Direct oxidation of the Csp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst

doi:10.1016/S1872-2067(16)62503-2

Abstract

Abstract:

Novel reusable MnO_x-N@C catalyst has been developed for the direct oxidation of N-heterocycles under solvent-free conditions using TBHP as benign oxidant to give the corresponding N-heterocyclic ketones. The catalytic system exhibited a broad substrate scope and excellent regioselectivity, as well as being amenable to gram-scale synthesis. This MnO_x-N@C catalyst also showed good reusability and was successfully recycled six times without any significant loss of activity.

Key words: Oxidation, Heterogeneous catalyst, Ketone, C-H bond, Manganese

Lanhui Ren, Lianyue Wang, Ying Lü, Guosong Li, Shuang Gao. Direct oxidation of the C_sp₃-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnO_x-N@C catalyst[J]. Chinese Journal of Catalysis, 2016, 37(8): 1216-1221.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(16)62503-2

https://www.cjcatal.com/EN/Y2016/V37/I8/1216

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Direct oxidation of the C_sp₃-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnO_x-N@C catalyst

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