{[K.18-Crown-6]Br3}n：A tribromide catalyst for the catalytic protection of amines and alcohols

doi:10.1016/S1872-2067(12)60644-5

催化学报 ›› 2013, Vol. 34 ›› Issue (9): 1730-1733.DOI: 10.1016/S1872-2067(12)60644-5

{[K.18-Crown-6]Br₃}_n：A tribromide catalyst for the catalytic protection of amines and alcohols

Gholamabbas Chehardoli^a, Mohammad Ali Zolfigol^b, Fateme Derakhshanpanah^b

a Department of Medicinal Chemistry, School of Pharmacy, Hamedan University of Medical Sciences, Hamedan 65178, Iran;
b Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran

收稿日期:2013-04-04 修回日期:2013-06-19 出版日期:2013-09-16 发布日期:2013-08-28
通讯作者: Gholamabbas Chehardoli

{[K.18-Crown-6]Br₃}_n：A tribromide catalyst for the catalytic protection of amines and alcohols

Gholamabbas Chehardoli^a, Mohammad Ali Zolfigol^b, Fateme Derakhshanpanah^b

a Department of Medicinal Chemistry, School of Pharmacy, Hamedan University of Medical Sciences, Hamedan 65178, Iran;
b Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran

Received:2013-04-04 Revised:2013-06-19 Online:2013-09-16 Published:2013-08-28

摘要/Abstract

摘要：

{[K.18-Crown-6]Br₃}_n, a unique tribromide-type catalyst, was utilized for the N-boc protection of amines and trimethylsilylation (TMS) and tetrahydropyranylation (THP) of alcohols. The method is general for the preparation of N-boc derivatives of aliphatic (acyclic and cyclic) and aromatic, and primary and secondary amines and also various TMS-ethers and THP-ethers. The simple separation of the catalyst from the product is one of the many advantages of this method.

关键词: {[K.18-Crown-6]Br₃}_n, Trimethylsilylation, Tetrahydropyranylation, Alcohol, Organic tribromide, N-boc protection of amine

Abstract:

Key words: {[K.18-Crown-6]Br₃}_n, Trimethylsilylation, Tetrahydropyranylation, Alcohol, Organic tribromide, N-boc protection of amine

Gholamabbas Chehardoli, Mohammad Ali Zolfigol, Fateme Derakhshanpanah. {[K.18-Crown-6]Br₃}_n：A tribromide catalyst for the catalytic protection of amines and alcohols[J]. 催化学报, 2013, 34(9): 1730-1733.

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{[K.18-Crown-6]Br₃}_n：A tribromide catalyst for the catalytic protection of amines and alcohols

{[K.18-Crown-6]Br₃}_n：A tribromide catalyst for the catalytic protection of amines and alcohols

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