Ceria-modified hierarchical Hβ zeolite as a robust solid acid catalyst for alkenylation of p-xylene with phenylacetylene

doi:10.1016/S1872-2067(17)62985-1

Abstract

Abstract:

A ceria-modified hierarchical Hβ zeolite was prepared by a desilication-dealumination procedure followed by ceria modification. The catalytic performance of the ceria-modified and unmodified hierarchical Hβ zeolite catalysts for alkenylation of p-xylene with phenylacetylene was investigated. Various characterization techniques, including X-ray diffraction, X-ray fluorescence, nitrogen adsorption-desorption, and NH₃ temperature-programmed desorption, were used to examine the structure-performance relationships. Our results show that the optimized ceria-modified hierarchical Hβ zeolite catalyst demonstrated higher catalytic activity, selectivity, and stability for alkenylation of p-xylene with phenylacetylene than those of pristine Hβ zeolite. This performance was attributed to more acidic sites and improved accessibility to active sites through larger pores, together with a higher mesoporous surface area and volume resulting from the hierarchical pore architecture and ceria modification. Thus, our 5 wt% CeO₂-Hβ-B_0.2A_0.2 catalyst shows great potential for producing alkenyl aromatics through solid acid catalyzed alkenylation.

Key words: Hierarchical beta zeolite, Desilication and dealumination, Ceriamodification, Heterogeneous catalysis, Alkenylation

Yongle Guo, Yu Zhang, Zhongkui Zhao. Ceria-modified hierarchical Hβ zeolite as a robust solid acid catalyst for alkenylation of p-xylene with phenylacetylene[J]. Chinese Journal of Catalysis, 2018, 39(1): 181-189.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(17)62985-1

https://www.cjcatal.com/EN/Y2018/V39/I1/181

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