One-step production of C1-C18 alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO2

doi:10.1016/S1872-2067(14)60252-7

Abstract

Abstract:

The promotional effect of SiO₂ on the catalytic synthesis of mixed C₁-C₁₈ alcohols from syngas using the Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts was investigated. X-ray diffraction, H₂ temperature-programmed reduction, pulsed CO chemisorption and N₂ physisorption techniques were all employed to assess the catalyst. Although the addition of SiO₂ decreased the reducibility of the Co component, Co dispersion was significantly increased and its aggregation during reaction was inhibited, resulting in greatly enhanced reaction activity. Appropriate amounts of SiO₂ also promoted the formation of Co₂C, leading to an increased selectivity for C₁-C₁₈ alcohols. More importantly, the addition of SiO₂ favored the formation of higher molecular mass alcohols (C₆-C₁₈) by suppressing Co reduction, thus producing an abundance of Co(II) species capable of facilitating CO insertion.

Key words: Co catalyst, Higher alcohol, SiO₂ promoter, Fischer-Tropsch synthesis, Co₂C

Yanpeng Pei, Yunjie Ding, Hejun Zhu, Hong Du. One-step production of C₁-C₁₈ alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO₂[J]. Chinese Journal of Catalysis, 2015, 36(3): 355-361.

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One-step production of C₁-C₁₈ alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO₂

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