47.2 | 20.2 |
| Y(OTf)3 | 63.1 | 33.1 |
| Yb(OTf)3 | 64.5 | 36.0 |
| Al(OTf)3 | 97.5 | 62.4 |
| Sc(OTf)3 | 99.9 | 64.3 |
| HOTf a | 58.5 | 31.6 |
Table 7 LA-modulated catalytic epoxidation of cyclooctene by Fe(BPMEN)(OTf)2 with aqueous H2O2.
| LA | Conv. (%) | Epoxide (%) |
|---|---|---|
| none | 38.0 | 20.2 |
| NaOTf | 49.7 | 21.2 |
| Mg(OTf)2 | 44.1 | 24.1 |
| Ca(OTf)2 | 45.3 | 31.1 |
| Zn(OTf)2 | 70.1 | 42.3 |
| Ba(OTf)2 | 47.2 | 20.2 |
| Y(OTf)3 | 63.1 | 33.1 |
| Yb(OTf)3 | 64.5 | 36.0 |
| Al(OTf)3 | 97.5 | 62.4 |
| Sc(OTf)3 | 99.9 | 64.3 |
| HOTf a | 58.5 | 31.6 |
Scheme 15. The activation barriers of the potential active oxygen intermediates in Fe(BPMEN)(OTf)2-catalzyed cyclooctene epoxidation in the absence/presence of Sc(OTf)3 with aqueous H2O2. Reprinted with permission from Ref. [150]. Copyright 2017, American Chemical Society.
Fig. 30. The structure of the MnIII(μ-OH)Ca2+ generated through dioxygen oxidation of the [MnIIMST]- complex in the presence of Ca(OTf)2/15-crown-5. Reprinted with permission from Ref. [157]. Copyright 2011, American Chemical Society.
Fig. 31. Initial kinetics of the reaction of [MnIIMST]- complex with dioxygen alone ((black, ?) in the presence of Ca(OTf)2/15-crown-5 (black, ?) or Ba(OTf)2/18-crown-6 (gray, ?) in CH2Cl2 at room temperature. Reprinted with permission from Ref. [157]. Copyright 2011, American Chemical Society.
| LA | Time (h) | Con. (%) | Benzene (%) |
|---|---|---|---|
| None | 24 | 30.3 | 10.4 |
| NaOTf | 24 | 32.2 | 14.5 |
| Mg(OTf)2 | 24 | 62.2 | 44.8 |
| Ca(OTf)2 | 24 | 70.1 | 52 |
| Ba(OTf)2 | 16 | 71.3 | 59.2 |
| Zn(OTf)2 | 16 | 99.2 | 85.3 |
| Y(OTf)3 | 8 | 99.5 | 82.3 |
| Al(OTf)3 | 8 | 99.6 | 83.3 |
| Sc(OTf)3 | 8 | 99.4 | 85.3 |
Table 8 LA-promoted dioxygen activation by the [VIV(O)Cl(TPA)]PF6 complex toward catalytic hydrogen abstraction from 1,4-cyclohexadiene.
| LA | Time (h) | Con. (%) | Benzene (%) |
|---|---|---|---|
| None | 24 | 30.3 | 10.4 |
| NaOTf | 24 | 32.2 | 14.5 |
| Mg(OTf)2 | 24 | 62.2 | 44.8 |
| Ca(OTf)2 | 24 | 70.1 | 52 |
| Ba(OTf)2 | 16 | 71.3 | 59.2 |
| Zn(OTf)2 | 16 | 99.2 | 85.3 |
| Y(OTf)3 | 8 | 99.5 | 82.3 |
| Al(OTf)3 | 8 | 99.6 | 83.3 |
| Sc(OTf)3 | 8 | 99.4 | 85.3 |
Scheme 16. Proposed mechanism for LA-promoted dioxygen activation and catalytic hydrogen abstraction by the [VIV(O)Cl(TPA)]PF6 complex. Reprinted with permission from Ref. [159]. Copyright 2017, American Chemical Society.
| LA | Conv. (%) | Aldehyde (%) | Epoxide (%) |
|---|---|---|---|
| none | 63 | 6 | 50 |
| NaOTf | 63 | 7 | 51 |
| Ca(OTf)2 | 62 | 7 | 50 |
| Mg(OTf)2 | 65 | 6 | 52 |
| Ba(OTf)2 | 61 | 6 | 51 |
| Y(OTf)3 | 40 | 5 | 30 |
| Al(OTf)3 | 89 | 9 | 77 |
| Sc(OTf)3 | 81 | 8 | 70 |
Table 9 LA-modulated dioxygen activation and catalysis by FeII(4-Me-BPMEN)(OTf)2 complex toward β-methyl-styrene epoxidation.
| LA | Conv. (%) | Aldehyde (%) | Epoxide (%) |
|---|---|---|---|
| none | 63 | 6 | 50 |
| NaOTf | 63 | 7 | 51 |
| Ca(OTf)2 | 62 | 7 | 50 |
| Mg(OTf)2 | 65 | 6 | 52 |
| Ba(OTf)2 | 61 | 6 | 51 |
| Y(OTf)3 | 40 | 5 | 30 |
| Al(OTf)3 | 89 | 9 | 77 |
| Sc(OTf)3 | 81 | 8 | 70 |
Fig. 32. LA-modulated amphoterically catalytic activity of Fe(4-Me-BPMEN)(OTf)2 in olefin oxygenation and 2-PPA deformylation. Reprinted with permission from Ref. [161]. Copyright 2026, Elsevier.
Fig. 33. Hammett plot for relative reactivities of styrene to para-substituted styrene catalyzed by Fe(BPMEN)(OTf)2 in the presence of different LAs. Reprinted with permission from Ref. [160]. Copyright 2022, Royal Society of Chemistry.
Scheme 17. Proposed mechanism for LA-improved olefin oxygenation by iron(II) complex through dioxygen activation. Reprinted with permission from Ref. [161]. Copyright 2026, Elsevier.
|
| [1] | Yue Zeng, Hongsheng Wang, Jing Xuan, Ping Xiao, Yaoyao Feng, Shuai Lyu, Junjiang Zhu. Size-dependent interfacial interactions in CeO2/Co3O4 catalysts: From single atoms to nanoparticles [J]. Chinese Journal of Catalysis, 2026, 88(9): 478-491. |
| [2] | Yaowen Wei, Jianwei Wang, Hao Guo, Tao Ban, Yufeng Yue, Di Hu, Haibao Huang. Highly selective oxidation of methane to acetic acid enabled by deficient UiO-66 under mild conditions [J]. Chinese Journal of Catalysis, 2026, 88(9): 356-368. |
| [3] | Dongpo Li, Qianqian Mao, Chao Xiong, Luying Xi, Yu Nie, Xiaotian Xu, Hongbing Ji. Constructing Ru-porphyrin COF for catalyzing air oxidation of adamantane C-H bonds to relay olefin epoxidation [J]. Chinese Journal of Catalysis, 2026, 88(9): 442-456. |
| [4] | Jiayu Zhang, Kun Wang, Jinglu Yu, Kaiyang Xu, Lu Yang, Jiali Rao, Shuqin Song, Yi Wang. Modulating active sites via Mn-doping in NiCo LDH for energy-saving paired electrosynthesis of H2O2 and formate [J]. Chinese Journal of Catalysis, 2026, 88(9): 307-321. |
| [5] | Yingzhen Zhang, Wei Zhang, Zhangzheng Huang, Weilong Cai, Yun Hau Ng, Jianying Huang, Yuekun Lai. Mn-triggered dynamic phase transition in NiSe2 catalyst via doping engineering for boosted urea electrolysis [J]. Chinese Journal of Catalysis, 2026, 88(9): 335-346. |
| [6] | Xinyi Zhang, Weichen Dong, Yi Cao, Caixia Zhou, Jiaxiu Guo, Hailong Zhang. Efficient continuous synthesis of methanol by direct methane conversion on Cu-KFI zeolite catalysts [J]. Chinese Journal of Catalysis, 2026, 88(9): 369-381. |
| [7] | Songling Wang, Anhua Huang, Fengxing Yin, Ruixiang Lu, Wengang Liu, Yun Zhang, Botao Qiao. In-situ synthesis of hydrogen peroxide for highly selective oxidation of methane to methanol over noble-metal-free catalyst [J]. Chinese Journal of Catalysis, 2026, 88(9): 347-355. |
| [8] | Xin Yuan, Linyi Wu, Fengying Cao, Lechu Xu, Peng Wang, Hulin Shi, Shuxian Zhong, Lian Liu, Weihao Mo, Leihong Zhao, Song Bai. Light-switchable product selectivity in CO2 photoreduction over hollow plasmonic TiO2/AuCu@COF core-shell architectures [J]. Chinese Journal of Catalysis, 2026, 87(8): 87-99. |
| [9] | Jianglin Duan, Pengcheng Deng, Huifeng Xiong, Na Yang, Xueling Zhou, Jingwen Wang, Rui Zhang, Dan Feng, Ji Yang, Yong Qin, Yujing Ren. Subangstrom spatial regulation of Fe1-N4 coordination structure for remarkably efficient C‒H bond oxidation [J]. Chinese Journal of Catalysis, 2026, 87(8): 305-315. |
| [10] | Wei Zuo, Mingyu Liu, Shengjun Sun, Yu Yang, Zixiao Li, Xixi Zhang, Chaoxin Yang, Hefeng Wang, Imran Shakir, Xuefei Liu, Qian Liu, Xuping Sun, Bo Tang. Synergistic chloride resistance via hydrogen‒bond network dynamic optimization and electrostatic repulsion for alkaline seawater oxidation [J]. Chinese Journal of Catalysis, 2026, 87(8): 295-304. |
| [11] | Keke Zhang, Fulin Zhang, Yuexin Wang, Fengwei Huang, Kanghui Xiong, Xiang-Kui Gu, Xianjun Lang. Tweaking the electron push-pull effect of vinylene-linked thienothiophene covalent organic frameworks for enhanced selective photocatalysis [J]. Chinese Journal of Catalysis, 2026, 87(8): 206-216. |
| [12] | Zi-Hang Wang, Wei Zhong, Si-Qi Li, Bin Sun, Hao Lan, Xiao-Yu Zhang, Xin Wang, Yu Chen, Xuan Ai. The C-C bond cleavage inhibition and intermediates adsorption enhancement co-boost the selective electrooxidation of ethylene glycol on silver-palladium hollow nanocubes [J]. Chinese Journal of Catalysis, 2026, 86(7): 191-200. |
| [13] | Qingxi Zhai, Yiqi Tian, Hao Wang, Shisi Tang, Qiang Yuan, Xu Liu, Weiping Ding, Fan Tian, Yan Zhu. Molecular adaptability and reactivity in Ni6(SR)12-catalyzed adipic acid synthesis [J]. Chinese Journal of Catalysis, 2026, 86(7): 225-235. |
| [14] | Chenyu Bu, Zhuoran Lu, Zhongcheng Xia, Yun Fan, Cairong Wang, Yutong Huang, Shuangyin Wang, Yuqin Zou. Interfacial two-site synergy for biomass electro-oxidation in a near-neutral electrolyte [J]. Chinese Journal of Catalysis, 2026, 86(7): 160-170. |
| [15] | Chao Wang, Kun Feng, Liangshuyu Tang, Wujun Zhang, Muyu Zhou, Jialu Li, Tianyu Shao, Flemming Besenbacher, Yanbin Shen, Jun Zhong, Ren Su. In-situ developed active sites of MOFs in aqueous electrocatalytic ammoxidation [J]. Chinese Journal of Catalysis, 2026, 86(7): 171-180. |
| Viewed | ||||||
|
Full text |
|
|||||
|
Abstract |
|
|||||
