Synthesis and characterization of Si/Ga Eni Carbon Silicates

doi:10.1016/S1872-2067(14)60296-5

Abstract

Abstract:

Phenylene-gallosilicates were prepared with the same crystalline structure as their aluminum analogues. The new Ga-Eni Carbon Silicates (Ga-ECS) phases were investigated by X-ray diffraction, scanning electron microscopy, nuclear magnetic resonance and thermogravimetric analysis, which demonstrated that gallium isomorphously replaced aluminum in the framework of the organic-inorganic hybrids similar to the case of classical zeolites. Hybrid ECS materials were obtained with different types of bridged silsesquioxane precursors that maintained the aluminum-silicate nature of the inorganic moiety. This work confirms a new level of crystal chemistry versatility for this class of materials, and demonstrates the possibility to tailor also the inorganic part of the framework by changing the nature of the trivalent heteroatom.

Key words: Eni Carbon Silicates, Hybrid organic-inorganic gallosilicates, Bridged silsesquioxane precursors, Isomorphous substitution

Giuseppe Bellussi, Angela Carati, Stefania Guidetti, Caterina Rizzo, Roberto Millini, Stefano Zanardi, Erica Montanari, Wallace O'Neil Parker Jr., Michela Bellettato. Synthesis and characterization of Si/Ga Eni Carbon Silicates[J]. Chinese Journal of Catalysis, 2015, 36(6): 813-819.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60296-5

https://www.cjcatal.com/EN/Y2015/V36/I6/813

References

[1] Čejka J, Centi G, Perez-Pariente J, Roth W J. Catal Today, 2012, 179: 2
[2] Bellussi G, Carati A, Rizzo C, Millini R. Catal Sci Technol, 2013, 3: 833
[3] Díaz U, Brunel D, Corma A. Chem Soc Rev, 2013, 42: 4083
[4] Sánchez C, Ribot F. New J Chem, 1994, 18: 1007
[5] Stein A, Melde B J, Schroder R C. Adv Mater, 2000, 12: 1403
[6] Eddaoudi M, Moler D B, Li H, Chen B, Reineke T M, O'Keeffe M, Yaghi O M. Acc Chem Res, 2001, 34: 319
[7] Wight A P, Davis M E. Chem Rev, 2002, 102: 3589
[8] Hoffmann F, Cornelius M, Morel J, Fröba M. Angew Chem Int Ed, 2006, 45: 3216
[9] Hoffmann F, Fröba M. Chem Soc Rev, 2011, 40: 608
[10] Corma A, Iglesias M, del Pino C, Sanchez F. J Chem Soc, Chem Commun, 1991: 1253
[11] Cauvel A, Brunel D, Di Renzo F, Moreau P, Fajula F. Stud Surf Sci Catal, 1994, 94: 286
[12] Jones C W, Tsuji K, Davis M E. Nature, 1998, 393: 52
[13] Tsuji K, Jones C W, Davis M E. Microporous Mesoporous Mater, 1999, 29: 339
[14] Jones C W, Tsuji K, Davis M E. Microporous Mesoporous Mater, 1999, 33: 223
[15] Jones C W, Tsuji K, Davis M E. Microporous Mesoporous Mater, 2001 42: 21
[16] Roth W J, Nachtigall P, Morris R E, Čejka J. Chem Rev, 2014, 144: 4807
[17] Corma A, Diaz U, Garcia T, Sastre G, Velty A. J Am Chem Soc, 2010, 132: 15011
[18] Opanasenko M, Parker W O Jr, Shamzhy M, Montanari E, Bellettato M, Mazur M, Millini R, Čejka J. J Am Chem Soc, 2014, 136: 2511
[19] Yamamoto K, Sakata Y, Nohara Y, Takahashi Y, Tatsumi T. Science, 2003, 300: 470
[20] Yamamoto K, Nohara Y, Domon Y, Takahashi Y, Sakata Y, Plévert J, Tatsumi T. Chem Mater, 2005, 17: 3913
[21] Yamamoto K, Tatsumi T. Chem Mater, 2008, 20: 972
[22] Díaz U, Vidal-Moya J A, Corma A. Microporous Mesoporous Mater, 2006, 93: 180
[23] Su B L, Roussel M, Vause K, Yang X Y, Gilles F, Shi L, Leonova E, Edén M, Zou X. Microporous Mesoporous Mater, 2007, 105: 49
[24] Zhou D, Lu X, Xu J, Yu A, Li J, Deng F, Xia Q. Chem Mater, 2012, 24: 4160
[25] Bellussi G, Carati A, Di Paola E, Millini R, Parker W O Jr, Rizzo C, Zanardi S. Microporous Mesoporous Mater, 2008, 113: 252
[26] Bellussi G, Montanari E, Di Paola E, Millini R, Carati A, Rizzo C, Parker W O Jr, Gemmi M, Mugnaioli E, Kolb U, Zanardi S. Angew Chem Int Ed, 2012, 51: 666
[27] Bellettato M, Bonoldi L, Cruciani G, Flego C, Guidetti S, Millini R, Montanari E, Parker W O Jr, Zanardi S. J Phys Chem C, 2014, 118: 7458
[28] Millini R, Perego G, Bellussi G. Top Catal, 1999, 9: 13
[29] Bellussi G, Millini R, Montanari E, Carati A, Rizzo C, Parker W O Jr, Cruciani G, de Angelis A, Bonoldi L, Zanardi S. Chem Commun, 2012, 48: 7356
[30] Zanardi S, Bellussi G, Parker W O Jr, Montanari E, Bellettato M, Cruciani G, Carati A, Guidetti S, Rizzo C, Millini R. Dalton Trans, 2014, 43: 10617
[31] Macario A, Aloise A, Giordano G, Nagy J. 7th Int Symp on Acid-Base Catalysis, Tokyo (J), May 12-15, 2013
[32] Goldsmith J R. Mineral Mag, J Miner Soc, 1952, 29: 952
[33] Newsam J M, Vaughan D E W. Stud Surf Sci Catal, 1986, 28: 457
[34] Weitkamp J, Puppe L. Catalysis and Zeolites: Fundamentals and Applications, 1999. 228
[35] Fricke R, Kosslick H, Lischke G, Richter M. Chem Rev, 2000, 100: 2303
[36] Larson A C, Von Dreele R B, Los Alamos National Laboratory Report LAUR, 1994, 86: 748
[37] Toby B H. J Appl Crystallogr, 2001, 34: 210
[38] Bendall M R, Pegg D T. Magn Reson Med, 1985, 2(2): 91
[39] Thomas J M, Klinowski J, Ramdas S, Hunter B K, Tennakoon D T B. Chem Phys Lett, 1983, 102: 158
[40] Zanardi S, Parker W O Jr, Carati A, Botti G, Montanari E. Microporous Mesoporous Mater, 2013, 172: 200
[41] Baur W H. J Solid State Chem, 1992, 97: 243
[42] Cruciani G. J Phys Chem Solids, 2006, 67: 1973