4-N,N-Dimethylamino Pyridine Promoted Oxidation of Toluene Catalyzed by Cobalt Acetate and Benzyl Bromide

doi:10.3724/SP.J.1088.2012.20314

Abstract

Abstract: The influence of different nitrous organic compounds, including triethylamine, 2,6-dimethylpyridine, 4-carboxylic pyridine, pyridine, and 4-N,N-dimethylamino pyridine (DMAP), on the oxidation of toluene catalyzed by cobalt acetate and benzyl bromide was investigated. DMAP showed improvement for the activity. The promoting effect was discussed.

Key words: selective oxidation, molecular oxygen, toluene, 4-N,N-dimethylamino pyridine, benzyl bromide

ZHANG Zhan, GAO Jin, MA Hong, XU Jie. 4-N,N-Dimethylamino Pyridine Promoted Oxidation of Toluene Catalyzed by Cobalt Acetate and Benzyl Bromide[J]. Chinese Journal of Catalysis, 2012, 33(7): 1198-1202.

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URL: https://www.cjcatal.com/EN/10.3724/SP.J.1088.2012.20314

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