Ethylbenzene to styrene over ZrO2-based mixed metal oxide catalysts with CO2 as soft oxidant

doi:10.1016/S1872-2067(15)60901-9

Abstract

Abstract:

ZrO₂-based mixed metal oxide catalysts for the industrially important dehydrogenation process of ethylbenzene to styrene monomer have been explored by our group for the past 20 years. These efforts were subjected to the activation of CO₂ over mixed metal oxide catalysts and resulted in several promising benefits to the dehydrogenation processes, such as stabilized conversion and selectivity, suppressed coke formation and commercially-acceptable longevity. In this review, we summarize the most recent developments on ZrO₂-based mixed metal oxide catalysts, including the further optimization of sol-gel process in the synthesis of catalysts, rationalizing acid-base properties by doping, co-operative properties between redox and acid-base active sites and additional promoters towards the effective improvement of the longevity of catalysts.

Key words: Oxidative dehydrogenation, Carbon dioxide activation, Zirconia-based mixed oxide, Acid-base properties, Redox properties

Nanzhe Jiang, Abhishek Burri, Sang-Eon Park. Ethylbenzene to styrene over ZrO₂-based mixed metal oxide catalysts with CO₂ as soft oxidant[J]. Chinese Journal of Catalysis, 2016, 37(1): 3-15.

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Ethylbenzene to styrene over ZrO₂-based mixed metal oxide catalysts with CO₂ as soft oxidant

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