Highly efficient Rh(I)/tris-H8-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes

doi:10.1016/S1872-2067(18)63098-0

Abstract

Abstract:

Novel catalytic systems for the Rh-catalyzed hydroformylation of dicyclopentadiene have been developed using tris-H₈-binaphthyl monophosphite as ligands containing different ester substituents at the 2'-binaphthyl position (OCOMe, OCOPh, OCOAdamantyl and OCOPhCl). The catalysts exhibited high activity (S/C=4000, TON=3286) with good to excellent selectivity towards dialdehydes. Remarkably, the Rh(I) complex bearing the ligands with chlorophenyl ester substituents led to 99.9% conversion and 98.7% selectivity for dialdehydes under relatively mild conditions (6 MPa, 120℃).

Key words: Hydroformylation, Dicyclopentadiene, Monophosphite, Dialdehyde, Homogeneous catalysis

Mi Tian, Haifeng Li, Lailai Wang. Highly efficient Rh(I)/tris-H₈-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes[J]. Chinese Journal of Catalysis, 2018, 39(10): 1646-1652.

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Highly efficient Rh(I)/tris-H₈-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes

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