Vanadium supported on graphitic carbon nitride as a heterogeneous catalyst for the direct oxidation of benzene to phenol

doi:10.1016/S1872-2067(16)62496-8

Abstract

Abstract:

A series of graphitic carbon nitride supported vanadium catalysts (xV/g-C₃N₄) with different vana-dium contents (x/%) were prepared by impregnation. XRD, FT-IR, TEM, TG-DTG, nitrogen adsorp-tion and XPS characterizations were conducted which revealed a strong interaction between the vanadium species and g-C₃N₄ support. 8V/g-C₃N₄ exhibited the highest activity and showed stable recyclability in the benzene hydroxylation reaction with a benzene conversion of 24.6% and phenol selectivity of 99.2% under the optimized conditions. The excellent catalytic performance of xV/g-C₃N₄ was due to the integration of vanadium species with high catalytic activity and the g-C₃N₄ support in their interaction with the benzene substrate.

Key words: Carbon nitride, Vanadium, Benzene hydroxylation, Phenol, Impregnation

Cheng Wang, Liya Hu, Meiyin Wang, Yuanhang Ren, Bin Yue, Heyong He. Vanadium supported on graphitic carbon nitride as a heterogeneous catalyst for the direct oxidation of benzene to phenol[J]. Chinese Journal of Catalysis, 2016, 37(11): 2003-2008.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(16)62496-8

https://www.cjcatal.com/EN/Y2016/V37/I11/2003

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