Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2

doi:10.1016/S1872-2067(16)62504-4

Abstract

Abstract:

We present an efficient approach for the chemoselective synthesis of arylamines from nitroarenes and formate over an oxygen-implanted MoS₂ catalyst(O-MoS₂). O-MoS₂ was prepared by incomplete sulfiidation and reduction of an ammonium molybdate precursor. A number of Mo-O bonds were implanted in the as-synthesized ultrathin O-MoS₂ nanosheets. As a consequence of the different coordination geometries of O(MoO2) and S(MoS₂), and lengths of the Mo-O and Mo-S bonds, the implanted Mo-O bonds induced obvious defects and more coordinatively unsaturated(CUS) Mo sites in O-MoS₂, as confirmed by X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, high resolution transmission electron microscopy, and extended X-ray absorption fine structure characterization of various MoS₂-based materials. O-MoS₂ with abundant CUS Mo sites was found to efficiently catalyze the chemoselective reduction of nitroarenes to arylamines.

Key words: MoS₂, Coordinative unsaturated Mo, Nitroarene, Transfer hydrogenation, Formate, Heterogeneous catalysis

Chaofeng Zhang, Xu Wang, Mingrun Li, Zhixin Zhang, Yehong Wang, Rui Si, Feng Wang. Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS₂[J]. Chinese Journal of Catalysis, 2016, 37(9): 1569-1578.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(16)62504-4

https://www.cjcatal.com/EN/Y2016/V37/I9/1569

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Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS₂

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