Cobalt Porphyrin Immobilized on Montmorillonite: A Highly Efficient and Reusable Catalyst for Aerobic Oxidation of Alcohols to Carbonyl Compounds

doi:10.1016/S1872-2067(11)60461-0

Abstract

Abstract: The highly efficient aerobic oxidation of alcohols to carbonyl compounds was achieved catalyzed by cationic meso-tetrakis (1-methyl-4-pyridyl, TM4PyP) metalloporphyrins immobilized in montmorillonite interlayers. Cobalt porphyrin (CoTM4PyP-MT) showed excellent activity and selectivity in the aerobic oxidation of benzyl alcohol, where 90% yield of benzaldehyde was obtained. CoTM4PyP-MT can be five times reused without significant loss of activity.

Key words: metalloporphyrins, montmorillonite, oxidation, alcohol, dioxygen

ZHOU Xian-Tai, JI Hong-Bing. Cobalt Porphyrin Immobilized on Montmorillonite: A Highly Efficient and Reusable Catalyst for Aerobic Oxidation of Alcohols to Carbonyl Compounds[J]. Chinese Journal of Catalysis, 2012, 33(12): 1906-1912.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60461-0

https://www.cjcatal.com/EN/Y2012/V33/I12/1906

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