One-step post-synthesis treatment for preparing hydrothermally stable hierarchically porous ZSM-5

doi:10.1016/S1872-2067(16)62549-4

Abstract

Abstract:

Hierarchically porous ZSM-5 (SiO₂/Al₂O₃≈120) containing phosphorus was prepared by a one-step post-synthesis treatment involving controlled desilication and phosphorous modification. The hier-archically porous ZSM-5 featured high thermal and hydrothermal stability. The obtained ZSM-5 zeolites were systematically characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, N₂ adsorption-desorption, NH₃ temperature-programmed de-sorption, and ²⁷Al and ³¹P magic-angle spinning nuclear magnetic resonance spectroscopy. The prepared ZSM-5 displayed enhanced activity and prolonged lifetime toward hydrocarbon cracking. The high activity was attributed to improved coke tolerance owing to the presence of the highly stable mesoporous network of ZSM-5 and acid sites introduced upon phosphorus modification. Additionally a mechanism of the stabilization of the zeolites by phosphorus was proposed and dis-cussed.

Key words: Desilication, Phosphorus stabilization, One-step modification, Hydrothermal stability, Hydrocarbon cracking

Jian Ding, Teng Xue, Haihong Wu, Mingyuan He. One-step post-synthesis treatment for preparing hydrothermally stable hierarchically porous ZSM-5[J]. Chinese Journal of Catalysis, 2017, 38(1): 48-57.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(16)62549-4

https://www.cjcatal.com/EN/Y2017/V38/I1/48

References

[1] W. W. Kaeding, L. B. Young, C. C. Chu, J. Catal., 1984, 89, 267-273.
[2] C. Feng, K. Khulbe, T. Matsuura, R. Farnood, A. Ismail, J. Membr. Sci. Res., 2015, 1, 49-72.
[3] B. M. Weckhuysen, J. Yu, Chem. Soc. Rev., 2015, 44, 7022-7024.
[4] D. Kubi?ka, O. Kikhtyanin, Catal. Today, 2015, 243, 10-22.
[5] W. W. Kaeding, C. Chu, L. B. Young, S. A. Butter, J. Catal., 1981, 69, 392-398.
[6] A. Corma, Chem. Rev., 1997, 97, 2373-2420.
[7] J. Pérez-Ram?rez, F. Kapteijn, J. C. Groen, A. Doménech, G. Mul, J. A. Moulijn, J. Catal., 2003, 214, 33-45.
[8] M. Hartmann, Angew. Chem. Int. Ed., 2004, 43, 5880-5882.
[9] T. Tago, H. Konno, Y. Nakasaka, T. Masuda, Catal. Surv. Asia, 2012, 16, 148-163.
[10] J. Perez-Ramirez, C. H. Christensen, K. Egeblad, C. H. Christensen, J. C. Groen, Chem. Soc. Rev., 2008, 37, 2530-2542.
[11] J. Ding, J. B. Hu, T Xue, Y. M. Wang, H. H. Wu, P. Wu, M. Y. He, RSC Adv., 2016, 6, 38671-38679.
[12] H. Mochizuki, T. Yokoi, H. Imai, S. Namba, J. N. Kondo, T. Tatsumi, Appl. Catal. A, 2012, 449, 188-197.
[13] M. Choi, K. Na, J. Kim, Y. Sakamoto, O. Terasaki, R. Ryoo, Nature, 2009, 461, 246-249.
[14] B. K. Singh, D. D. Xu, L. Han, J. Ding, Y. M. Wang, S. Che, Chem. Ma-ter., 2014, 26, 7183-7188.
[15] F. L. Bleken, K. Barbera, F. Bonino, U. Olsbye, K. P. Lillerud, S. Bor-diga, P. Beato, T. V. W. Janssens, S. Svelle, J. Catal., 2013, 307, 62-73.
[16] J. Li, X. Y. Li, G. Q. Zhou, W. Wang, C. W. Wang, S. Komarneni, Y. J. Wang, Appl. Catal. A, 2014, 470, 115-122.
[17] J. C. Groen, J. A. Moulijn, J. Pérez-Ramírez, J. Mater. Chem. A, 2006, 16, 2121-2131.
[18] S. Mitchell, M. Milina, R. Verel, M. Hernández-Rodríguez, A. B. Pi-nar, L. B. McCusker, J. Pérez-Ramírez, Chem. Eur. J., 2015, 21, 14156-14164.
[19] H. E. Van Der Bij, F. Meirer, S. Kalirai, J. Wang, B. M. Weckhuysen, Chem. Eur. J., 2014, 20, 16922-16932.
[20] M. Derewinski, P. Sarv, X. Sun, S. Mü ller, A. C. van Veen, J. A. Lerch-er, J. Phys. Chem. B, 2014, 118, 6122-6131.
[21] Q. Fu, C. P. Kelkar, G. Smith, B. Yilmaz, US Patent 8940652, 2015.
[22] T. Blasco, A. Corma, J. Martínez-Triguero, J. Catal., 2006, 237, 267-277.
[23] T. F. Degnan, G. K. Chitnis, P. H. Schipper, Microporous Mesoporous Mater., 2000, 35, 245-252.
[24] N. H. Xue, X. K. Chen, L. Nie, X. F. Guo, W. P. Ding, Y. Chen, M. Gu, Z. K. Xie, J. Catal., 2007, 248, 20-28.
[25] R. Chal, C. Gérardin, M. Bulut, S. Van Donk, ChemCatChem, 2011, 3, 67-81.
[26] K. Y. Lee, H. K. Lee, S. K. Ihm, Top. Catal., 2010, 53, 247-253.
[27] H. G. Jang, H. K. Min, S. B. Hong, G. Seo, J. Catal., 2013, 299, 240-248.
[28] J. J. Huangfu, D. S. Mao, X. L. Zhai, Q. S. Guo, Appl. Catal. A, 2016, 520, 99-104.
[29] J. A. Lercher, G. Rumplmayr, Appl. Catal., 1986, 25, 215-222.
[30] J. Ding, M. Wang, L. M. Peng, N. H. Xue, Y. M. Wang, M. Y. He, Appl. Catal. A, 2015, 503, 147-155.
[31] G. Caeiro, P. Magnoux, J. M. Lopes, F. R. Ribeiro, S. M. C. Menezes, A. F. Costa, H. S. Cerqueira, Appl. Catal. A, 2006, 314, 160-171.
[32] D. Minoux, C. Adam, N. Nesterenko, S. Van Donk, J. P. Dath, W. Vermeiren, US Patent 9249066, 2016.
[33] D. H. Choo, H. C. Kim, S. J. Kim, J. M. Kim, T. J. Kim, S. Choi, S. H. Oh, Y. S. Kim, D. S. Park, Y. K. Park, C. W. Lee, H. Y. Kim, W. C. Choi, N. Y. Kang, B. S. Song, US Patent 9056308, 2015.
[34] K. Sadowska, K. Góra-Marek, M. Drozdek, P. Ku?trowski, J. Datka, J. Martinez Triguero, F. Rey, Microporous Mesoporous Mater., 2013, 168, 195-205.
[35] J. C. Groen, L. A. A. Peffer, J. A. Moulijn, J. Pérez-Ramírez, Chem. Eur. J., 2005, 11, 4983-4994.
[36] J. C. Groen, J. C. Jansen, J. A. Moulijn, J. Pérez-Ramírez, J. Phys. Chem. B, 2004, 108, 13062-13065.
[37] Z. M. Yan, D. Ma, J. Q. Zhuang, X. C. Liu, X. M. Liu, X. W. Han, X. H. Bao, F. X. Chang, L. M. Xu, Z. Liu, J. Mol. Catal. A, 2003, 194, 153-167.
[38] Y. Y. Shu, D. Ma, X. C. Liu, X. W. Han, Y. D. Xu, X. H. Bao, J. Phys.Chem. B, 2000, 104, 8245-8249.
[39] C. A. Fyfe, Solid State NMR for Chemists, CFC Press, Guelph, Ont., 1983.
[40] R. F. Nogueira, M. I. B. Tavares, R. A. San Gil, A. G. Ferreira, Mater. Sci. Appl., 2011, 2, 453.
[41] Z. Li, J. Martínez-Triguero, J. Yu, A. Corma, J. Catal., 2015, 329, 379-388.
[42] J. Caro, M. Bülow, M. Derewinski, J. Haber, M. Hunger, J. Kärger, H. Pfeifer, W. Storek, B. Zibrowius, J. Catal., 1990, 124, 367-375.
[43] N. H. Xue, R. Olindo, J. A. Lercher, J. Phys. Chem. C, 2010, 114, 15763-15770.
[44] K. Damodaran, J. W. Wiench, S. M. Cabral de Menezes, Y. M. Lam, J. Trébosc, J. P. Amoureux, M. Pruski, Microporous Mesoporous Ma-ter., 2006, 95, 296-305.
[45] P. M. Bautista, J. M. Campelo, A. Garcia, D. Luna, J. M. Marinas, A. A. Romero, Appl. Catal. A, 1993, 96, 175-199.
[46] T. Sonoda, T. Maruo, Y. Yamasaki, N. Tsunoji, Y. Takamitsu, M. Sadakane, T. Sano, J. Mater. Chem. A, 2015, 3, 857-865.
[47] Y. Nakasaka, J. i. Nishimura, T. Tago, T. Masuda, Chem. Eng. J., 2015, 278, 159-165.
[48] R. Javaid, K. Urata, S. Furukawa, T. Komatsu, Appl. Catal. A, 2015, 491, 100-105.
[49] S. Al-Khattaf, J. A. Atias, K. Jarosch, H. de Lasa, Chem. Eng. Sci., 2002, 57, 4909-4920.