SiO2-NaHSO4 as an Efficient Reusable Heterogeneous Catalyst for the One-Pot Three-Component Synthesis of Octahydro-quinazolin-2,5-diones in Water

doi:10.1016/S1872-2067(11)60366-5

催化学报 ›› 2012, Vol. 33 ›› Issue (4): 677-680.DOI: 10.1016/S1872-2067(11)60366-5

SiO₂-NaHSO₄ as an Efficient Reusable Heterogeneous Catalyst for the One-Pot Three-Component Synthesis of Octahydro-quinazolin-2,5-diones in Water

Sadeq Hamood Saleh AZZAM1, Aisha SIDDEKHA2, Aatika NIZAM1, Mohamed Afzal PASHA*

1Department of Studies in Chemistry, Central College Campus, Bangalore University, Bengaluru-560001, India; 2Department of Chemistry, Smt. V. H. D. Central Institute of Home Science, Bangalore-560 001, India

收稿日期:2011-10-16 修回日期:2012-01-06 出版日期:2012-04-13 发布日期:2015-09-09

SiO₂-NaHSO₄ as an Efficient Reusable Heterogeneous Catalyst for the One-Pot Three-Component Synthesis of Octahydro-quinazolin-2,5-diones in Water

Sadeq Hamood Saleh AZZAM1, Aisha SIDDEKHA2, Aatika NIZAM1, Mohamed Afzal PASHA*

1Department of Studies in Chemistry, Central College Campus, Bangalore University, Bengaluru-560001, India; 2Department of Chemistry, Smt. V. H. D. Central Institute of Home Science, Bangalore-560 001, India

Received:2011-10-16 Revised:2012-01-06 Online:2012-04-13 Published:2015-09-09

摘要/Abstract

摘要： An environmentally benign method for the synthesis of octahydro-quinazolin-2,5-diones by the reaction of aromatic aldehydes, dimedone, and urea in the presence of SiO₂-NaHSO₄is reported. SiO₂-NaHSO₄ acts as an efficient, mild, and recyclable heterogeneous catalyst to give excellent yields within a short reaction time in water at 60–80 °C.

关键词: octahydro-quinazolin-2,5-dione, aromatic aldehyde, dimedone, urea, water

Abstract: An environmentally benign method for the synthesis of octahydro-quinazolin-2,5-diones by the reaction of aromatic aldehydes, dimedone, and urea in the presence of SiO₂-NaHSO₄is reported. SiO₂-NaHSO₄ acts as an efficient, mild, and recyclable heterogeneous catalyst to give excellent yields within a short reaction time in water at 60–80 °C.

Key words: octahydro-quinazolin-2,5-dione, aromatic aldehyde, dimedone, urea, water

Sadeq Hamood Saleh AZZAM, Aisha SIDDEKHA, Aatika NIZAM, Mohamed Afzal PASHA. SiO₂-NaHSO₄ as an Efficient Reusable Heterogeneous Catalyst for the One-Pot Three-Component Synthesis of Octahydro-quinazolin-2,5-diones in Water[J]. 催化学报, 2012, 33(4): 677-680.

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https://www.cjcatal.com/CN/Y2012/V33/I4/677

参考文献

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SiO₂-NaHSO₄ as an Efficient Reusable Heterogeneous Catalyst for the One-Pot Three-Component Synthesis of Octahydro-quinazolin-2,5-diones in Water

SiO₂-NaHSO₄ as an Efficient Reusable Heterogeneous Catalyst for the One-Pot Three-Component Synthesis of Octahydro-quinazolin-2,5-diones in Water

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