Polyvinylpolypyrrolidoniume Tribromide as an Efficient Catalyst for the Acetylation of Alcohols and Phenols

doi:10.1016/S1872-2067(11)60428-2

催化学报 ›› 2012, Vol. 33 ›› Issue (9): 1470-1473.DOI: 10.1016/S1872-2067(11)60428-2

Polyvinylpolypyrrolidoniume Tribromide as an Efficient Catalyst for the Acetylation of Alcohols and Phenols

Arash GHORBANI-CHOGHAMARANI*, Nasrin POURBAHAR

Department of Chemistry, Faculty of Science, Ilam University, PO Box 69315516, Ilam, Iran

收稿日期:2012-02-17 修回日期:2012-05-07 出版日期:2012-09-11 发布日期:2012-09-11

Polyvinylpolypyrrolidoniume Tribromide as an Efficient Catalyst for the Acetylation of Alcohols and Phenols

Arash GHORBANI-CHOGHAMARANI*, Nasrin POURBAHAR

Department of Chemistry, Faculty of Science, Ilam University, PO Box 69315516, Ilam, Iran

Received:2012-02-17 Revised:2012-05-07 Online:2012-09-11 Published:2012-09-11

摘要/Abstract

摘要： An efficient and versatile procedure for the acetylation of alcohols and phenols using acetic anhydride in the presence of a catalytic amount of polyvinylpolypyrrolidoniume tribromide has been successfully developed. Primary, secondary, and tertiary alcohols, as well as a selection of the phenolic compounds, have been successfully acetylated according to this procedure, with good to high yields being achieved over short reaction times.

关键词: alcohol, phenol, polyvinylpolypyrrolidoniume tribromide, acetylation, acetic anhydride

Abstract: An efficient and versatile procedure for the acetylation of alcohols and phenols using acetic anhydride in the presence of a catalytic amount of polyvinylpolypyrrolidoniume tribromide has been successfully developed. Primary, secondary, and tertiary alcohols, as well as a selection of the phenolic compounds, have been successfully acetylated according to this procedure, with good to high yields being achieved over short reaction times.

Key words: alcohol, phenol, polyvinylpolypyrrolidoniume tribromide, acetylation, acetic anhydride

Arash GHORBANI-CHOGHAMARANI, Nasrin POURBAHAR. Polyvinylpolypyrrolidoniume Tribromide as an Efficient Catalyst for the Acetylation of Alcohols and Phenols[J]. 催化学报, 2012, 33(9): 1470-1473.

Arash GHORBANI-CHOGHAMARANI, Nasrin POURBAHAR. Polyvinylpolypyrrolidoniume Tribromide as an Efficient Catalyst for the Acetylation of Alcohols and Phenols[J]. Chinese Journal of Catalysis, 2012, 33(9): 1470-1473.

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参考文献

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Polyvinylpolypyrrolidoniume Tribromide as an Efficient Catalyst for the Acetylation of Alcohols and Phenols

Polyvinylpolypyrrolidoniume Tribromide as an Efficient Catalyst for the Acetylation of Alcohols and Phenols

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