Theoretical and Experimental Study on the Partial Hydrogenation of Benzene over Ru-Zn/ZrO2 Catalyst

Abstract

Abstract: Partial hydrogenation of benzene over Ru-Zn/ZrO2 catalyst was investigated. Both the theoretical calculation and experimental study showed that the presence of Zn atoms on the catalyst surface is unfavorable to the chemisorption of cyclohexene, which is considered to be crucial to the improvement of cyclohexene yield. The optimal Zn content in the catalyst was also confirmed.

Key words: Ru-Zn alloy, zirconia, density functional theory, benzene, partial hydrogenation, cyclohexene

HE Huimin;YUAN Peiqing*;MA Yueming;CHENG Zhenmin;YUAN Weikang. Theoretical and Experimental Study on the Partial Hydrogenation of Benzene over Ru-Zn/ZrO2 Catalyst[J]. Chinese Journal of Catalysis, 2009, 30(4): 312-318.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/

https://www.cjcatal.com/EN/Y2009/V30/I4/312

[1]	Jin-Nian Hu, Ling-Chan Tian, Haiyan Wang, Yang Meng, Jin-Xia Liang, Chun Zhu, Jun Li. Theoretical screening of single-atom electrocatalysts of MXene-supported 3d-metals for efficient nitrogen reduction [J]. Chinese Journal of Catalysis, 2023, 52(9): 252-262.
[2]	Lu Cheng, Xuning Chen, P. Hu, Xiao-Ming Cao. Advantages and limitations of hydrogen peroxide for direct oxidation of methane to methanol at mono-copper active sites in Cu-exchanged zeolites [J]. Chinese Journal of Catalysis, 2023, 51(8): 135-144.
[3]	Zhaochun Liu, Xue Zong, Dionisios G. Vlachos, Ivo A. W. Filot, Emiel J. M. Hensen. A computational study of electrochemical CO₂ reduction to formic acid on metal-doped SnO₂ [J]. Chinese Journal of Catalysis, 2023, 50(7): 249-259.
[4]	Shipeng Geng, Liming Chen, Haixin Chen, Yi Wang, Zhao-Bin Ding, Dandan Cai, Shuqin Song. Revealing the electrocatalytic mechanism of layered crystalline CoMoO₄ for water splitting: A theoretical study from facet selecting to active site engineering [J]. Chinese Journal of Catalysis, 2023, 50(7): 334-342.
[5]	Mengistu Tulu Gonfa, Sheng Shen, Lang Chen, Biao Hu, Wei Zhou, Zhang-Jun Bai, Chak-Tong Au, Shuang-Feng Yin. Research progress on the heterogeneous photocatalytic selective oxidation of benzene to phenol [J]. Chinese Journal of Catalysis, 2023, 49(6): 16-41.
[6]	Zheng-Qing Huang, Shu-Yue He, Tao Ban, Xin Gao, Yun-Hua Xu, Chun-Ran Chang. Mechanistic and microkinetic study of nonoxidative coupling of methane on Pt-Cu alloy catalysts: From single-atom sites to single-cluster sites [J]. Chinese Journal of Catalysis, 2023, 48(5): 90-100.
[7]	Huijuan Jing, Jun Long, Huan Li, Xiaoyan Fu, Jianping Xiao. Computational insights on potential dependence of electrocatalytic synthesis of ammonia from nitrate [J]. Chinese Journal of Catalysis, 2023, 48(5): 205-213.
[8]	Zhiyue Zhao, Zhiwei Jiang, Yizhe Huang, Mebrouka Boubeche, Valentina G. Matveeva, Hector F. Garces, Huixia Luo, Kai Yan. Facile synthesis of CoSi alloy catalysts with rich vacancies for base- and solvent-free aerobic oxidation of aromatic alcohols [J]. Chinese Journal of Catalysis, 2023, 48(5): 175-184.
[9]	Sue-Faye Ng, Xingzhu Chen, Joel Jie Foo, Mo Xiong, Wee-Jun Ong. 2D carbon nitrides: Regulating non-metal boron-doped C₃N₅ for elucidating the mechanism of wide pH range photocatalytic hydrogen evolution reaction [J]. Chinese Journal of Catalysis, 2023, 47(4): 150-160.
[10]	Chengcheng Chen, Fangting Liu, Qiaoyu Zhang, Zhengguo Zhang, Qiong Liu, Xiaoming Fang. Theoretical design and experimental study of pyridine-incorporated polymeric carbon nitride with an optimal structure for boosting photocatalytic CO₂ reduction [J]. Chinese Journal of Catalysis, 2023, 46(3): 91-102.
[11]	Hua Liu, Leilei Kang, Hua Wang, Qike Jiang, Xiao Yan Liu, Aiqin Wang. Ru single-atom catalyst anchored on sulfated zirconia for direct methane conversion to methanol [J]. Chinese Journal of Catalysis, 2023, 46(3): 64-71.
[12]	Tingting Jiang, Weiwei Xie, Shipeng Geng, Ruchun Li, Shuqin Song, Yi Wang. Constructing oxygen vacancy-regulated cobalt molybdate nanoflakes for efficient oxygen evolution reaction catalysis [J]. Chinese Journal of Catalysis, 2022, 43(9): 2434-2442.
[13]	Xiangyu Meng, Rui Li, Junyi Yang, Shiming Xu, Chenchen Zhang, Kejia You, Baochun Ma, Hongxia Guan, Yong Ding. Hexanuclear ring cobalt complex for photochemical CO₂ to CO conversion [J]. Chinese Journal of Catalysis, 2022, 43(9): 2414-2424.
[14]	Nan Li, Chuanyi Wang, Ke Zhang, Haiqin Lv, Mingzhe Yuan, Detlef W. Bahnemann. Progress and prospects of photocatalytic conversion of low-concentration NO_x [J]. Chinese Journal of Catalysis, 2022, 43(9): 2363-2387.
[15]	Yijing Gao, Shijie Zhang, Xiang Sun, Wei Zhao, Han Zhuo, Guilin Zhuang, Shibin Wang, Zihao Yao, Shengwei Deng, Xing Zhong, Zhongzhe Wei, Jian-guo Wang. Computational screening of O-functional MXenes for electrocatalytic ammonia synthesis [J]. Chinese Journal of Catalysis, 2022, 43(7): 1860-1869.

Theoretical and Experimental Study on the Partial Hydrogenation of Benzene over Ru-Zn/ZrO2 Catalyst

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics