Synthesis of a New Biphophorus Ligand and Its Application in Hydroformylation of 2-Butene

doi:10.3724/SP.J.1088.2010.00833

Chinese Journal of Catalysis ›› 2011, Vol. 32 ›› Issue (2): 299-302.DOI: 10.3724/SP.J.1088.2010.00833

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Synthesis of a New Biphophorus Ligand and Its Application in Hydroformylation of 2-Butene

ZHANG Lin, LI Chun, FU Haiyan, YUAN Maolin, LI Ruixiang, CHEN Hua*

Key Laboratory of Green Chemistry and Technology of Ministry of Education, Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, Sichuan, China

Received:2010-08-30 Revised:2010-10-14 Online:2011-01-26 Published:2014-06-25

Abstract

Abstract: A new biphosphorus ligand has been developed and applied in the rhodium-catalyzed regioselective hydroformylation of 2-butene. The effects of ligand/Rh ratio, reaction temperature, reaction pressure, and substrate/catalyst molar ratio were investigated. High activity and regioselectivity were achieved. The n-aldehyde/iso-aldehyde ratio of about 28.5 was obtained at 60 °C, and the TOF increased to 660 h^-¹ at the pressure of 2.0 MPa.

Key words: hydroformylation, 2-butene, biphosphorus ligand, rhodium, indole

ZHANG Lin, LI Chun, FU Haiyan, YUAN Maolin, LI Ruixiang, CHEN Hua*. Synthesis of a New Biphophorus Ligand and Its Application in Hydroformylation of 2-Butene[J]. Chinese Journal of Catalysis, 2011, 32(2): 299-302.

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Synthesis of a New Biphophorus Ligand and Its Application in Hydroformylation of 2-Butene

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