Fischer-Tropsch synthesis: Characterizing and reaction testing of Co2C/SiO2 and Co2C/Al2O3 catalysts

doi:10.1016/S1872-2067(14)60179-0

Abstract

Abstract:

SiO₂- and Al₂O₃-supported Co₂C catalysts were prepared by carburizing supported Co precursors with CO. The catalysts were characterized by N₂ physisorption, X-ray diffraction and H₂ temperature-programmed reduction techniques, and evaluated by the Fischer-Tropsch (F-T) reaction. The results showed that SiO₂- and Al₂O₃-supported Co₂C catalysts could be successfully obtained but sufficient carburization time was required. All of the as-prepared supported Co₂C catalysts exhibited activity and selectivity towards alcohols. It is considered that surface metallic Co species contributed to the activity, surface Co₂C species were responsible for the formation of alcohols, and bulk Co₂C species were inert during the F-T reaction.

Key words: Supported cobalt carbide, Fischer-Tropsch synthesis, Alcohols, Surface sites

Yanpeng Pei, Yunjie Ding, Juan Zang, Xiangen Song, Wenda Dong, Hejun Zhu, Tao Wang, Weimiao Chen. Fischer-Tropsch synthesis: Characterizing and reaction testing of Co₂C/SiO₂ and Co₂C/Al₂O₃ catalysts[J]. Chinese Journal of Catalysis, 2015, 36(2): 252-259.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60179-0

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Fischer-Tropsch synthesis: Characterizing and reaction testing of Co₂C/SiO₂ and Co₂C/Al₂O₃ catalysts

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