Ru/FeOx catalyst performance design: Highly dispersed Ru species for selective carbon dioxide hydrogenation

doi:10.1016/S1872-2067(17)62967-X

Chinese Journal of Catalysis ›› 2018, Vol. 39 ›› Issue (1): 157-166.DOI: 10.1016/S1872-2067(17)62967-X

• Articles • Previous Articles Next Articles

Ru/FeO_x catalyst performance design: Highly dispersed Ru species for selective carbon dioxide hydrogenation

Di Zhang^a,b, Jingjie Luo^b, Jiajie Wang^a, Xin Xiao^a, Yuefeng Liu^c, Wei Qi^b, Dang Sheng Su^b,c, Wei Chu^a

a Department of Chemical Engineering, & Institute of New Energy and Low Carbon Technology, Sichuan University, Chengdu 610065, Sichuang, China;
b Shenyang National Laboratory for Materials Science(SYNL), Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, Liaoning, China;
c Dalian National Laboratory for Clean Energy(DNL), Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received:2017-09-20 Revised:2017-11-01 Online:2018-01-18 Published:2018-01-19
Contact: 10.1016/S1872-2067(17)62967-X
Supported by:
This work was supported by the National Natural Science Foundation of China (21476145, 91645117) and China Postdoctoral Science Foundation (2016M600221).

Abstract

Abstract:

A series of Ru/FeO_x catalysts were synthesized for the selective hydrogenation of CO₂ to CO. Detailed characterizations of the catalysts through X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and temperature-programmed techniques were performed to directly monitor the surface chemical properties and the catalytic performance to elucidate the reaction mechanism. Highly dispersed Ru species were observed on the surface of FeO_x regardless of the initial Ru loading. Varying the Ru loading resulted in changes to the Ru coverage over the FeO_x surface, which had a significant impact on the interaction between Ru and adsorbed H, and concomitantly, the H₂ activation capacity via the ability for H₂ dissociation. FeO_x having 0.01% of Ru loading exhibited 100% selectivity toward CO resulting from the very strong interaction between Ru and adsorbed H, which limits the desorption of the activated H species and hinders over-reduction of CO to CH₄. Further increasing the Ru loading of the catalysts to above 0.01% resulted in the adsorbed H to be easily dissociated, as a result of a weaker interaction with Ru, which allowed excessive CO reduction to produce CH₄. Understanding how to selectively design the catalyst by tuning the initial loading of the active phase has broader implications on the design of supported metal catalysts toward preparing liquid fuels from CO₂.

Key words: Highly dispersed Ru/FeO_x catalyst, Temperature-programmed surface reaction, CO₂ selective hydrogenation, Product selectivity, Hydrogen adsorption

Di Zhang, Jingjie Luo, Jiajie Wang, Xin Xiao, Yuefeng Liu, Wei Qi, Dang Sheng Su, Wei Chu. Ru/FeO_x catalyst performance design: Highly dispersed Ru species for selective carbon dioxide hydrogenation[J]. Chinese Journal of Catalysis, 2018, 39(1): 157-166.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(17)62967-X

https://www.cjcatal.com/EN/Y2018/V39/I1/157

References

[1] T. R. Knutson, R. E. Tuleya, J. Climate, 2004, 17, 3477-3495.
[2] J. D. Shakun, P. U. Clark, F. He, S. A. Marcott, A. C. Mix, Z. Liu, B. Otto-Bliesner, A. Schmittner, E. Bard, Nature, 2012, 484, 49-54.
[3] X. F. Yang, S. Kattel, S. D. Senanayake, J. A. Boscoboinik, X. Nie, J. Graciani, J. A. Rodriguez, P. Liu, D. J. Stacchiola, J. G. Chen, J. Am. Chem. Soc., 2015, 137, 10104-10107.
[4] W. Chu, L. N. Wang, P. A. Chernavskii, A. Y. Khodakov, Angew. Chem. Int. Ed., 2008, 47, 5052-5055.
[5] X. Chen, J. H. Jin, G. Y. Sha, C. Li, B. S. Zhang, D. S. Su, C. T. Williams, C. H. Liang, Catal. Sci. Technol., 2014, 4, 53-61.
[6] X. D. Chen, X. Su, H. Y. Su, X. Y. Liu, S. Miao, Y. H. Zhao, K. J. Sun, Y. Q. Huang, T. Zhang, ACS Catal., 2017, 7, 4613-4620.
[7] A. S. Hall, Y. Yoon, A. Wuttig, Y. Surendranath, J. Am. Chem. Soc., 2015, 137, 14834-14837.
[8] L. F. Liotta, G. A. Martin, G. Deganello, J. Catal., 1996, 164, 322-333.
[9] H. H. Nijs, P. A. Jacobs, J. Catal., 1980, 66, 401-411.
[10] M. P. Andersson, F. Abild-Pedersen, I. N. Remediakis, T. Bligaard, G. Jones, J. Engbwk, O. Lytken, S. Horch, J. H. Nielsen, J. Sehested, J. R. Rostrup-Nielsen, J. K. Norskov, I. Chorkendorff, J. Catal., 2008, 255, 6-19.
[11] F. Wang, S. He, H. Chen, B. Wang, L. R. Zheng, M. Wei, D. G. Evans, X. Duan, J. Am. Chem. Soc., 2016, 138, 6298-6305.
[12] W. Lin, K. M. Stocker, G. C. Schatz, J. Am. Chem. Soc., 2017, 139, 4663.
[13] Y. F. Liu, J. J. Luo, Y. Shin, S. Moldovan, O. Ersen, A. Hébraud, G. Schlatter, C. Pham-Huu, C. Meny, Nat. Commun., 2016, 7, 11532.
[14] X. D. Chen, X. Su, H. M. Duan, B. L. Liang, Y. Q. Huang, T. Zhang, Catal. Today, 2017, 281, 312-318.
[15] S. W. Li, Y. Xu, Y. F. Chen, W. Z. Li, L. L. Lin, M. Z. Li, Y. C. Deng, X. P. Wang, B. H. Ge, C. Yang, S. Y. Yao, J. L. Xie, Y. W. Li, X. Liu, D. Ma, Angew. Chem. Int. Ed., 2017, 56, 10761-10765.
[16] J. H. Kwak, L. Kovarik, J. Szanyi, ACS Catal., 2013, 3, 2094-2100.
[17] M. D. Porosoff, J. G. Chen, J. Catal., 2013, 301, 30-37.
[18] X. Wang, H. Shi, J. H. Kwak, J. Szanyi, ACS Catal., 2015, 5, 6337-6349.
[19] P. A. U. Aldana, F. Ocampo, K. Kobl, B. Louis, F. Thibault-Starzyk, M. Daturi, P. Bazin, S. Thomas, A. C. Roger, Catal. Today, 2013, 215, 201-207.
[20] B. T. Qiao, A. Q. Wang, X. F. Yang, L. F. Allard, Z. Jiang, Y. T. Cui, J. Y. Liu, J. Li, T. Zhang, Nat. Chem., 2011, 3, 634-641.
[21] P. J. Lunde, F. L. Kester, J. Catal., 1973, 30, 423-429.
[22] A. Kim, C. Sanchez, G. Patriarche, O. Ersen, S. Moldovan, A. Wisnet, C. Sassoye, D. P. Debecker, Catal. Sci. Technol., 2016, 6, 8117-8128.
[23] J. H. Xu, X. Su, H. M. Duan, B. L. Hou, Q. Q. Lin, X. Y. Liu, X. L. Pan, G. X. Pei, H. R. Geng, Y. Q. Huang, T. Zhang, J. Catal., 2016, 333, 227-237.
[24] X. Wang, Y. C. Hong, H. Shi, J. Szanyi, J. Catal., 2016, 343, 185-195.
[25] J. Lin, A. Q. Wang, B. T. Qiao, X. Y. Liu, X. F. Yang, X. D. Wang, J. X. Liang, J. Li, J. Y. Liu, T. Zhang, J. Am. Chem. Soc., 2013, 135, 15314-15317.
[26] S. Tada, R. Kikuchi, Catal. Sci. Technol., 2015, 5, 3061-3070.
[27] J. Y. Ye, C. J. Liu, D. H. Mei, Q. F. Ge, ACS Catal., 2013, 3, 1296-1306.
[28] J. Deng, W. Chu, B. Wang, W. Yang, X. S. Zhao, Catal. Sci. Technol., 2016, 6, 851-862.
[29] N. Rui, Z. Y. Wang, K. H. Sun, J. Y. Ye, Q. F. Ge, C. J. Liu, Appl. Catal. B, 2017, 218, 488-497.
[30] W. C. Conner, J. L. Falconer, Chem. Rev., 1995, 95, 759-788.
[31] M. Schubert, S. Pokhrel, A. Thomé, V. Zielasek, T. M. Gesing, F. Roessner, L. M. dler, M. Bae Umer, Catal. Sci. Technol., 2016, 6, 7449-7460.
[32] J. P. Hong, W. Chu, P. A. Chernavskii, A. Y. Khodakov, J. Catal., 2010, 273, 9-17.
[33] S. T. Srinivas, P. K. Rao, J. Catal., 1994, 148, 470-477.
[34] F. Solymosi, A. Erdohelyi, M. Lancz, J. Catal., 1985, 95, 567-577.
[35] W. X. Wang, X. K. Li, Y. Zhang, R. Zhang, H. Ge, J. C. Bi, M. G. Tang, Catal. Sci. Technol., 2017, 7, 4413-4421.
[36] M. R. Gogate, R. J. Davis, Catal. Commun., 2010, 11, 901-906.
[37] Y. Zhu, S. R. Zhang, Y. C. Ye, X. Q. Zhang, L. Wang, W. Zhu, F. Cheng, F. F. Tao, ACS. Catal., 2012, 2, 2403-2408.
[38] A. P. Grosvenor, B. A. Kobe, M. C. Biesinger, N. S. McIntyre, Surf. Interface Anal., 2004, 36, 1564-1574.
[39] J. J. Luo, O. Ersen, W. Chu, T. Dintzer, P. Petit, C. Petit, J. Colloid. Interf. Sci., 2016, 482, 135-141.
[40] X. Y. Deng, A. Verdaguer, T. Herranz, C. Weis, H. Bluhm, M. Salmeron, Langmuir, 2008, 24, 9474-9478.

Ru/FeO_x catalyst performance design: Highly dispersed Ru species for selective carbon dioxide hydrogenation

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 10

Recommended Articles

Metrics

[1]	Haixia Gao, Kang Liu, Tao Luo, Yu Chen, Junhua Hu, Junwei Fu, Min Liu. CO₂ reduction reaction pathways on single-atom Co sites: Impacts of local coordination environment [J]. Chinese Journal of Catalysis, 2022, 43(3): 832-838.
[2]	Tianmi Tang, Zhenlu Wang, Jingqi Guan. A review of defect engineering in two-dimensional materials for electrocatalytic hydrogen evolution reaction [J]. Chinese Journal of Catalysis, 2022, 43(3): 636-678.
[3]	Qi Hao, Yongmeng Wu, Cuibo Liu, Yanmei Shi, Bin Zhang. Unveiling subsurface hydrogen inhibition for promoting electrochemical transfer semihydrogenation of alkynes with water [J]. Chinese Journal of Catalysis, 2022, 43(12): 3095-3100.
[4]	Bingyu Lin, Yuyuan Wu, Biyun Fang, Chunyan Li, Jun Ni, Xiuyun Wang, Jianxin Lin, Lilong Jiang. Ru surface density effect on ammonia synthesis activity and hydrogen poisoning of ceria-supported Ru catalysts [J]. Chinese Journal of Catalysis, 2021, 42(10): 1712-1723.
[5]	Jiawei Zhong, Jingfeng Han, Yingxu Wei, Shutao Xu, Tantan Sun, Shu Zeng, Xinwen Guo, Chunshan Song, Zhongmin Liu. Tuning the product selectivity of SAPO-18 catalysts in MTO reaction via cavity modification [J]. Chinese Journal of Catalysis, 2019, 40(4): 477-485.
[6]	Yinwen Li, Xin Zhang, Min Wei. New development in Fe/Co catalysts: Structure modulation and performance optimization for syngas conversion [J]. Chinese Journal of Catalysis, 2018, 39(8): 1329-1346.
[7]	Jiawei Zhong, Jingfeng Han, Yingxu Wei, Shutao Xu, Tantan Sun, Xinwen Guo, Chunshan Song, Zhongmin Liu. Enhancing ethylene selectivity in MTO reaction by incorporating metal species in the cavity of SAPO-34 catalysts [J]. Chinese Journal of Catalysis, 2018, 39(11): 1821-1831.
[8]	LIU Bing, XU Heng-Yong, ZHANG Ze-Hui. Temperature-Programmed Surface Reaction Study of Adsorption and Reaction of H₂S on Ceria [J]. Chinese Journal of Catalysis, 2012, 33(10): 1631-1635.
[9]	MIAO Jianwen;*;SONG Guohua;FAN Yining. Propane Oxidative Dehydrogenation over Vanadia Catalysts Supported on Sili-cas with Different Pore Structures [J]. Chinese Journal of Catalysis, 2009, 30(11): 1143-1149.
[10]	MIAO Jianwen;*;SONG Guohua;FAN Yining;ZHOU Jing. Characterization of Nanosized SrTiO3 Catalyst for Oxidative Coupling of Methane by in Situ ESR and TPSR [J]. Chinese Journal of Catalysis, 2008, 29(12): 1277-1282.