Abstract: This review presents the research progress of heterogeneous chiral catalysis on surface, in nanopores, and with emulsion and mainly focuses on the recent res ul ts on chiral hydrogenation, transfer hydrogenation, hydroformylation, epoxidatio n, hydrolytic kinetics resolution, Aldol reaction, Diels-Alder reaction, enzyme catalytic reaction, etc., in this laboratory.

Key words: heterogeneous chiral catalysis, asymmetric catalysis, surface, nanopore, chiral emulsion, assembly, confinement, cooperative activation effect