Well-Ordered Mesoporous Silica Nanoparticles as a Recoverable Catalyst for One-Pot Multicomponent Synthesis of 4H-Chromene Derivatives

doi:10.1016/S1872-2067(11)60423-3

催化学报 ›› 2012, Vol. 33 ›› Issue (9): 1486-1494.DOI: 10.1016/S1872-2067(11)60423-3

Well-Ordered Mesoporous Silica Nanoparticles as a Recoverable Catalyst for One-Pot Multicomponent Synthesis of 4H-Chromene Derivatives

Yaghoub SARRAFI*, Ebrahim MEHRASBI, Amir VAHID, Mahmood TAJBAKHSH

Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran

收稿日期:2012-04-14 修回日期:2012-05-30 出版日期:2012-09-11 发布日期:2012-09-11

Well-Ordered Mesoporous Silica Nanoparticles as a Recoverable Catalyst for One-Pot Multicomponent Synthesis of 4H-Chromene Derivatives

Yaghoub SARRAFI*, Ebrahim MEHRASBI, Amir VAHID, Mahmood TAJBAKHSH

Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran

Received:2012-04-14 Revised:2012-05-30 Online:2012-09-11 Published:2012-09-11

摘要/Abstract

摘要： A simple, efficient and environmentally benign protocol for the synthesis of 4H-chromene derivatives was developed using bio-compatible, neutral, and recoverable mesoporous silica nanoparticles as a catalyst. The 4H-chromene derivatives were obtained in excellent yields by three component reaction of an aldehyde or isatin, malononitrile, and cyclic 1,3-diketones in ethanol at 60 °C.

关键词: green synthesis, multicomponent reactions, 4H-chromene derivatives, mesoporous silica nanoparticles

Abstract: A simple, efficient and environmentally benign protocol for the synthesis of 4H-chromene derivatives was developed using bio-compatible, neutral, and recoverable mesoporous silica nanoparticles as a catalyst. The 4H-chromene derivatives were obtained in excellent yields by three component reaction of an aldehyde or isatin, malononitrile, and cyclic 1,3-diketones in ethanol at 60 °C.

Key words: green synthesis, multicomponent reactions, 4H-chromene derivatives, mesoporous silica nanoparticles

Yaghoub SARRAFI, Ebrahim MEHRASBI, Amir VAHID, Mahmood TAJBAKHSH. Well-Ordered Mesoporous Silica Nanoparticles as a Recoverable Catalyst for One-Pot Multicomponent Synthesis of 4H-Chromene Derivatives[J]. 催化学报, 2012, 33(9): 1486-1494.

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Well-Ordered Mesoporous Silica Nanoparticles as a Recoverable Catalyst for One-Pot Multicomponent Synthesis of 4H-Chromene Derivatives

Well-Ordered Mesoporous Silica Nanoparticles as a Recoverable Catalyst for One-Pot Multicomponent Synthesis of 4H-Chromene Derivatives

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