Improving the Hydrothermal Stability of Mesoporous Silica SBA-15 by Pre-treatment with (NH4)2SiF6

doi:10.1016/S1872-2067(10)60283-5

Abstract

Abstract: The hydrothermal stability of the mesoporous silica material SBA-15 was improved by a pre-treatment of 5 mol% ammonium hexafluorosilicate solution with 1 mol% SiO₂ ratio of (NH₄)₂SiF₆ and SBA-15. The modified SBA-15 kept its ordered meso-structure well even when kept under boiling water for 14 d or 100 % H₂O stream at 800 °C for 12 h, and still had BET surface areas as high as 310 and 213 m²/g, respectively, after these treatments. The possible reasons for the stabilization were that the surface defects of SBA-15 were partially repaired by silicon insertion and some silicon hydroxyls were replaced by F^- ions. Larger amounts of ammonium hexafluorosilicate did not give more stabilization.

Key words: hydrothermal stability, ammonium fluorosilicate, SBA-15 zeolite, mesoporous material, silicon insertion, hydrophobization

SONG Ming-Juan, ZOU Cheng-Long, NIU Guo-Xing, ZHAO Dong-Yuan. Improving the Hydrothermal Stability of Mesoporous Silica SBA-15 by Pre-treatment with (NH4)2SiF6[J]. Chinese Journal of Catalysis, 2012, 33(1): 140-151.

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References

1Beck J S, Vartuli J C, Roth W J, Leonowicz M E, Kresge C T, Schmitt K D, Chu C T W, Olson D H, Sheppard E W, McCullen S B, Higgins J B, Schlenker J L. J Am Chem Soc, 1992, 114: 10834
2Kresge C T, Leonowicz M E, Roth W J, Vartuli J C, Beck J S. Nature, 1992, 359: 710
3Zhao D Y, Huo Q S, Feng J L, Chmelka B F, Stucky G D. J Am Chem Soc, 1998, 120: 6024
4Zhao D Y, Feng J L, Huo Q S, Melosh N, Fredrickson G H, Chmelka B F, Stucky G D. Science, 1998, 279: 548
5Bagshaw S A, Prouzet E, Pinnavaia T J. Science, 1995, 269: 1242
6Liu X Y, Tian B Z, Yu C Z, Gao F, Xie S H, Tu B, Che R C, Peng L M, Zhao D Y. Angew Chem, Int Ed, 2002, 41: 3876
7Yu C Z, Tian B Z, Fan B, Stucky G D, Zhao D Y. Chem Commun, 2001: 2726
8Tanev P T, Chibwe M, Pinnavaia T J. Nature, 1994, 368: 321
9Tanev P T, Pinnavaia T J. Science, 1995, 267: 865
10张微, 徐恒泳, 毕亚东, 李文钊. 化工进展 (Zhang W, Xu H Y, Bi Y D, Li W Zh. Chem Ind Eng Progr), 2007, 26: 152
11Ryoo R, Jun S. J Phys Chem B, 1997, 101: 317
12Galarneau A, Nader M, Guenneau F, Renzo F D, Gedeon A. J Phys Chem C, 2007, 111: 8268
13Zhang F Q, Yan Y, Yang H F, Meng Y, Yu C Z, Tu B, Zhao D Y. J Phys Chem B, 2005, 109: 8723
14Han Y, Li N, Zhao L, Li D F, Xu X Z, Wu S, Di Y, Li C J, Zou Y C, Yu Y, Xiao F S. J Phys Chem B, 2003, 107: 7551
15Lai X Y, Tu J C, Wang H, Du J, Yang M, Mao D, Xing C J, Wang D, Li X T. Chem Res Chin Univ, 2009, 25: 773
16On D T, Kaliaguine S. J Am Chem Soc, 2003, 125: 618
17Chen G D, Wang L Z, Lei J Y, Zhang J L. Microporous Mesoporous Mater, 2009, 124: 204
18Li C L, Wang Y Q, Guo Y L, Liu X H, Guo Y, Zhang Z G, Wang Y S, Lu G Z. Chem Mater, 2007, 19: 173
19于善青, 赵瑞玉, 刘晨光. 石油学报 (石油加工)(Yu Sh Q, Zhao R Y, Liu Ch G. Acta Petrol Sin (Petrol Process Sect)), 2004, 20(4): 79
20Selvaraj M, Park D W, Ha C S. Microporous Mesoporous Mater, 2011, 138: 94
21Du Y C, Liu S, Zhang Y L, Nawaz F, Ji Y Y, Xiao F S. Microporous Mesoporous Mater, 2009, 121: 185
22Du Y C, Lan X J, Liu S, Ji Y Y, Zhang Y L, Zhang W P, Xiao F S. Microporous Mesoporous Mater, 2008, 112: 225
23Selvaraj M, Kawi S. Chem Mater, 2007, 19: 509
24Yang D J, Xu Y, Wu D, Sun Y H. J Solid State Chem, 2008, 181: 2401
25Ye F, Dong Z W, Zhang H J. Mater Lett, 2010, 64: 1441
26Song K, Guan J Q, Wang Z Q, Xu C, Kan Q B. Appl Surf Sci, 2009, 255: 5843
27Sun H, Tang Q H, Du Y, Liu X B, Chen Y, Yang Y H. J Colloid Inter Sci, 2009, 333: 317
28Wei J W, Shi J J, Pan H, Su Q F, Zhu J B, Shi Y. Microporous Mesoporous Mater, 2009, 117: 596
29Xia Q H, Hidajat K, Kawi S. Mater Lett, 2000, 42: 102
30Jiang T L, Tao H X, Ren J W, Liu X H, Wang Y Q, Lu G Z. Microporous Mesoporous Mater, 2011, 142: 341
31Chen G D, Wang L Z, Lei J Y, Zhang J L. Microporous Mesoporous Mater, 2009, 124: 204
32Xu M, Wang W, Seiler M, Buchholz A, Hunger M. J Phys Chem B, 2002, 106: 3202
33Chen J H, Li Q H, Xu R R, Xiao F S. Angew Chem, Int Ed, 1995, 34: 2694
34Sindorf D W, Maciel G E. J Phys Chem, 1982, 86: 5208

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