Ni-based catalysts derived from a metal-organic framework for selective oxidation of alkanes

doi:10.1016/S1872-2067(15)61067-1

Abstract

Abstract:

Ni nanoparticles embedded in nitrogen-doped carbon (Ni@C-N) materials were prepared by thermolysis of a Ni-containing metal-organic framework (Ni-MOF) under inert atmosphere. The as-synthesized Ni@C-N materials were characterized by powder X-ray diffraction, N₂ adsorption-desorption analysis, scanning electron microscopy, transmission electron microscopy, atomic absorption spectroscopy, and X-ray photoelectron spectroscopy. The MOF-derived Ni-based materials were then examined as heterogeneous catalysts for the oxidation of alkanes under mild reaction conditions. The Ni@C-N composites displayed high activity and selectivity toward the oxidation of a variety of saturated C-H bonds, affording the corresponding oxidation products in good-to-excellent yields. Furthermore, the catalysts could be recycled and reused for at least four times without any significant loss in activity and selectivity under the investigated conditions.

Key words: Nickel, Nanoparticle, Metal-organic framework, Alkane, Oxidation, Heterogeneous catalysis

Ying Zhou, Jilan Long, Yingwei Li. Ni-based catalysts derived from a metal-organic framework for selective oxidation of alkanes[J]. Chinese Journal of Catalysis, 2016, 37(6): 955-962.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61067-1

https://www.cjcatal.com/EN/Y2016/V37/I6/955

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