Catalytic oxidative dehydrogenation of n-butane over V2O5/MO-Al2O3 (M = Mg, Ca, Sr, Ba) catalysts

doi:10.1016/S1872-2067(15)60839-7

Abstract

Abstract:

V₂O₅/MO-Al₂O₃ (M = Mg, Ca, Sr, Ba) catalysts with different V₂O₅ loading were prepared by impregnation with ammonium metavanadate as the V precursor and characterized and tested for the selectively oxidative dehydrogenation of n-butane to butenes. Characterization by BET, XRD, FTIR, H₂-TPR and Raman spectra showed that the catalysts doped with different alkaline earth metals had different structure and catalytic activity. The catalysts doped with Ca, Sr or Ba had the orthovanadate phase that was difficult to reduce, so their redox cycles could not be established and they exhibited low activity. The catalysts doped with Mg showed high catalytic activity and selectivity. The catalyst with 5% V₂O₅ loading exhibited the highest n-butane conversion (30.3%) and total butene selectivity (64.3%) at 600 ℃. This was due to the well dispersed VO_x species and the existence of the MgO crystalline phase, which were both present at a V₂O₅ loading of 5%.

Key words: Oxidative dehydrogenation, n-Butane, Butene, Magnesia, Alumina, Vanadium catalyst

Bing Xu, Xuefeng Zhu, Zhongwei Cao, Lina Yang, Weishen Yang . Catalytic oxidative dehydrogenation of n-butane over V₂O₅/MO-Al₂O₃ (M = Mg, Ca, Sr, Ba) catalysts[J]. Chinese Journal of Catalysis, 2015, 36(7): 1060-1067.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)60839-7

https://www.cjcatal.com/EN/Y2015/V36/I7/1060

References

[1] Al-Ghamdi S A, de Lasa H I. Fuel, 2014, 128: 120
[2] Wittcoff H A. CHEMTECH, 1990, 20: 48
[3] Madeira L M, Portela M F. Catal Rev Sci Eng, 2002, 44: 247
[4] Téllez C, Abon M, Dalmon J A, Mirodatos C, Santamarıá J. J Catal, 2000, 195: 113
[5] Mamedov E A, Corberán V C. Appl Catal A, 1995, 127: 1
[6] Blasco T, Nieto J M L. Appl Catal A, 1997, 157: 117
[7] Khodakov A, Olthof B, Bell A T, Iglesia E. J Catal, 1999, 181: 205
[8] Banares M A, Khatib S J. Catal Today, 2004, 96: 251
[9] Martinez-Huerta M V, Gao X, Tian H, Wachs I E, Fierro J L G, Banares M A. Catal Today, 2006, 118: 279
[10] Banares M A. Catal Today, 1999, 51: 319
[11] Wachs I E, Weckhuysen B M. Appl Catal A, 1997, 157: 67
[12] Enache D I, Bordes-Richard E, Ensuque A, Bozon-Verduraz F. Appl Catal A, 2004, 278: 93
[13] Yuan R X, Li Y, Yan H B, Wang H, Song J, Zhang Z S, Fan W B, Chen J G, Liu Z W, Liu Z T, Hao Z P. Chin J Catal (袁瑞雪, 李杨, 闫浩兵, 王欢, 宋健, 张中申, 樊卫斌, 陈建刚, 刘忠文, 刘昭铁, 郝郑平. 催化学报), 2014, 35: 1329
[14] Sun G S, Huang Q Z, Li H Q, Liu H T, Zhang Z, Wang X R, Wang Q P, Wang J S. Chin J Catal (孙果宋, 黄青则, 李会泉, 柳海涛, 张钊, 王兴瑞, 王秋萍, 王金淑. 催化学报), 2011, 32: 1424
[15] Lee J K, Lee H, Hong U G, Yoo Y, Cho Y-J, Lee J, Chang H, Song I K. J Ind Eng Chem, 2012, 18: 1758
[16] López Nieto J M. Top Catal, 2006, 41: 3
[17] Harlin M E, Niemi V M, Krause A O I. J Catal, 2000, 195: 67
[18] Ishida S, Imamura S, Fujimura Y. React Kinet Catal Lett, 1991, 43: 453
[19] Zou H, Li M, Shen J, Auroux A. J Therm Anal Calorim, 2003, 72: 209
[20] Deo G, Wachs I E. J Catal, 1994, 146: 323
[21] Michalakos P M, Kung M C, Jahan I, Kung H. J Catal, 1993, 140: 226
[22] Kijima N, Toba M, Yoshimura Y. Catal Lett, 2009, 127: 63
[23] Wang Y, Xie S H, Yue B, Feng S J, He H Y. Chin J Catal (汪玉, 谢颂海, 岳斌, 冯素姣, 贺鹤勇. 催化学报), 2010, 31: 1054
[24] Abdollahifar M. J Chem Res, 2014, 38: 154
[25] Liu Y F, Wang X P, Tian F P, Yia C Y. Chin J Catal (刘尧飞, 王新平, 田福平, 贾翠英. 催化学报), 2004, 25: 721
[26] Barrera A, Muramatsu K, Viveros T, Gomez S, Montoya J A, del Angel P, Perez G, Campa Molina J. Appl Clay Sci, 2009, 42: 415
[27] Fu X Y, Niu S Y, Zhang H W, Xin Q. Spectrosc Spect Anal (付晓燕, 牛淑云, 张洪武, 辛勤. 光谱学与光谱分析), 2006, 26: 27
[28] Wang H, Liu J Y, Yan W Q, Kang M, Sun R, Chen C. J Synth Cryst (王浩, 刘君玉, 燕文清, 康明, 孙蓉, 陈超. 人工晶体学报), 2011, 40: 1209
[29] Han B, Li M J, Li C. Chin J Light Scatter (韩波, 李美俊, 李灿. 光散射学报), 2002, 14: 82
[30] Wang X J, Fei Y J, Xiong Y Y, Nie Y X, Feng K A. Chin J Light Scatter (王学进, 费允杰, 熊艳云, 聂玉昕, 冯克安. 光散射学报), 2002, 13: 235
[31] Liu J, Zhao Z, Xu C M, Duan A J, Jiang G Y, Gao J S, Lin W Y, Wachs I E. Sci China Ser B (刘坚, 赵震, 徐春明, 段爱军, 姜桂元, 高金森, Lin W Y, Wachs I E. 中国科学B辑), 2008, 38: 238
[32] Lemonidou A A, Tjatjopoulos G J, Vasalos I A. Catal Today, 1998, 45: 65
[33] Mattos A, San Gil R a D, Rocco M L M, Eon J G. J Mol Catal A, 2002, 178: 229
[34] Schwarz O, Frank B, Hess C, Schomäcker R. Catal Commun, 2008, 9: 229
[35] Heracleous E, Machli M, Lemonidou A A, Vasalos I A. J Mol Catal A, 2005, 232: 29
[36] Rubio O, Herguido J, Menéndez M. Chem Eng Sci, 2003, 58: 4619
[37] Liu R, Wang X P, Jia C Y, Shi W. Chin J Catal (刘睿, 王新平, 贾翠英, 施维. 催化学报), 2005, 26: 650
[38] Rubio O, Herguido J, Menéndez M, Grasa G, Abanades J C. AIChE J, 2004, 50: 1510
[39] Dejoz A, López Nieto J M, Márquez F, Vázquez M I. Appl Catal A, 1999, 180: 83
[40] Setnička M, Bulánek R, Čapek L, Čičmanec P. J Mol Catal A, 2011, 344: 1

Catalytic oxidative dehydrogenation of n-butane over V₂O₅/MO-Al₂O₃ (M = Mg, Ca, Sr, Ba) catalysts

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Hao Tian, Bingjun Xu. Oxidative co-dehydrogenation of ethane and propane over h-BN as an effective means for C-H bond activation and mechanistic investigations [J]. Chinese Journal of Catalysis, 2022, 43(8): 2173-2182.
[2]	Li Ren, Bowen Wang, Kun Lu, Rusi Peng, Yejun Guan, Jin-gang Jiang, Hao Xu, Peng Wu. Selective conversion of methanol to propylene over highly dealuminated mordenite: Al location and crystal morphology effects [J]. Chinese Journal of Catalysis, 2021, 42(7): 1147-1159.
[3]	Jinghua Xu, Ruifeng Wang, Yaru Zhang, Lin Li, Wenjun Yan, Junying Wang, Guodong Liu, Xiong Su, Yanqiang Huang, Tao Zhang. Identification of the structure of Ni active sites for ethylene oligomerization on an amorphous silica-alumina supported nickel catalyst [J]. Chinese Journal of Catalysis, 2021, 42(12): 2181-2188.
[4]	Bing Yan, Wen-Duo Lu, Jian Sheng, Wen-Cui Li, Ding Ding, An-Hui Lu. Electrospinning synthesis of porous boron-doped silica nanofibers for oxidative dehydrogenation of light alkanes [J]. Chinese Journal of Catalysis, 2021, 42(10): 1782-1789.
[5]	Rao Lu, Lei He, Yang Wang, Xin-Qian Gao, Wen-Cui Li. Promotion effects of nickel-doped Al₂O₃-nanosheet-supported Au catalysts for CO oxidation [J]. Chinese Journal of Catalysis, 2020, 41(2): 350-356.
[6]	Wen-Duo Lu, Xin-Qian Gao, Quan-Gao Wang, Wen-Cui Li, Zhen-Chao Zhao, Dong-Qi Wang, An-Hui Lu. Ordered macroporous boron phosphate crystals as metal-free catalysts for the oxidative dehydrogenation of propane [J]. Chinese Journal of Catalysis, 2020, 41(12): 1837-1845.
[7]	Kaimin Du, Mengjia Hao, Zhinian Li, Wei Hong, Juanjuan Liu, Liping Xiao, Shihui Zou, Hisayoshi Kobayashi, Jie Fan. Tuning catalytic selectivity of propane oxidative dehydrogenation via surface polymeric phosphate modification on nickel oxide nanoparticles [J]. Chinese Journal of Catalysis, 2019, 40(7): 1057-1062.
[8]	Xin-Qian Gao, Wen-Duo Lu, Shou-Zhao Hu, Wen-Cui Li, An-Hui Lu. Rod-shaped porous alumina-supported Cr₂O₃ catalyst with low acidity for propane dehydrogenation [J]. Chinese Journal of Catalysis, 2019, 40(2): 184-191.
[9]	Nagaraju Pasupulety, Muhammad A. Daous, Abdulrahim A. Al-Zahrani, Hafedh Driss, Lachezar A. Petrov. Alumina-boron catalysts for oxidative dehydrogenation of ethylbenzene to styrene: Influence of alumina-boron composition and method of preparation on catalysts properties [J]. Chinese Journal of Catalysis, 2019, 40(11): 1758-1765.
[10]	Christian Ahoba-Sam, Marius Westgard Erichsen, Unni Olsbye. Ethene and butene oligomerization over isostructural H-SAPO-5 and H-SSZ-24: Kinetics and mechanism [J]. Chinese Journal of Catalysis, 2019, 40(11): 1766-1777.
[11]	Chang Huang, Zhi-Qiang Wang, Xue-Qing Gong. Activity and selectivity of propane oxidative dehydrogenation over VO₃/CeO₂(111) catalysts: A density functional theory study [J]. Chinese Journal of Catalysis, 2018, 39(9): 1520-1526.
[12]	Lei Shi, Dongqi Wang, Anhui Lu. A viewpoint on catalytic origin of boron nitride in oxidative dehydrogenation of light alkanes [J]. Chinese Journal of Catalysis, 2018, 39(5): 908-913.
[13]	Hongmei Ai, Hongyuan Yang, Qing Liu, Guoming Zhao, Jing Yang, Fangna Gu. ZrO₂-modified Ni/LaAl₁₁O₁₈ catalyst for CO methanation:Effects of catalyst structure on catalytic performance [J]. Chinese Journal of Catalysis, 2018, 39(2): 297-308.
[14]	Svetlana A. Yashnik, Vadim V. Kuznetsov, Zinfer R. Ismagilov. Effect of χ-alumina addition on H₂S oxidation properties of pure and modified γ-alumina [J]. Chinese Journal of Catalysis, 2018, 39(2): 258-274.
[15]	CeGuo, Xiujie Li, Xiangxue Zhu, Weifeng Chu, Shenglin Liu, Yuzhong Wang, Peng Zeng, Shujing Guo, Longya Xu. Self-metathesis of 1-butene to ethene and hexene over molybdenum-based heterogeneous catalysts [J]. Chinese Journal of Catalysis, 2018, 39(1): 37-46.