Selective catalytic reduction of NOx by NH3 for heavy-duty diesel vehicles

doi:10.1016/S1872-2067(14)60048-6

Abstract

Abstract:

A catalyst production line with a production capacity of 6000 catalyst monoliths per month for the selective catalytic reduction of NO_x by NH₃(NH₃-SCR) for NO_x abatement in diesel vehicle exhaust was set up based on a detailed laboratory study of the catalyst formulation and washcoating technology for V₂O₅-WO₃/TiO₂ catalyst. The catalyst produced by this line was tested on a bench scale diesel engine. The V₂O₅-WO₃/TiO₂ powder catalyst prepared in the laboratory and production line both achieved >80% NO_x conversion at 200-450 ℃ and a GHSV of 50000 h^-1. The washcoated catalyst used a large cordierite support and gave >80% NO_x conversion at 250-450 ℃ and GHSVs of 10000-30000 h^-1. The engine bench tests showed that after treatment by the catalyst, the NO_x emission met the European steady-state cycle (ESC) and European transient cycle (ETC) limits of the China IV standard. The production line can also be used for the production of vanadium-free NH₃-SCR catalysts to meet the required replacement of the present vanadium-based NH₃-SCR catalyst in the future.

Key words: Diesel exhaust, Nitrogen oxide, Selective catalytic reduction, Vanadium-based catalyst, Industrial production

Fudong Liu, Wenpo Shan, Dawei Pan, Tengying Li, Hong He. Selective catalytic reduction of NO_x by NH₃ for heavy-duty diesel vehicles[J]. Chinese Journal of Catalysis, 2014, 35(9): 1438-1445.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60048-6

https://www.cjcatal.com/EN/Y2014/V35/I9/1438

References

[1] Granger P, Parvulescu V I. Chem Rev, 2011, 111: 3155
[2] Liu Z M, Woo S I. Catal Rev, 2006, 48: 43
[3] Ministry of Environmental Protection of the People's Republic of China. China Vehicle Emission Control Annual Report (2012) [EB/OL]. [2012-12-27]. http://www.mep.gov.cn/gkml/hbb/qt/201212/t20121227_244340.htm
[4] Johnson T V. Int J Engine Res, 2009, 10: 275
[5] Liu Q Y, Liu Z Y. J Chem Ind Eng (China), 2008, 59: 1894
[6] Roy S, Hegde M S, Madras G. Appl Energy, 2009, 86: 2283
[7] Long R Q, Yang R T. J Am Chem Soc, 1999, 121: 5595
[8] Brandenberger S, Kröcher O, Tissler A, Althoff R. Catal Rev, 2008, 50: 492
[9] Shi X Y, Liu F D, Xie L J, Shan W P, He H. Environ Sci Technol, 2013, 47: 3293
[10] Kwak J H, Tonkyn R G, Kim D H, Szanyi J, Peden C H F. J Catal, 2010, 275: 187
[11] Schmieg S J, Oh S H, Kim C H, Brown D B, Lee J H, Peden C H F, Kim D H. Catal Today, 2012, 184: 252
[12] Fickel D W, D'addio E, Lauterbach J A, Lobo R F. Appl Catal B, 2011, 102: 441
[13] Xie L J, Liu F D, Ren L M, Shi X Y, Xiao F S, He H. Environ Sci Technol, 2014, 48: 566
[14] Martínez-Franco R, Moliner M, Franch C, Kustov A, Corm A. Appl Catal B, 2012, 127: 273
[15] Yu T, Wang J, Shen M Q, Li W. Catal Sci Technol, 2013, 3: 3234
[16] Ma L, Cheng Y S, Cavataio G, McCabe R W, Fu L X, Li J H. Chem Eng J, 2013, 225: 323
[17] Shan W P, Liu F D, He H, Shi X Y, Zhang C B. Appl Catal B, 2012, 115-116: 100
[18] Shan W P, Liu F D, He H, Shi X Y, Zhang C B. Chem Commun, 2011, 47: 8046
[19] Chen L, Li J H, Ge M F, Zhu R H. Catal Today, 2010, 153: 77
[20] Peng Y, Qu R Y, Zhang X Y, Li J H. Chem Commun, 2013, 49: 6215
[21] Liu Z M, Yi Y, Li J H, Woo S I, Wang B Y, Cao X Z, Li Z X. Chem Commun, 2013, 49: 7726
[22] Ma Z R, Weng D, Wu X D, Si Z C. J Environ Sci, 2012, 24: 1305
[23] Si Z C, Weng D, Wu X D, Yang J, Wang B. Catal Commun, 2010, 11: 1045
[24] Si Z C, Weng D, Wu X D, Ran R, Ma Z R. Catal Commun, 2012, 17: 146
[25] Liu F D, He H, Zhang C B. Chem Commun, 2008: 2043
[26] Yang S J, Li J H, Wang C Z, Chen J H, Ma L, Chang H Z, Chen L, Peng Y, Yan N Q. Appl Catal B, 2012, 117-118: 73
[27] Ma L, Li J H, Ke R, Fu L X. J Phys Chem C, 2011, 115: 7603
[28] Si Z C, Weng D, Wu X D, Li J, Li G. J Catal, 2010, 271: 43
[29] Busca G, Lietti L, Ramis G, Berti F. Appl Catal B, 1998, 18: 1
[30] Liu F D, Shan W P, Shi X Y, Zhang C B, He H. Chin J Catal (刘福东, 单文坡, 石晓燕, 张长斌, 贺泓. 催化学报), 2011, 32: 1113

Selective catalytic reduction of NO_x by NH₃ for heavy-duty diesel vehicles

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Xiaona Liu, Yi Cao, Nana Yan, Chao Ma, Lei Cao, Peng Guo, Peng Tian, Zhongmin Liu. Cu-SAPO-17: A novel catalyst for selective catalytic reduction of NO_x [J]. Chinese Journal of Catalysis, 2020, 41(11): 1715-1722.
[2]	Yiyang Zhang, Hui Zeng, Bin Jia, Zhihua Wang, Zhiming Liu. Selective catalytic reduction of NO_x by H₂ over Pd/TiO₂ catalyst [J]. Chinese Journal of Catalysis, 2019, 40(6): 849-855.
[3]	Shujun Ming, Lei Pang, Chi Fan, Wen Guo, Yahao Dong, Peng Liu, Zhen Chen, Tao Li. Chemical deactivation of Cu-SAPO-18 deNO_x catalyst caused by basic inorganic contaminants in diesel exhaust [J]. Chinese Journal of Catalysis, 2019, 40(4): 590-599.
[4]	Chuanmin Chen, Yue Cao, Songtao Liu, Jianmeng Chen, Wenbo Jia. Review on the latest developments in modified vanadium-titanium-based SCR catalysts [J]. Chinese Journal of Catalysis, 2018, 39(8): 1347-1365.
[5]	Jun Yang, Yupeng Chang, Weili Dai, Guangjun Wu, Naijia Guan, Landong Li. Bimetallic Cr-In/H-SSZ-13 for selective catalytic reduction of nitric oxide by methane [J]. Chinese Journal of Catalysis, 2018, 39(5): 1004-1011.
[6]	Zhongyi Sheng, Dingren Ma, Danqing Yu, Xiang Xiao, Bingjie Huang, Liu Yang, Sheng Wang. Synthesis of novel MnO_x@TiO₂ core-shell nanorod catalyst for low-temperature NH₃-selective catalytic reduction of NO_x with enhanced SO₂ tolerance [J]. Chinese Journal of Catalysis, 2018, 39(4): 821-830.
[7]	Yarong Fang, Yanbing Guo. Copper-based non-precious metal heterogeneous catalysts for environmental remediation [J]. Chinese Journal of Catalysis, 2018, 39(4): 566-582.
[8]	Xiaoxia Dai, Weiyu Jiang, Wanglong Wang, Xiaole Weng, Yuan Shang, Yehui Xue, Zhongbiao Wu. Supercritical water syntheses of transition metal-doped CeO₂nano-catalysts for selective catalytic reduction of NO by CO: An in situ diffuse reflectance Fourier transform infrared spectroscopy study [J]. Chinese Journal of Catalysis, 2018, 39(4): 728-735.
[9]	Yexuan Wen, Shuang Cao, Xiaoqi Fei, Haiqiang Wang, Zhongbiao Wu. One-step synthesized SO₄^2--TiO₂ with exposed (001) facets and its application in selective catalytic reduction of NO by NH₃ [J]. Chinese Journal of Catalysis, 2018, 39(4): 771-778.
[10]	Lei Chen, Ding Weng, Jiadao Wang, Duan Weng, Li Cao. Low-temperature activity and mechanism of WO₃-modified CeO₂-TiO₂ catalyst under NH₃-NO/NO₂ SCR conditions [J]. Chinese Journal of Catalysis, 2018, 39(11): 1804-1813.
[11]	Wei Li, Cheng Zhang, Xin Li, Peng Tan, Anli Zhou, Qingyan Fang, Gang Chen. Ho-modified Mn-Ce/TiO₂ for low-temperature SCR of NO_x with NH₃: Evaluation and characterization [J]. Chinese Journal of Catalysis, 2018, 39(10): 1653-1663.
[12]	Wenjin Xu, Guangxu Zhang, Hanwei Chen, Guomeng Zhang, Yang Han, Yichuan Chang, Peng Gong. Mn/beta and Mn/ZSM-5 for the low-temperature selective catalytic reduction of NO with ammonia: Effect of manganese precursors [J]. Chinese Journal of Catalysis, 2018, 39(1): 118-127.
[13]	Tiaoyun Zhou, Qing Yuan, Xiulian Pan, Xinhe Bao. Growth of Cu/SSZ-13 on SiC for selective catalytic reduction of NO with NH₃ [J]. Chinese Journal of Catalysis, 2018, 39(1): 71-78.
[14]	Xiaojiang Yao, Li Chen, Tingting Kong, Shimin Ding, Qiong Luo, Fumo Yang. Support effect of the supported ceria-based catalysts during NH₃-SCR reaction [J]. Chinese Journal of Catalysis, 2017, 38(8): 1423-1430.
[15]	Kai Qi, Junlin Xie, De Fang, Fengxiang Li, Feng He. Performance enhancement mechanism of Mn-based catalysts prepared under N₂ for NO_x removal: Evidence of the poor crystallization and oxidation of MnO_x [J]. Chinese Journal of Catalysis, 2017, 38(5): 845-852.