Effect of lengthening alkyl spacer on hydroformylation performance of tethered-phosphine modified Rh/SiO2 catalyst

doi:10.1016/S1872-2067(15)61019-1

Chinese Journal of Catalysis ›› 2016, Vol. 37 ›› Issue (2): 268-272.DOI: 10.1016/S1872-2067(15)61019-1

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Effect of lengthening alkyl spacer on hydroformylation performance of tethered-phosphine modified Rh/SiO₂ catalyst

Jia Liu^a,c, Li Yan^a,b, Miao Jiang^a,c, Cunyao Li^a,c, Yunjie Ding^a,b

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
c University of Chinese Academy of Sciences, Beijing 100049, China

Received:2015-08-24 Revised:2015-11-10 Online:2016-01-30 Published:2016-01-31
Supported by:
This work was financially supported by the National Natural Science Foundation of China (21273227, 20903090).

Abstract

Abstract:

Rh/SiO₂ catalysts with tethered-phosphines with different alkyl spacer lengths have been prepared, tested and characterized. Lengthening the alkyl spacer of the tethered-phosphine improved the flexibility of tethered-phospine, promoted the formation of active species and enhanced the activity of hydroformylation over other tethered-phosphine modified Rh/SiO₂ catalysts.

Key words: Tethered phosphine, Chain length, Rhodium, Silica, Hydroformylation

Jia Liu, Li Yan, Miao Jiang, Cunyao Li, Yunjie Ding. Effect of lengthening alkyl spacer on hydroformylation performance of tethered-phosphine modified Rh/SiO₂ catalyst[J]. Chinese Journal of Catalysis, 2016, 37(2): 268-272.

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Effect of lengthening alkyl spacer on hydroformylation performance of tethered-phosphine modified Rh/SiO₂ catalyst

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