Au/FeOx-羟基磷灰石催化CO氧化反应中羟基磷灰石和FeOx的作用

doi:10.1016/S1872-2067(12)60590-7

催化学报

Au/FeO_x-羟基磷灰石催化CO氧化反应中羟基磷灰石和FeO_x的作用

赵昆峰^a,b, 乔波涛^a, 张彦杰^a, 王军虎^a

a 中国科学院大连化学物理研究所, 辽宁大连 116023;
b 中国科学院大学, 北京 100049

收稿日期:2013-01-31 修回日期:2013-03-25 出版日期:2013-07-16 发布日期:2013-07-16
通讯作者: 王军虎
基金资助:
中国科学院“百人计划”;国家自然科学基金(11079036);辽宁省自然科学基金(20092173).

The roles of hydroxyapatite and FeO_x in a Au/FeO_x-hydroxyapatite catalyst for CO oxidation

ZHAO Kunfeng^a,b, QIAO Botao^a, ZHANG Yanjie^a, WANG Junhu^a

a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received:2013-01-31 Revised:2013-03-25 Online:2013-07-16 Published:2013-07-16
Supported by:
This work was supported by the Chinese Academy of Sciences for “100 Talents” Project, the National Natural Science Foundation of China (11079036), and the Natural Science Foundation of Liaoning Province (20092173).

摘要/Abstract

摘要： 近期我们报道了Au/FeO_x-羟基磷灰石(HAP, Ca₁₀(PO₄)₆(OH)₂)催化剂应用于CO氧化反应的研究结果,该催化剂不仅具有很高的低温CO氧化活性和反应稳定性, 同时也具有很好的高温抗烧结性能, 即使600℃焙烧后依然能够维持很好的CO氧化反应活性. 为了进一步研究Au/FeO_x-HAP催化CO氧化反应中HAP和FeO_x的作用, 本文对该催化剂进行了更加深入的表征. X射线光电子能谱结果表明, HAP能与Au和FeO_x形成强相互作用, 进而在高温条件下稳定Au和FeO_x纳米粒子. 根据原位漫反射红外结果, FeO_x则主要通过改变反应路径和中间产物的方式起到促进催化剂CO氧化活性的作用. 结合透射电镜, 穆斯堡尔谱和原位漫反射红外结果可知, Au/FeO_x-HAP催化剂良好的反应稳定性源于其优异的抗碳酸盐累积能力.

关键词: 金, 氧化铁, 羟基磷灰石, 一氧化碳, 抗烧结

Abstract: A FeO_x-modified hydroxyapatite (HAP, Ca₁₀(PO₄)₆(OH)₂)-supported gold catalyst is highly active and stable during CO oxidation at low temperature, and it is also sinter-resistant to calcination at temperature up to 600 ℃. This work used catalyst characterization and activity tests to investigate the roles of the HAP support and FeO_x promoter in CO oxidation. XPS results suggested that a strong interaction between the HAP support and the Au and FeO_x nanoparticles gave the sintering resistance. In situ DRIFT studies revealed that the addition of FeO_x changed the nature of the reaction mechanism and intermediates to promote catalytic activity. TEM and Mössbauer examination of the spent catalysts in combination with the in situ DRIFT results suggested that the better stability of Au/FeO_x-HAP originated from its better prevention of carbonate accumulation.

Key words: Gold, Iron oxide, Hydroxyapatite, Carbon monoxide, Sintering resistance

赵昆峰, 乔波涛, 张彦杰, 王军虎. Au/FeO_x-羟基磷灰石催化CO氧化反应中羟基磷灰石和FeO_x的作用[J]. 催化学报, DOI: 10.1016/S1872-2067(12)60590-7.

ZHAO Kunfeng, QIAO Botao, ZHANG Yanjie, WANG Junhu. The roles of hydroxyapatite and FeO_x in a Au/FeO_x-hydroxyapatite catalyst for CO oxidation[J]. Chinese Journal of Catalysis, DOI: 10.1016/S1872-2067(12)60590-7.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(12)60590-7

https://www.cjcatal.com/CN/Y2013/V34/I7/1386

参考文献

[1] Wang D H, Cheng D Y, Hao Z P, Shi X C. Nano-Gold Catalysts and Their Applications. Beijing: National Defence Ind Press (王东辉, 程代云, 郝郑平, 史喜成. 纳米金催化剂及其应用. 北京: 国防工业出版社), 2006. 14

[2] Bond G C, Louis C, Thompson D T. Catalysis by Gold. London: Imperial College Press, 2006. 337

[3] Bond G C, Louis C, Thompson D T. Catalysis by Gold— Phenomenon·Principle·Application. Xu B Q, Yang X Z, Wang D H transl. Beijing: Science Press (邦德, 路易斯, 汤普森. 黄金的催化作用——现象·原理·应用. 徐柏庆, 杨绪壮, 王东辉译. 北京: 科学出版社), 2008. 253

[4] Zhu H G, Liang C D, Yan W F, Overbury S H, Dai S. J Phys Chem B, 2006, 110: 10842

[5] Zhang H L, Yan X J, Li W C. Chin J Catal (张慧丽, 阎晓洁, 李文翠. 催化学报), 2009, 30: 1085

[6] Yan W F, Mahurin S M, Pan Z W, Overbury S H, Dai S. J Am Chem Soc, 2005, 127: 10480

[7] Ma Z, Brown S, Overbury S H, Dai S. Appl Catal A, 2007, 327: 226

[8] Zhang H L, Ren L H, Lu A H, Li W C. Chin J Catal (张慧丽, 任丽会, 陆安慧, 李文翠. 催化学报), 2012, 33: 1125

[9] Yan W F, Brown S, Pan Z W, Mahurin S M, Overbury S H, Dai S. Angew Chem, Int Ed, 2006, 45: 3614

[10] Ma Z, Yin H F, Overbury S H, Dai S. Catal Lett, 2008, 126: 20

[11] Liu X Y, Wang A Q, Wang X D, Mou C Y, Zhang T. Chem Commun, 2008: 3187

[12] Yu K, Wu Z C, Zhao Q R, Li B X, Xie Y. J Phys Chem C, 2008, 112: 2244

[13] Li L C, Wang C S, Ma X X, Yang Z H, Lu X H. Chin J Catal (李力成, 王昌松, 马璇璇, 杨祝红, 陆小华. 催化学报), 2012, 33: 1778

[14] Brown M A, Carrasco E, Sterrer M, Freund H J. J Am Chem Soc, 2010, 132: 4064

[15] Qi C X, Su H J, Guan R G, Xu X F. J Phys Chem C, 2012, 116: 17492

[16] Veith G M, Lupini A R, Dudney N J. J Phys Chem C, 2009, 113: 269

[17] Zhang Y J, Wang J, Yin J, Zhao K F, Jin C Z, Huang Y Y, Jiang Z, Zhang T. J Phys Chem C, 2010, 114: 16443

[18] Vallet-RegÍ M, González-Calbet J M. Prog Solid State Chem, 2004, 32: 1

[19] Tsuchida T, Kubo J, Yoshioka T, Sakuma S, Takeguchi T, Ueda W. J Catal, 2008, 259: 183

[20] Phonthammachai N, Zhong Z Y, Guo J, Han Y F, White T J. Gold Bull, 2008, 41: 42

[21] DomÍnguez M I, Romero-Sarria F, Centeno M A, Odriozola J A. Appl Catal B, 2009, 87: 245

[22] Huang J, Wang L C, Liu Y M, Cao Y, He H Y, Fan K N. Appl Catal B, 2011, 101: 560

[23] Liu X S, Korotkikh O, Farrauto R. Appl Catal A, 2002, 226: 293

[24] Shou M, Tanaka K-i, Yoshioka K, Moro-oka Y, Nagano S. Catal Today, 2004, 90: 255

[25] Siani A, Alexeev O S, Captain B, Lafaye G, Marécot P, Adams R D, Amiridis M D. J Catal, 2008, 255: 162

[26] Tomita A, Shimizu K-i, Kato K, Tai Y. Catal Commun, 2012, 17: 194

[27] Fu Q, Li W X, Yao Y X, Liu H Y, Su H Y, Ma D, Gu X K, Chen L M, Wang Z, Zhang H, Wang B, Bao X H. Science, 2010, 328: 1141

[28] Liu K, Wang A Q, Zhang W S, Wang J, Huang Y Q, Shen J Y, Zhang T. J Phys Chem C, 2010, 114: 8533

[29] Liu L Q, Zhou F, Wang L G, Qi X J, Shi F, Deng Y Q. J Catal, 2010, 274: 1

[30] Liu K, Wang A Q, Zhang W S, Wang J, Huang Y Q, Wang X D, Shen J Y, Zhang T. Ind Eng Chem Res, 2011, 50: 758

[31] Zhao K F, Qiao B T, Wang J, Zhang Y J, Zhang T. Chem Commun, 2011, 47: 1779

[32] Wolf A, Schüth F. Appl Catal A, 2002, 226: 1

[33] Moreau F, Bond G C, Taylor A O. J Catal, 2005, 231: 105

[34] Zhang J X, Maeda M, Kotobuki N, Hirose M, Ohgushi H, Jiang D L, Iwasa M. Mater Chem Phys, 2006, 99: 398

[35] Fu H L, Rahaman M N, Day D E, Brown R F. J Mater Sci: Mater Med, 2011, 22: 579

[36] Kittaka S. J Colloid Interface Sci, 1974, 48: 327

[37] Qiao B T, Deng Y Q. Appl Catal B, 2006, 66: 241

[38] Qiao B T, Zhang J, Liu L Q, Deng Y Q. Appl Catal A, 2008, 340: 220

[39] Moulder J F, Stickle W F, Sobol P E, Bomben K D. Handbook of X-Ray Photoelectron Spectroscopy. 2 nd Ed. Eden Prairie: Perkin-Elmer Corporation, Physical Electronics Divition, 1992. 80

[40] Banerjee I, Khollam Y B, Balasubramanian C, Pasricha R, Bakare P P, Patil K R, Das A K, Bhoraskar S V. Scripta Mater, 2006, 54: 1235

[41] Kozlova A P, Sugiyama S, Kozlov A I, Asakura K, Iwasawa Y. J Catal, 1998, 176: 426

[42] Mizera J, Spiridis N, Socha R, Grabowski R, Samson K, Korecki J, Grzybowska B, Gurgul J, Kepinski L, Malecka M A. Catal Today, 2012, 187: 20

[43] Zhao K F, Liu X, Jin C Z, Yu F H, Rykov A, Wang J, Zhang T. Hyperfine Interact, 2013, 218: 1

[44] Tripathi A K, Kamble V S, Gupta N M. J Catal, 1999, 187: 332

[45] Li M J, Wu Z L, Ma Z, Schwartz V, Mullins D R, Dai S, Overbury S H. J Catal, 2009, 266: 98

[46] Liu K, Wang A Q, Zhang T. ACS Catal, 2012, 2: 1165

[47] Li L, Wang A Q, Qiao B T, Lin J, Huang Y Q, Wang X D, Zhang T. J Catal, 2013, 299: 90

[48] Lin J, Qiao B T, Liu J Y, Huang Y Q, Wang A Q, Li L, Zhang W S, Allard L F, Wang X D, Zhang T. Angew Chem, Int Ed, 2012, 51: 2920

[49] Baltrusaitis J, Jensen J H, Grassian V H. J Phys Chem B, 2006, 110: 12005

[50] Smit G, Zrncevic S, Lazar K. J Mol Catal A, 2006, 252: 103

[51] Daniells S T, Overweg A R, Makkee M, Moulijn J A. J Catal, 2005, 230: 52

[52] Glisenti A. J Chem Soc, Faraday Trans, 1998, 94: 3671

[53] Qiao B T, Wang A Q, Yang X F, Allard L F, Jiang Z, Cui Y T, Liu J Y, Li J, Zhang T. Nat Chem, 2011, 3: 634

[54] Qiao B T, Wang A Q, Lin J, Li L, Su D S, Zhang T. Appl Catal B, 2011, 105: 103
[55] Hattori H. Chem Rev, 1995, 95: 537

Au/FeO_x-羟基磷灰石催化CO氧化反应中羟基磷灰石和FeO_x的作用

The roles of hydroxyapatite and FeO_x in a Au/FeO_x-hydroxyapatite catalyst for CO oxidation

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	刘勇, 赵晓丽, 隆昶, 王晓艳, 邓邦为, 李康璐, 孙艳娟, 董帆. 原位构筑动态Cu/Ce(OH)_x界面用于高活性、高选择性和高稳定性硝酸盐还原合成氨[J]. 催化学报, 2023, 52(9): 196-206.
[2]	孙丽娟, 于晓慧, 唐丽永, 王伟康, 刘芹芹. 构建K₃PW₁₂O₄₀/CdS核壳S型异质结实现同步太阳能光催化分解水和选择性苯甲醇氧化反应[J]. 催化学报, 2023, 52(9): 164-175.
[3]	李世杰, 王春春, 董珂欣, 张鹏, 陈晓波, 李鑫. 新型MIL-101(Fe)/BiOBr S型异质催化剂用于高效光催化降解抗生素和还原六价铬: 光催化性能分析和光催化机理研究[J]. 催化学报, 2023, 51(8): 101-112.
[4]	阎菲, 张由子, 刘思碧, 邹睿卿, Jahan B Ghasemi, 李炫华. 供体-受体型卟啉基金属有机框架实现有效电荷分离高效光催化析氢[J]. 催化学报, 2023, 51(8): 124-134.
[5]	孙利娟, 王伟康, 路平, 刘芹芹, 王乐乐, 唐华. 纳米高熵合金实现光催化剂肖特基势垒的调控用于光催化制氢与苯甲醇氧化耦合反应[J]. 催化学报, 2023, 51(8): 90-100.
[6]	刘海峰, 黄祥, 陈加藏. 电子态调控促进氢气无损耗纯化中CO的光致富集和氧化[J]. 催化学报, 2023, 51(8): 49-54.
[7]	袁鑫, 范海滨, 刘杰, 覃龙州, 王剑, 段秀, 邱江凯, 郭凯. 连续流技术在光氧化还原催化转化的最新进展[J]. 催化学报, 2023, 50(7): 175-194.
[8]	周波, 石建巧, 姜一民, 肖磊, 逯宇轩, 董帆, 陈晨, 王特华, 王双印, 邹雨芹. 强化脱氢动力学实现超低电池电压和大电流密度下抗坏血酸电氧化[J]. 催化学报, 2023, 50(7): 372-380.
[9]	李慧杰, 池漫洲, 辛兴, 王瑞杰, 刘天府, 吕红金, 杨国昱. 异金属取代的多金属氧酸盐@光响应型金属-有机框架用于高选择性光催化CO₂还原[J]. 催化学报, 2023, 50(7): 343-351.
[10]	Sang Eon Jun, Sungkyun Choi, Jaehyun Kim, Ki Chang Kwon, Sun Hwa Park, Ho Won Jang. 用于电化学能量转换反应的非贵金属单原子催化剂[J]. 催化学报, 2023, 50(7): 195-214.
[11]	刘诗瑶, 巩玉同, 杨晓, 张楠楠, 刘会斌, 梁长海, 陈霄. 具有富电子镍位点的耐酸金属间化合物CaNi₂Si₂催化剂用于不饱和有机酸酐/酸的水相加氢[J]. 催化学报, 2023, 50(7): 260-272.
[12]	韩璟怡, 管景奇. 通过限域-热解策略可控合成双原子催化剂[J]. 催化学报, 2023, 49(6): 1-4.
[13]	娄向西, 高璇, 刘钰, 褚名宇, 张丛洋, 邱盈华, 杨文秀, 曹暮寒, 王贵领, 张桥, 陈金星. 高效光热催化废旧聚酯塑料升级回收[J]. 催化学报, 2023, 49(6): 113-122.
[14]	张海波, 王中辽, 张金锋, 代凯. 金属硫化物基异质结光催化剂: 原理、影响、应用和原位表征[J]. 催化学报, 2023, 49(6): 42-67.
[15]	米金星, 陈孝平, 丁亚军, 张良柱, 马军, 康辉, 吴籼虹, 刘岳峰, 陈建军, 吴忠帅. 活化高熵氧化物中部分金属位点显著增强热催化和电催化[J]. 催化学报, 2023, 48(5): 235-246.

Au/FeOx-羟基磷灰石催化CO氧化反应中羟基磷灰石和FeOx的作用

The roles of hydroxyapatite and FeOx in a Au/FeOx-hydroxyapatite catalyst for CO oxidation

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

Au/FeO_x-羟基磷灰石催化CO氧化反应中羟基磷灰石和FeO_x的作用

The roles of hydroxyapatite and FeO_x in a Au/FeO_x-hydroxyapatite catalyst for CO oxidation