Rh/ZnO-Al2O3 Catalysts for Selective Hydrogenation of Crotonaldehyde

doi:10.1016/S1872-2067(10)60240-9

Abstract

Abstract: Gas phase hydrogenation of crotonaldehyde was performed over 1 wt% Rh/ZnO-Al₂O₃catalysts with various Zn/Rh atomic ratios. Monometallic Rh/Al₂O₃ was also prepared for comparison. The samples were prepared by the successive impregnation of Al₂O₃with chloride precursors of zinc and rhodium. The solids have been characterized by H₂ chemisorption, temperature-programmed reduction, scanning electron microscopy, and cyclohexane dehydrogenation. Their catalytic behaviour in the gas phase crotonaldehyde hydrogenation reaction after reduction treatment in flowing hydrogen at 723 K was investigated. The relationship between catalytic activity, selectivity for crotyl alcohol, and physicochemical properties of the catalysts was examined. Results obtained showed that the presence of Zn clearly promotes the hydrogenation of the carbonyl bond. The catalyst with Zn/Rh atomic ratio of 5 displayed good catalytic stability and the highest selectivity for crotyl alcohol (70%) along with alloy formation.

Key words: rhodium-based catalyst, crotonaldehyde, hydrogenation, zinc oxide, selectivity

Mouna AOUN, Aicha BENAMAR, Mohamed CHATER. Rh/ZnO-Al2O3 Catalysts for Selective Hydrogenation of Crotonaldehyde[J]. Chinese Journal of Catalysis, 2011, 32(7): 1185-1190.

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References

1Gallezot P, Richard D. Catal Rev-Sci Eng, 1998, 40: 81
2Cerveny L, Ruzicka V. Catal Rev-Sci Eng, 1982, 24: 503
3Farnetti E, Pesce M, Kaspar J, Spogliarich R, Graziani M. J Chem Soc, Chem Commun, 1986, 746
4Weissermel K, Arpe H J. Industrial Organic Chemistry. Weinheim: Verlag Chemie, 1978
5Jenck J A, Germain J E. J Catal, 1980, 65: 133
6Vannice M A, Sen B. J Catal, 1989, 115: 65
7Vannice M A. J Mol Catal, 1990, 59: 165
8Ponec V. Appl Catal A, 1997, 149: 27
9Touroude R. J Catal, 1980, 65: 110
10Reyes P, Aguirre M C, Fierro J L G, Santori G, Ferreti O. J Mol Catal A, 2002, 184: 431
11Gallezot P, Richard D. Catal Rev-Sci Eng, 1998, 40: 81
12Rylander P N. Catalytic Hydrogenation over Platinum Metal. New York: Academic Press, 1967
13English M, Ranade V S, Lercher J A. J Mol Catal, 1997, 121: 69
14Galvagno S, Capannelli G, Damato A, Neri G, Pietropaolo R. J Mol Catal, 1986, 35: 365
15Merlo A B, Santori G F, Sambeth J, Siri G J, Casella M L, Ferretti O A. Catal Commun, 2006, 7: 204
16Dandekar A, Vannice M A. J Catal, 1998, 183: 344
17Huidobro A, Sepulveda-Escribano A, Rodriguez-Reinoso F. J Catal, 2002, 212: 94
18Igarashi A, Ohta M. Sekiyu Gakkaishi, 1994, 37: 64
19Sepulveda-Escribano A, Coloma F, Rodriguez-Reinoso F. J Catal, 1998, 178: 649
20Silvestre-Albero J, Rodriguez-Reinoso F, Sepulveda-Escribano A. J Catal, 2002, 210: 127
21Abid M, Ehret G, Touroude R. Appl Catal A, 2001, 217: 219
22Consonni M, Jokic D, Murzin, Touroude R. J Catal, 1999, 188: 165
23Ammari F, Milone C, Touroude R. J Catal, 2005, 235: 1
24Silvertre-Albero J, Senano-Ruiz J C, Sepulved-Escribano A, Rodriguez-Reinoso F. Appl Catal A, 2005, 292: 244
25Vannice M A. Top Catal, 1997, 4: 241
26Tauster S. J Acc Chem Res, 1987, 203: 89
27Rodrigues E L, Marchi A J, Apestegnia C R, Bueno J M C. Appl Catal A, 2005, 294: 197
28Gallezot P. Encyclopaedia of Catalysis: Hydrogena-tion-Heterogeneous. New York: John Wiley & Sons, 2002
29Duprez D, Sadi F, Miloudi A, Percheron-Guegan A. Stud Surf Sci Catal, 1991, 71: 629
30Duprez D. J Chim Phys, 1983, 80: 487
31Benseradj F, Sadi F, Chater M. C R Chimie, 2004, 7: 669
32Sato K, Yoshinari T, Kintaichi Y, Haneda M, Hamada H. Catal Commun, 2003, 4: 315
33Silvester-Albero J, Sepulveda-Escribano A, Rodriguez- Rei-noso F, Anderson J A. J Catal, 2004, 223: 179
34Benseradj F, Sadi F, Chater M. J Soc Alger Chim, 2002, 12: 99
35Benseradj F, Sadi F, Chater M. Appl Catal A, 2002, 228: 135
36Ojeda M, Rojas S, Garcia-Garciq F J, Lopez Granados M, Terreros P, Fierro J L G. Catal Commun, 2004, 5: 703
37Cusumano J A, Dembinski G W, Sinfelt J H. J Catal, 1966, 5: 471
38Blakely D W, Somorjai G A. J Catal, 1976, 42: 181
39Rodriguez-Ramos I, Guerrero-Ruiz A. J Catal, 1992, 135: 458
40Silvester-Albero J, Sepulveda-Escribano A, Rodriguez- Reinoso F, Anderson J A. J Catal, 2004, 223: 179
41Rodriguez E L, Bueno J M C. Appl Catal A, 2002, 232: 147
42Vannice M A. Catal Today, 1992, 12: 255
43Backman L B, Rautiainenb A, Lindbladb M, Krausea A O I. Appl Catal A, 2000, 191: 55
44Nishiyama S, Hra T, Tsuruya S, Masai M. J Phys Chem, 1999, 103: 4431
45Singh U K, Vannice M A. J Catal, 2000, 191: 165
46Lafaye G, Micheaud-Especel C, Montassier C, Marecot P. Appl Catal A, 2002, 230: 19
47Bailie J E, Hutching G J. J Mol Catal A, 2002, 177: 209
48Singh U K, Vannice M A. J Mol Catal A, 2000, 163: 233
49Marchi A J, Gordo D A, Trasarti A F, Apestegnia C R. Appl Catal A, 2003, 249: 53
50Rodrigues C E C, Rodrigues E L, Marques C M, Bueno J M C. Anais do XVII, Simpósio Ibero-Americano de Catálise. Portugal: Porto, 2000. 595
51Rodrigues E L, Bueno J M C. Appl Catal A, 2004, 257: 201
52Ammari F, Lamotte J, Touroude R. J Catal, 2004, 221: 32
53Homs N, Llorca J, Ramirez de la Piscina P, Rodriguez- Reinoso F, Sepúlveda-Escribano A, Silvestre- Albero J. Phys Chem Chem Phys, 2001, 3: 1782
54Reyes P, Rojas H, Fierro J L G. Appl Catal A, 2003, 248: 59

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