Heterogeneous Bimetallic Pt-Sn/γ-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines

doi:10.3724/SP.J.1088.2012.11105

Abstract

Abstract: N-Alkylation of amines with alcohols through a borrowing hydrogen strategy is a green route to amines. Heterogeneous bimetallic Pt-Sn/γ-Al₂O₃ catalyzed the reactions of primary (secondary) amines with alcohols in the absence of external hydrogen source, efficiently affording secondary (tertiary) amines with water and a small amount of imines as the by-products. Various functional groups in the substrates were tolerated in the catalytic system. The Pt-Sn/γ-Al₂O₃catalyst was easily recycled, suggesting its potential application in the production of secondary and tertiary amines.

Key words: platinum, tin, alumina, supported catalyst, borrowing hydrogen, heterogeneous catalysis, N-alkylation, amine, alcohol

HE Wei, HE Song-Bo, SUN Cheng-Lin, WU Kai-Kai, WANG Lian-Di, YU Zheng-Kun. Heterogeneous Bimetallic Pt-Sn/γ-Al₂O₃ Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines[J]. Chinese Journal of Catalysis, 2012, 33(4): 717-722.

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Heterogeneous Bimetallic Pt-Sn/γ-Al₂O₃ Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines

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