新型Brönsted酸性离子液体催化二氧化碳与环氧化合物偶联反应

doi:10.1016/S1872-2067(14)60227-8

催化学报 ›› 2015, Vol. 36 ›› Issue (3): 408-413.DOI: 10.1016/S1872-2067(14)60227-8

新型Brönsted酸性离子液体催化二氧化碳与环氧化合物偶联反应

常涛^a, 高晓蕊^a, 边丽^a, 付西英^b, 袁明霞^a, 景欢旺^b

a 河北工程大学理学院, 河北省煤层气开发利用工程实验室, 河北邯郸056038;
b 兰州大学化学化工学院, 功能有机分子化学国家重点实验室, 甘肃兰州730000

收稿日期:2014-08-11 修回日期:2014-09-15 出版日期:2015-02-14 发布日期:2015-02-14
通讯作者: 常涛, 景欢旺
基金资助:
河北省自然科学基金(B2012402001); 国家自然科学基金(51202054, 21173106).

Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids

Tao Chang^a, Xiaorui Gao^a, Li Bian^a, Xiying Fu^b, Mingxia Yuan^a, Huanwang Jing^b

a Engineering Laboratory for Coalbed Gas Exploitation of Hebei Province, College of Science, Hebei University of Engineering, Handan 056038, Hebei, China;
b State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, Gansu, China

Received:2014-08-11 Revised:2014-09-15 Online:2015-02-14 Published:2015-02-14
Supported by:
This work was supported by the Natural Science Foundation of Hebei Province (B2012402001) and the National Natural Science Foundation of China (51202054, 21173106).

摘要/Abstract

摘要：

设计合成了一系列由碳链长度可调节的Brönsted酸中心阳离子及Lewis碱中心阴离子构成的酸性离子液体, 并应用于二氧化碳与环氧化合物的偶联反应合成环碳酸酯.考察了离子液体结构以及温度、压力和催化剂用量等参数的影响.结果表明, 具有长碳链的离子液体表现出高催化活性及可重复使用性能.离子液体的酸性影响催化活性.

关键词: 二氧化碳固定, 偶联反应, 酸性离子液体, 环碳酸酯, 哈米特酸度

Abstract:

A series of Brönsted acid ionic liquids (BAILs) containing a long chain Brönsted acid site in the cationic part and a Lewis basic site in the anionic part were designed, synthesized, and used as catalyst for the coupling of epoxides and carbon dioxide to cyclic carbonates without a co-catalyst or co-solvent. The effects of catalyst structure and other parameters on the catalytic performance were investigated. The long chain 2-(N,N-dimethyldodecylammonium) acetic acid bromide ([(CH₂COOH)DMDA]Br) showed high catalytic activity and good reusability. This protocol was expanded to various epoxides, which gave the corresponding cyclic carbonates in good yields. The acidity of the catalyst influenced its catalytic activity.

Key words: Carbon dioxide fixation, Coupling reaction, Brönsted acidic ionic liquid, Cyclic carbonate, Hammett acidity

常涛, 高晓蕊, 边丽, 付西英, 袁明霞, 景欢旺 . 新型Brönsted酸性离子液体催化二氧化碳与环氧化合物偶联反应[J]. 催化学报, 2015, 36(3): 408-413.

Tao Chang, Xiaorui Gao, Li Bian, Xiying Fu, Mingxia Yuan, Huanwang Jing. Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids[J]. Chinese Journal of Catalysis, 2015, 36(3): 408-413.

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新型Brönsted酸性离子液体催化二氧化碳与环氧化合物偶联反应

Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids

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