Cu-SAPO-17: A novel catalyst for selective catalytic reduction of NOx

doi:10.1016/S1872-2067(20)63609-9

Abstract

Abstract: The high-temperature (HT) and low-temperature (LT) hydrothermal stabilities of molecular-sieve-based catalysts are important for the selective catalytic reduction of NO_x with ammonia (NH₃-SCR). In this paper, we report a catalyst, Cu²⁺ loading SAPO-17, synthesized using cyclohexylamine (CHA), which is commercially available and inexpensive and is utilized in NH₃-SCR reduction for the first time. After systematic investigations on the optimization of Si and Cu²⁺ contents, it was concluded that Cu-SAPO-17-8.0%-0.22 displays favorable catalytic performance, even after being heated at 353 K for 24 h and at 973 K for 16 h. Moreover, the locations of CHAs, host-guest interaction and the Brönsted acid sites were explored by Rietveld refinement against powder X-ray diffraction data of as-made SAPO-17-8.0%. The refinement results showed that two CHAs exist within one eri cage and that the protonated CHA forms a hydrogen bond with O4, which indicates that the proton bonding with O4 will form the Brönsted acid site after the calcination.

Key words: SAPO-17 molecular sieve, Rietveld refinement, Host-guest interaction, Selective catalytic reduction by ammonia (NH₃-SCR), Hydrothermal stability, Location of Cu²⁺

Xiaona Liu, Yi Cao, Nana Yan, Chao Ma, Lei Cao, Peng Guo, Peng Tian, Zhongmin Liu. Cu-SAPO-17: A novel catalyst for selective catalytic reduction of NO_x[J]. Chinese Journal of Catalysis, 2020, 41(11): 1715-1722.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(20)63609-9

https://www.cjcatal.com/EN/Y2020/V41/I11/1715

References

[1] L. Zhang, Q. Wu, X. Meng, U. Müller, M. Feyen, D. Dai, S. Maurer, R. McGuire, A. Moini, A.-N. Parvulescu, W Zhang, C. Shi, T. Yokoi, X. Pan, X. H. Bao, H. Gies, B. Marler, D. de Vos, U. Kolb, F. Xiao, React. Chem. Eng., 2019, 4, 975-985.
[2] A. M. Beale, F. Gao, I. Lezcano-Gonzalez, C. H. F. Peden, J. Szanyi, Chem. Soc. Rev., 2015, 44, 7371-7405.
[3] Y. Cao, D. Fan, P. Tian, L. Cao, T. Sun, S. Xu, M. Yang, Z. Liu, Chem. Eng. J., 2018, 354, 85-92.
[4] N. Wilken, K. Wijayanti, K. Kamasamudram, N. W. Currier, R. Vedaiyan, A. Yezerets, L. Olsson, Appl. Catal. B, 2012, 111-112, 58-66.
[5] J. A. Sullivan, J. Cunningham, M. A. Morris, K. Keneavey, Appl. Catal. B, 1995, 7, 137-151.
[6] J. H. Kwak, R. G. Tonkyn, D. H. Kim, J. Szanyi, C. H. F. Peden, J. Catal., 2010, 275, 187-190.
[7] M. Moliner, C. Franch, E. Palomares, M. Grill, A. Corma, Chem. Commun., 2012, 48, 8264-8266.
[8] N. H. Ahn, T. Ryu, Y. Kang, H. Kim, J. Shin, I.-S. Nam, S. B. Hong, ACS Catal., 2017, 7, 6781-6785.
[9] N. Martín, C. Paris, P. N. R. Vennestrøm, J. R. Thøgersen, M. Moliner, A. Corma, Appl. Catal. B, 2017, 217, 125-136.
[10] X. Liu, N. Yan, L. Wang, C. Ma, P. Guo, P. Tian, G. Cao, Z. Liu, Microporous Mesoporous Mater., 2019, 280, 105-115.
[11] Z. Chen, C. Fan, L. Pang, S. Ming, W. Guo, P. Liu, H. Chen, T. Li, Chem. Eng. J., 2018, 348, 608-617.
[12] N. Liu, J. Wang, B. Chen, Y. Li, R. Zhang, Chem. J. Chin. Univ., 2016, 37, 1817-1825.
[13] X.-Q. Liu, S.-h. Li, M.-t. Sun, C.-l. Yu, B.-C. Huang, Acta Phys. Chim. Sin., 2016, 32, 1236-1246.
[14] A. Lorena Picone, S. J. Warrender, A. M. Z. Slawin, D. M. Dawson, S. E. Ashbrook, P. A. Wright, S. P. Thompson, L. Gaberova, P. L. Llewellyn, B. Moulin, A. Vimont, M. Daturi, M. B. Park, S. K. Sung, I. Nam, S. B. Hong, Microporous Mesoporous Mater., 2011, 146, 36-47.
[15] J. J. Pluth, J. V. Smith, J. M. Bennett, Acta Cryst. Sec. C, 1986, C42, 283-286.
[16] B. M. Lok, C. A. Messina, R. L. Patton, R. T. Gajek, T. R. Cannan, E. M. Flanigen, US Patent 4440871, 1984.
[17] A. M. Prakash, L. Kevan, Langmuir, 1997, 13, 5341-5348.
[18] B. Zibrowius, U. Lohse, Solid State Nucl. Magn. Reson., 1992, 1, 137-148.
[19] I. Girnus, E. Löffler, U. Lohse, F. Neissendorfer, Collect. Czech. Chem. Commun., 1992, 57, 946-958.
[20] Q. Liu, N. C. O. Cheung, A. E. Garcia-Bennett, N. Hedin, ChemSusChem, 2011, 4, 91-97.
[21] Q. Gao, S. Li, R. Xu, J. Chem. Soc., Chem. Commun., 1994, 1465-1466.
[22] A. Tuel, C. Lorentz, V. Gramlich, C. Baerlocher, C. R. Chimie, 2005, 8, 531-540.
[23] E. W. Valyocsik, R. Von Ballmoos, US Patent 4778780, 1988.
[24] M. J. Maple, C. D. Williams, Dalton Trans., 2007, 4175-4181.
[25] A. B. Pinar, L. Gómez-Hortigüela, L. B. McCusker, J. Pérez-Pariente, Chem. Mater., 2013, 25, 3654-3661.
[26] L. Gómez-Hortigüela, F. Corà, C. R. A. Catlow, J. Pérez-Pariente, J. Am. Chem. Soc., 2004, 126, 12097-12102.
[27] L. Marchese, A. Frache, E. Gianotti, G. Martra, M. Causà, S. Coluccia, Microporous Mesoporous Mater., 1999, 30, 145-153.
[28] F. Fan, Z. Feng, K. Sun, M. Guo, Q. Guo, Y. Song, W. Li, C. Li, Angew. Chem. Int. Ed., 2009, 48, 8743-8747.
[29] M. B. Park, Y. Lee, A. Zheng, F.-S. Xiao, C. P. Nicholas, G. J. Lewis, S. B. Hong, J. Am. Chem. Soc., 2013, 135, 2248-2255.
[30] B. Han, C.-H. Shin, S. J. Warrender, P. Lightfoot, P. A. Wright, M. A. Camblor, S. B. Hong, Chem. Mater., 2006, 18, 3023-3033.
[31] S. Smeets, S. I. Zones, D. Xie, L. Palatinus, J. Pascual, S.-J. Hwang, J. E. Schmidt, L. B. McCusker, Angew. Chem. Int. Ed., 2019, 58, 13080-13086.
[32] N. Yan, L. Wang, X. Liu, P. Wu, T. Sun, S. Xu, J. Han, P. Guo, P. Tian, Z. Liu, J. Mater. Chem. A, 2018, 6, 24186-24193.
[33] S. B. Hong, E. G. Lear, P. A. Wright, W. Zhou, P. A. Cox, C.-H. Shin, J.-H. Park, I.-S. Nam, J. Am. Chem. Soc., 2004, 126, 5817-5826.
[34] S. Zhong, S. Song, B. Wang, N. Bu, X. Ding, R. Zhou, W. Jin, Microporous Mesoporous Mater., 2018, 263, 11-20.
[35] U. Lohse, Loffler, E, Kosche, K, Janchen, J, Parlitz, B, Zeolites, 1993, 13, 549-556.
[36] X. Xiang, M. Yang, B. Gao, Y. Qiao, P. Tian, S. Xu, Z. Liu, RSC Adv., 2016, 6, 12544-12552.
[37] Y. Cao, D. Fan, L. Sun, M. Yang, L. Cao, T. Sun, S. Xu, P. Tian, Z. Liu, Chem. Eng. J., 2019, 374, 832-839.
[38] T. Yu, J. Wang, M. Shen, W. Li, Catal. Sci. Technol., 2013, 3, 3234-3241.
[39] S. A. Bates, A. A. Verma, C. Paolucci, A. A. Parekh, T. Anggara, A. Yezerets, W. F. Schneider, J. T. Miller, W. N. Delgass, F. H. Ribeiro, J. Catal., 2014, 312, 87-97.
[40] J. Tang, M. Xu, T. Yu, H. Ma, M. Shen, J. Wang, Chem. Eng. Sci., 2017, 168, 414-422.

Cu-SAPO-17: A novel catalyst for selective catalytic reduction of NO_x

PDF (PC)

Knowledge

Supporting Information

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Wen Zhang, Cai-Cai Song, Jia-Wei Wang, Shu-Ting Cai, Meng-Yu Gao, You-Xiang Feng, Tong-Bu Lu. Bidirectional host-guest interactions promote selective photocatalytic CO₂ reduction coupled with alcohol oxidation in aqueous solution [J]. Chinese Journal of Catalysis, 2023, 52(9): 176-186.
[2]	Lijing Sun, Miao Yang, Yi Cao, Peng Tian, Pengfei Wu, Lei Cao, Shutao Xu, Shu Zeng, Zhongmin Liu. A reconstruction strategy for the synthesis of Cu-SAPO-34 with excellent NH₃-SCR catalytic performance and hydrothermal stability [J]. Chinese Journal of Catalysis, 2020, 41(9): 1410-1420.
[3]	XU Jun, WANG Qiang, DENG Feng. Solid-State NMR Spectroscopy in Catalysis: Progress and Perspective [J]. Chinese Journal of Catalysis, 2019, 40(s1): 30-35.
[4]	Zeshu Zhang, Jingwei Li, Ting Yi, Liwei Sun, Yibo Zhang, Xuefeng Hu, Wenhao Cui, Xiangguang Yang. Surface density of synthetically tuned spinel oxides of Co³⁺ and Ni³⁺ with enhanced catalytic activity for methane oxidation [J]. Chinese Journal of Catalysis, 2018, 39(7): 1228-1239.
[5]	Shuang Zhao, Liming Huang, Boqiong Jiang, Min Cheng, Jiawei Zhang, Yijing Hu. Stability of Cu-Mn bimetal catalysts based on different zeolites for NO_x removal from diesel engine exhaust [J]. Chinese Journal of Catalysis, 2018, 39(4): 800-809.
[6]	Jian Ding, Teng Xue, Haihong Wu, Mingyuan He. One-step post-synthesis treatment for preparing hydrothermally stable hierarchically porous ZSM-5 [J]. Chinese Journal of Catalysis, 2017, 38(1): 48-57.
[7]	Yun Zhao, Jiaxu Liu, Guang Xiong, Hongchen Guo. Enhancing hydrothermal stability of nano-sized HZSM-5 zeolite by phosphorus modification for olefin catalytic cracking of full-range FCC gasoline [J]. Chinese Journal of Catalysis, 2017, 38(1): 138-145.
[8]	Xuesong Liu, Xiaodong Wu, Tengfei Xu, Duan Weng, Zhichun Si, Rui Ran. Effects of silica additive on the NH₃-SCR activity and thermal stability of a V₂O₅/WO₃-TiO₂ catalyst [J]. Chinese Journal of Catalysis, 2016, 37(8): 1340-1346.
[9]	Xiaohui Du, Xueli Li, Haitao Zhang, Xionghou Gao. Kinetics study and analysis of zeolite Y destruction [J]. Chinese Journal of Catalysis, 2016, 37(2): 316-323.
[10]	Chenglong Zou, Guanyu Sha, Haifang Gu, Yao Huang, Guoxing Niu. Facile solvothermal post-treatment to improve hydrothermal stability of mesoporous SBA-15 zeolite [J]. Chinese Journal of Catalysis, 2015, 36(8): 1350-1357.
[11]	Chenglong Zou, Guanyu Sha, Yao Huang, Guoxing Niu, Dongyuan Zhao . Incorporation of Al³⁺ ions to promote the stabilization effect of (NH₄)₂SiF₆ treatment on the hydrothermal stability of mesoporous SBA-15 zeolite [J]. Chinese Journal of Catalysis, 2015, 36(7): 1001-1008.
[12]	Shenhui Li, Lei Zhou, Anmin Zheng, Feng Deng. Recent advances in solid state NMR characterization of zeolites [J]. Chinese Journal of Catalysis, 2015, 36(6): 789-796.
[13]	Xiaoyan Shi, Hong He, Lijuan Xie. The effect of Fe species distribution and acidity of Fe-ZSM-5 on the hydrothermal stability and SO₂ and hydrocarbons durability in NH₃-SCR reaction [J]. Chinese Journal of Catalysis, 2015, 36(4): 649-656.
[14]	Runqin Wang, Ronghe Lin, Yunjie Ding, Jia Liu, Wenting Luo, Hong Du, Yuan Lü. Highly hydrothermally stable FePO₄-SBA-15 synthesized using a novel one-pot hydrothermal method [J]. Chinese Journal of Catalysis, 2015, 36(3): 446-453.
[15]	Lei Pang, Chi Fan, Lina Shao, Junxia Yi, Xing Cai, Jian Wang, Ming Kang, Tao Li. Effect of V₂O₅/WO₃-TiO₂ catalyst preparation method on NO_x removal from diesel exhaust [J]. Chinese Journal of Catalysis, 2014, 35(12): 2020-2028.