Catalytic properties of nanosized zinc aluminates prepared by green process using Opuntia dilenii haw plant extract

doi:10.1016/S1872-2067(12)60682-2

催化学报 ›› 2013, Vol. 34 ›› Issue (10): 1951-1958.DOI: 10.1016/S1872-2067(12)60682-2

• 研究论文 • 上一篇

Catalytic properties of nanosized zinc aluminates prepared by green process using Opuntia dilenii haw plant extract

C. Ragupathi^a, J. Judith Vijaya^a, S. Narayanan^a, L. John Kennedy^b, Seeram Ramakrishna^c

a Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College, Chennai-34, India;
b Materials Division, School of Advanced Sciences, Vellore Institute of Technology University, Chennai Campus, Chennai-127, India;
c Centre for Nanofibres and Nanotechnology, National University of Singapore, Singapore

收稿日期:2013-06-06 修回日期:2013-08-16 出版日期:2013-09-29 发布日期:2013-09-29

Catalytic properties of nanosized zinc aluminates prepared by green process using Opuntia dilenii haw plant extract

C. Ragupathi^a, J. Judith Vijaya^a, S. Narayanan^a, L. John Kennedy^b, Seeram Ramakrishna^c

a Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College, Chennai-34, India;
b Materials Division, School of Advanced Sciences, Vellore Institute of Technology University, Chennai Campus, Chennai-127, India;
c Centre for Nanofibres and Nanotechnology, National University of Singapore, Singapore

Received:2013-06-06 Revised:2013-08-16 Online:2013-09-29 Published:2013-09-29
Contact: J. Judith Vijaya

摘要/Abstract

摘要：

Various nanosized zinc aluminate (ZnAl₂O₄) samples were prepared by a conventional and a microwave method both with and without using Opuntia dilenii haw plant extract, and were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), high resolution scanning electron microscopy (HRSEM), energy dispersion scanning (EDX), temperature dependent conductance measurements, thermoelectric power measurements, ultraviolet-visible (UV-Vis) diffuse reflectance spectroscopy, and photoluminescence spectroscopy. The formation of a pure ZnAl₂O₄ phase was confirmed by XRD and FT-IR. A change in morphology from nanosized plates to nanosized sheets with, respectively, the conventional and microwave heating methods was clearly shown by HRSEM. UV-Vis diffusion reflectance spectroscopy measured the band gaps of ZnAl₂O₄ nanosized plates and nanosized sheets as 3.5 and 3.9 eV, respectively. The synthesized ZnAl₂O₄ was single crystalline and has three photoluminescence emissions at 482, 528, and 540 nm. ZnAl₂O₄ nanosized sheets prepared by the microwave method showed higher catalytic activity for the oxidation of benzyl alcohol (85% conversion) than ZnAl₂O₄ nanosized plates prepared by the conventional method (60% conversion).

关键词: Green synthesis, Zinc aluminate, Spinel, Microwave, Optical property

Abstract:

Key words: Green synthesis, Zinc aluminate, Spinel, Microwave, Optical property

C. Ragupathi, J. Judith Vijaya, S. Narayanan, L. John Kennedy, Seeram Ramakrishna. Catalytic properties of nanosized zinc aluminates prepared by green process using Opuntia dilenii haw plant extract[J]. 催化学报, 2013, 34(10): 1951-1958.

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Catalytic properties of nanosized zinc aluminates prepared by green process using Opuntia dilenii haw plant extract

Catalytic properties of nanosized zinc aluminates prepared by green process using Opuntia dilenii haw plant extract

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