Ammoximation of Citronellal with H2O2 Catalyzed by TS-1

doi:10.3724/SP.J.1088.2012.11019

Abstract

Abstract: The TS-1/H₂O₂ system has excellent catalytic performance in citronellal ammoximation to citronellal oxime. The effects of various reaction parameters on the catalytic properties of TS-1 were studied in detail. Under the optimized reaction conditions, citronellal conversion and citronellal oxime selectivity are over 99.9% and 99.2%, respectively. We found that there is also aldol condensation, which is competitive with ammoximation. Moreover, the epoxidation and ammoximation of citronellal catalyzed by TS-1 are also competitive reactions. The side reactions can be restrained efficiently by adjusting NH₃amount in reaction system.

Key words: TS-1 zeolite, citronellal, hydrogen superoxide, ammoximation, citronellal oxime

ZHANG Shuo, DENG Xiu-Juan, SHEN Lu, LIU Yue-Ming. Ammoximation of Citronellal with H₂O₂ Catalyzed by TS-1[J]. Chinese Journal of Catalysis, 2012, 33(4): 723-729.

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Ammoximation of Citronellal with H₂O₂ Catalyzed by TS-1

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