One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts

doi:10.1016/S1872-2067(14)60287-4

Abstract

Abstract:

The one-pot synthesis of 5-hydroxymethylfurfural (5-HMF) from glucose was investigated, using [Sn,Al]-Beta catalysts prepared by a combination of partial dealumination and isomorphous substitution of Sn into the zeolite framework. The amount of Al in [Sn,Al]-Beta was adjusted by changing the concentration and acid treatment time, and the Sn content was varied by changing the SnCl₄ vapor treatment time. [Sn,Al]-Beta contains framework Al-related Brönsted acid sites and tetrahedral Sn-related Lewis acid sites, and is therefore a bifunctional solid acid catalyst. The reaction parameters for the [Sn,Al]-Beta-catalyzed one-pot conversion of glucose to 5-HMF were optimized. [Sn,Al]-Beta with a suitable Sn/Al molar ratio gave a glucose conversion of 60.0% and 5-HMF selectivity of 62.1%.

Key words: [Sn,Al]-Beta, Aldose-Ketose Isomerization, Bifunctional Catalysis, Hydroxymethyl furfural, Biomass, Isomorphous substitution

Liang Li, Jianghong Ding, Jin-Gang Jiang, Zhiguo Zhu, Peng Wu. One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts[J]. Chinese Journal of Catalysis, 2015, 36(6): 820-828.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60287-4

https://www.cjcatal.com/EN/Y2015/V36/I6/820

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