Effect of χ-alumina addition on H2S oxidation properties of pure and modified γ-alumina

doi:10.1016/S1872-2067(18)63016-5

Abstract

Abstract:

The influence of the textural and acidic properties of γ-Al₂O₃, (γ+χ)-Al₂O₃, and α-Al₂O₃ on the catalytic activity, selectivity, and stability of direct H₂S oxidation has been studied. A comparison of the H₂S-to-S conversion effectiveness of aluminas with their acidic properties (identified by Fourier transform infrared spectroscopy and temperature programmed desorption of NH₃) shows that H₂S adsorption occurs predominantly on weak Lewis acid sites (LAS). γ-Alumina samples containing a χ-phase and/or modified Mg²⁺ ions have a greater concentration of weak LAS and exhibit greater catalytic activity. When alumina is treated with a sulfuric acid solution, strong LAS appear and the number of LAS decreases significantly. Modification of alumina with hydrochloric acid has a limited effect on LAS strength. Weak LAS are retained and double in number compared to that present in the unmodified alumina, but the treated sample has Al-Cl bonds. Alumina samples modified by sulfate and chloride anions exhibit poor catalytic activity in H₂S oxidation.

Key words: Alumina, χ-Al₂O₃, Hydrogen sulfide oxidation, Acidic property, Lewis acid sites, Fourier transform infrared spectroscopy, NH₃-temperature programmed desorption

Svetlana A. Yashnik, Vadim V. Kuznetsov, Zinfer R. Ismagilov. Effect of χ-alumina addition on H₂S oxidation properties of pure and modified γ-alumina[J]. Chinese Journal of Catalysis, 2018, 39(2): 258-274.

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Effect of χ-alumina addition on H₂S oxidation properties of pure and modified γ-alumina

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