Synthesis of α-hydroxy ketones by copper(I)-catalyzed hydration of propargylic alcohols: CO2 as a cocatalyst under atmospheric pressure

doi:10.1016/S1872-2067(19)63313-9

Abstract

Abstract: Inexpensive and efficient Cu(I) catalysis is reported for the synthesis of α-hydroxy ketones from propargylic alcohols, CO₂, and water via tandem carboxylative cyclization and nucleophilic addition reaction. Notably, hydration of propargylic alcohols can be carried out smoothly under atmospheric CO₂ pressure, generating a series of α-hydroxy ketones efficiently and selectively. This strategy shows great potential for the preparation of valuable α-hydroxy ketones by using CO₂ as a crucial cocatalyst under mild conditions.

Key words: Copper catalysis, Propargylic alcohols, Hydration, α-Hydroxy ketones, Carbon dioxide, Cocatalyst

Zhi-Hua Zhou, Xiao Zhang, Yong-Fu Huang, Kai-Hong Chen, Liang-Nian He. Synthesis of α-hydroxy ketones by copper(I)-catalyzed hydration of propargylic alcohols: CO₂ as a cocatalyst under atmospheric pressure[J]. Chinese Journal of Catalysis, 2019, 40(9): 1345-1351.

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Synthesis of α-hydroxy ketones by copper(I)-catalyzed hydration of propargylic alcohols: CO₂ as a cocatalyst under atmospheric pressure

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