H-ZSM-5分子筛内C1催化过程中芳烃生成的选择性控制机制

doi:10.1016/S1872-2067(25)64856-X

催化学报 ›› 2026, Vol. 82: 301-311.DOI: 10.1016/S1872-2067(25)64856-X

H-ZSM-5分子筛内C1催化过程中芳烃生成的选择性控制机制

辛欣^a^,^b, 高鹏^a^,^b^,^c^,^*(), 李圣刚^a^,^b^,^c^,^d^,^*()

^a中国科学院上海高等研究院, 低碳转化科学与工程中心, 上海 201210
^b中国科学院大学, 北京 100049
^c中国科学院上海高等研究院, 低碳催化与二氧化碳利用全国重点实验室, 上海 201210
^d上海科技大学物质科学与技术学院, 上海 201210

收稿日期:2025-07-03 接受日期:2025-09-16 出版日期:2026-03-18 发布日期:2026-03-05
通讯作者: * 电子信箱: gaopeng@sari.ac.cn (高鹏),lisg@sari.ac.cn (李圣刚).
基金资助:
国家重点研发计划(2024YFB4206103);中国国家自然科学基金(22293023);中国国家自然科学基金(22172188);中国国家自然科学基金(22172189);中国国家自然科学基金(22293025);中国科学院青年跨学科团队, 上海市学术带头人项目(22XD1424100);上海市科学技术委员会(23YF1453400);上海市科学技术委员会(23ZR1481700)

Selectivity control mechanism of aromatics formation in C1 catalysis within H-ZSM-5 zeolites

Xin Xin^a^,^b, Peng Gao^a^,^b^,^c^,^*(), Shenggang Li^a^,^b^,^c^,^d^,^*()

^aLow-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China
^bUniversity of Chinese Academy of Sciences, Beijing 100049, China
^cState Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China
^dSchool of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China

Received:2025-07-03 Accepted:2025-09-16 Online:2026-03-18 Published:2026-03-05
Contact: * E-mail: gaopeng@sari.ac.cn (P. Gao),lisg@sari.ac.cn (S. Li).
Supported by:
National Key R&D Program of China(2024YFB4206103);National Natural Science Foundation of China(22293023);National Natural Science Foundation of China(22172188);National Natural Science Foundation of China(22172189);National Natural Science Foundation of China(22293025);CAS Youth Interdisciplinary Team, the Program of Shanghai Academic Research Leader(22XD1424100);Science and Technology Commission of Shanghai Municipality(23YF1453400);Science and Technology Commission of Shanghai Municipality(23ZR1481700)

摘要/Abstract

摘要：

利用CO₂等碳基资源, 可在减少石油资源消耗的情况下生产重要有机化学品、合成材料和燃料添加剂. 在甲醇转化和CO/CO₂加氢反应中, 分子筛(特别是中孔H-ZSM-5)的酸性位点是实现芳烃选择性生成的关键活性中心. H-ZSM-5的酸性位点可分布在其MFI拓扑结构的直孔道、正弦孔道和交叉位点处, 所生成的芳烃可通过分子筛孔道扩散到催化剂表面. 在此类反应中, 甲醇、甲氧基、二甲醚等C1物种在催化过程中可作为反应物或中间体促进活性烃池物种的生成和转化. 尽管分子筛的限域效应被普遍认为是实现芳烃选择性的关键, 但关键反应步骤及甲醇或其他C1中间体的作用仍不清晰. 因此, 阐明甲醇转化为芳烃的反应路径具有重要意义, 这使得通过调节芳烃/烯烃双循环烃池机理中的烃池物种来优化芳烃合成过程成为可能.

本文通过系统的第一性原理计算, 阐明了在H-ZSM-5分子筛中具有代表性的烯烃反应中间体丙烯与含氧化合物甲醇反应形成芳烃的机制, 该低碳烯烃中间体会经历链增长、环形成和环甲基化, 从而生成各种芳烃. 结果表明, 上述反应步骤的能垒会越来越高, 其中芳环通过甲醇甲基化反应形成质子化的多甲基苯最为困难. 这在很大程度上可归因于两个因素: 一是分子筛的限域效应, 即甲醇对芳环的甲基化比对碳链的甲基化有更高的空间要求; 二是芳烃甲基化反应破坏了其芳香性. 该理论预测与近期实验观察一致, 向稳态催化系统中投入碳标记的甲醇时, 碳标记的产物首先出现在烯烃组分中, 而碳标记的芳烃组分的出现则会有较长的延时. 计算结果也很好地解释了通过共进料芳烃物种可提高特定芳烃产量, 该过程改变烃池物种的组成和抑制碳链的增长, 从而增强芳烃烷基化反应, 促进特定芳烃的生成.

综上, 该研究结果对理解芳烃的形成和甲醇的作用, 以及开发具有增强性能的分子筛基催化剂至关重要, 有助于从各种C1原料出发合成芳烃.

关键词: C1转化, 芳烃合成, H-ZSM-5分子筛, 限域效应, Brönsted酸

Abstract:

Zeolites are important components of catalysts for aromatics synthesis from methanol and CO/CO₂. Although generally attributed to their confinement effects, the key reaction steps and the role of methanol or other C1 intermediates remain unclear. Herein, extensive first principles calculations were performed to reveal the mechanism of aromatics formation from light olefins such as propene and methanol within H-ZSM-5 zeolites. Propene was found to undergo chain growth, ring formation, and ring methylation, resulting in various aromatics. Our calculations show that the above steps become increasingly more difficult, so aromatic ring methylation by methanol to form protonated polymethylbenzenes was the most challenging. This can largely be attributed to both the zeolite confinement effect due to the higher spatial demand for the methylation of the aromatic ring than that of the carbon chain by methanol, and the disruption of its aromaticity. Our prediction agrees with the experimentally observed delayed formation of aromatic species, and also explains the improved production of specific aromatics by co-feeding aromatic species to change the hydrocarbon pool composition and suppress the chain growth. Thus, theoretical insights can enable the rational design of better catalysts and processes for the valorization of C1 molecules.

Key words: C1 conversion, Aromatics synthesis, H-ZSM-5 zeolites, Confinement effects, Brönsted acid

辛欣, 高鹏, 李圣刚. H-ZSM-5分子筛内C1催化过程中芳烃生成的选择性控制机制[J]. 催化学报, 2026, 82: 301-311.

Xin Xin, Peng Gao, Shenggang Li. Selectivity control mechanism of aromatics formation in C1 catalysis within H-ZSM-5 zeolites[J]. Chinese Journal of Catalysis, 2026, 82: 301-311.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(25)64856-X

https://www.cjcatal.com/CN/Y2026/V82/I3/301

图/表 7

Fig. 1. Catalyst models and general reaction steps simulated in this work. View of the H-ZSM-5 zeolite model from the straight (a) and sinusoidal (b) channels. (c) Schematic illustration of the transition states of the typical reaction steps involved in the chain growth of olefin intermediates, their aromatization, and methylation of the benzene ring. (d) 5-Ring (R5) and 6-ring (R6) routes for the cyclization reaction of the C6 species in the aromatization step with the calculated reaction barriers shown in eV.

Fig. 2. Reaction pathway for aromatics formation from propene and methanol catalyzed by the acidic site of H-ZSM-5. The reaction processes considered include the growth of the carbon chain in propene to form long-chain C6 species, its further aromatization to yield benzene, and the formation of heavier aromatics by methylation of the benzene ring. ZOH, ZO-, and ZOCH3 after @denote protonated, deprotonated acid sites of zeolite, and the zeolite with surface methoxy species (SMS) formed by methanol, respectively.

Fig. 3. Formation of C6 species via stepwise methylation of propene by methanol. The elementary steps consist of methylation with methanol, intramolecular hydride transfer (IHT), and deprotonation of the carbenium ion, resulting in a C6 carbenium ion. The rate-determining steps are chain methylation with methanol, and their transition state (TS) structures are shown in the inserts. Numbers in the paratheses are the calculated energy barriers. The asterisk (*) refers to the acid site of the H-ZSM-5 zeolite. Color code: Si (yellow), Al (purple), O (red), H (white), C (gray).

Fig. 4. Aromatization of C6 species for benzene formation via the R5 route. The elementary steps include the deprotonation of the carbenium ions, hydride transfer (HT), cyclization, intramolecular hydride transfer (IHT), and expansion of the 5-member ring. Transition state (TS) structures of the rate-determining steps (i.e., hydride transfer) are shown in the inserts. Energy barriers of related reaction steps are shown after the TS. Color code: Si (yellow), Al (purple), O (red), H (white), C (gray).

Fig. 5. Methylation of the benzene ring with methanol to form polymethylbenzene. The elementary steps in this process consist of successive ring methylation with methanol and deprotonation of the benzenium ions. Transition state (TS) structures for the rate-determining steps (i.e., ring methylation with methanol) in this process are shown in the inserts. Energy barriers of the related reaction steps are shown after the TS. Color code: Si (yellow), Al (purple), O (red), H (white), C (gray).

Fig. 6. Rate-determining steps in aromatics formation from propene in H-ZSM-5. (a) Comparison of the energy barriers (Ea, eV) for the rate-determining steps in chain growth, ring formation, and ring methylation, which are the chain methylation, hydride transfer, and ring methylation steps, respectively. Analysis of the distances (?) between the carbon atom undergoing methylation in olefins and aromatics (denoted as COl and CAr, respectively) and the carbon atom of methanol (CMe), as well as the distance (?) between the carbon and oxygen (OMe) atoms of methanol in the transition state structures for the methylations of carbon chain (b) and benzene ring (c) with methanol.

Fig. 7. Mechanism of methanol-mediated aromatics formation from propene in H-ZSM-5. The relationship of the aromatics formation with the induction period and aromatic cycle are also indicated in the figure.

参考文献

[1]	T. Li, T. Shoinkhorova, J. Gascon, J. Ruiz-Martínez, ACS Catal., 2021, 11, 7780-7819.
[2]	T. Xiao, J. Luo, W. Huang, L. Lu, C. Liu, Y. Pan, ACS Catal., 2024, 14, 6881-6896.
[3]	X. Shang, H. Zhuo, Q. Han, X. Yang, G. Hou, G. Liu, X. Su, Y. Huang, T. Zhang, Angew. Chem. Int. Ed., 2023, 62, e202309377.
[4]	W. Zhou, K. Cheng, J. Kang, C. Zhou, V. Subramanian, Q. Zhang, Y. Wang, Chem. Soc. Rev., 2019, 48, 3193-3228.
[5]	P. Liu, J. Wang, L. Ling, X. Shen, X. Li, R. Zhang, B. Wang, Fuel, 2024, 357, 130000.
[6]	J. Wang, J. Ma, L. Ling, Y. Zhang, R. Zhang, X. Shen, X. Li, B. Wang, Fuel, 2024, 366, 131362.
[7]	I. Pinilla-Herrero, E. Borfecchia, T. Cordero-Lanzac, U. V. Mentzel, F. Joensen, K. A. Lomachenko, S. Bordiga, U. Olsbye, P. Beato, S. Svelle, J. Catal., 2021, 394, 416-428.
[8]	P. Gao, Q. Wang, J. Xu, G. Qi, C. Wang, X. Zhou, X. Zhou, N. Feng, X. Liu, F. Deng, ACS Catal., 2018, 8, 69-74.
[9]	C. Liu, E. A. Uslamin, E. Khramenkova, E. Sireci,L. T. L. J. Ouwehand, S. Ganapathy, F. Kapteijn, E. A. Pidko, ACS Catal., 2022, 12, 3189-3200.
[10]	Y. Wu, J. Han, W. Zhang, Z. Yu, K. Wang, X. Fang, Y. Wei, Z. Liu, J. Am. Chem. Soc., 2024, 146, 8086-8097.
[11]	Z. Wei, M. Wang, X. Lu, Z. Zhou, Z. Tang, C. Chang, Y. Yang, S. Li, P. Gao, Chin. J. Catal., 2025, 72, 301-313.
[12]	P. Gao, L. Zhang, S. Li, Z. Zhou, Y. Sun, ACS Cent. Sci., 2020, 6, 1657-1670.
[13]	R.-P. Ye, J. Ding, W. Gong, M. D. Argyle, Q. Zhong, Y. Wang, C. K. Russell, Z. Xu, A. G. Russell, Q. Li, M. Fan, Y.-G. Yao, Nat. Commun., 2019, 10, 5698.
[14]	Q. Wang, K. Hu, R. Gao, L. Zhang, L. Wang, C. Zhang, Atmosphere, 2022, 13, 1238.
[15]	J. Wei, R. Yao, Q. Ge, D. Xu, C. Fang, J. Zhang, H. Xu, J. Sun, Appl. Catal. B, 2021, 283, 119648.
[16]	G. Tian, Z. Li, C. Zhang, X. Liu, X. Fan, K. Shen, H. Meng, N. Wang, H. Xiong, M. Zhao, X. Liang, L. Luo, L. Zhang, B. Yan, X. Chen, H.-J. Peng, F. Wei, Nat. Commun., 2024, 15, 3037.
[17]	H. Wang, P. Gao, S. Li, T. Wang, C. Yang, J. Li, T. Lin, L. Zhong, Y. Sun, Chem Catal., 2022, 2, 779-796.
[18]	T. Wang, C. Yang, P. Gao, S. Zhou, S. Li, H. Wang, Y. Sun, Appl. Catal. B, 2021, 286, 119929.
[19]	X. Cui, P. Gao, S. Li, C. Yang, Z. Liu, H. Wang, L. Zhong, Y. Sun, ACS Catal., 2019, 9, 3866-3876.
[20]	D. Lesthaeghe, B. De Sterck, V. Van Speybroeck, G. Marin, M. Waroquier, Angew. Chem. Int. Ed., 2007, 46, 1311-1314.
[21]	J. Ke, W.-D. Hu, Y.-J. Du, Y.-D. Wang, C.-M. Wang, Z.-K. Xie, ACS Catal., 2023, 13, 8642-8661.
[22]	F.-E. Gao, J.-Y. Liu, Mol. Catal., 2022, 533, 112755.
[23]	W. Zhang, S. Lin, Y. Wei, P. Tian, M. Ye, Z. Liu, Natl. Sci. Rev., 2023, 10, nwad120.
[24]	X. Wu, Y. Wei, Z. Liu, Acc. Chem. Res., 2023, 56, 2001-2014.
[25]	C. Chizallet, C. Bouchy, K. Larmier, G. Pirngruber, Chem. Rev., 2023, 123, 6107-6196.
[26]	R. Liu, X. Shao, C. Wang, W. Dai, N. Guan, Chin. J. Catal., 2023, 47, 67-92.
[27]	C.-M. Wang, Y.-D. Wang, Y.-J. Du, G. Yang, Z.-K. Xie, Catal. Sci. Technol., 2015, 5, 4354-4364.
[28]	S. L. C. Moors, K. De Wispelaere, J. Van der Mynsbrugge, M. Waroquier, V. Van Speybroeck, ACS Catal., 2013, 3, 2556-2567.
[29]	J. H. Kang, F. H. Alshafei, S. I. Zones, M. E. Davis, ACS Catal., 2019, 9, 6012-6019.
[30]	S. Lu, H. Yang, Z. Zhou, L. Zhong, S. Li, P. Gao, Y. Sun, Chin. J. Catal., 2021, 42, 2038-2048.
[31]	N. Wang, J. Li, W. Sun, Y. Hou, L. Zhang, X. Hu, Y. Yang, X. Chen, C. Chen, B. Chen, W. Qian, Angew. Chem. Int. Ed., 2022, 61, e202114786.
[32]	X. Zhang, X. Gong, E. Abou-Hamad, H. Zhou, X. You, J. Gascon, A. Dutta Chowdhury, Angew. Chem. Int. Ed., 2024, 63, e202411197.
[33]	Y. Wang, S. Kazumi, W. Gao, X. Gao, H. Li, X. Guo, Y. Yoneyama, G. Yang, N. Tsubaki, Appl. Catal. B, 2020, 269, 118792.
[34]	C. Li, X. Fang, B. Li, S. Yan, Z. Chen, L. Yang, S. Hao, H. Liu, J. Liu, W. Zhu, Chin. J. Catal., 2025, 72, 314-322.
[35]	U. Olsbye, S. Svelle, K. P. Lillerud, Z. H. Wei, Y. Y. Chen, J. F. Li, J. G. Wang, W. B. Fan, Chem. Soc. Rev., 2015, 44, 7155-7176.
[36]	A. D. Chowdhury, K. Houben, G. T. Whiting, M. Mokhtar, A. M. Asiri, S. A. Al-Thabaiti, S. N. Basahel, M. Baldus, B. M. Weckhuysen, Angew. Chem. Int. Ed., 2016, 55, 15840-15845.
[37]	P. N. Plessow, F. Studt, ACS Catal., 2017, 7, 7987-7994.
[38]	S. Wang, Y. Chen, Z. Wei, Z. Qin, H. Ma, M. Dong, J. Li, W. Fan, J. Wang, J. Phys. Chem. C, 2015, 119, 28482-28498.
[39]	S. Wang, Z. Li, Z. Qin, M. Dong, J. Li, W. Fan, J. Wang, Chin. J. Catal., 2021, 42, 1126-1136.
[40]	Y. Chen, S. Wang, Z. Wei, J. Li, M. Dong, Z. Qin, J. Wang, W. Fan, J. Phys. Chem. C, 2021, 125, 26472-26483.
[41]	C.-M. Wang, Y.-D. Wang, Y.-J. Du, G. Yang, Z.-K. Xie, Catal. Sci. Technol., 2016, 6, 3279-3288.
[42]	C. Liu, E. A. Uslamin, E. A. Pidko, F. Kapteijn, ACS Catal., 2023, 13, 5205-5212.
[43]	X. Sun, S. Mueller, H. Shi, G. L. Haller, M. Sanchez-Sanchez, A. C. van Veen, J. A. Lercher, J. Catal., 2014, 314, 21-31.
[44]	X. Shang, J. Han, Q. Han, G. Hou, A. Zheng, X. Yang, Z. Liu, G. Liu, X. Su, Y. Huang, T. Zhang, Appl. Catal. B, 2024, 359, 124523.
[45]	G. Kresse, J. Furthmüller, Phys. Rev. B, 1996, 54, 11169-11186.
[46]	G. Kresse, J. Furthmüller, Comput. Mater. Sci., 1996, 6, 15-50.
[47]	J. Wellendorff, K. T. Lundgaard, A. Møgelhøj, V. Petzold, D. D. Landis, J. K. Nørskov, T. Bligaard, K. W. Jacobsen, Phys. Rev. B, 2012, 85, 235149.
[48]	P. E. Blöchl, Phys. Rev. B, 1994, 50, 17953-17979.
[49]	G. Kresse, D. Joubert, Phys. Rev. B, 1999, 59, 1758-1775.
[50]	G. Henkelman, B. P. Uberuaga, H. Jónsson, J. Chem. Phys., 2000, 113, 9901-9904.
[51]	G. Henkelman, H. Jónsson, J. Chem. Phys., 2000, 113, 9978-9985.
[52]	A. Heyden, A. T. Bell, F. J. Keil, J. Chem. Phys., 2005, 123, 224101.
[53]	Database of Zeolite Structures, https://www.iza-structure.org/databases/.
[54]	R. Y. Brogaard, R. Henry, Y. Schuurman, A. J. Medford, P. G. Moses, P. Beato, S. Svelle, J. K. Nørskov, U. Olsbye, J. Catal., 2014, 314, 159-169.
[55]	S. Guo, S. Fan, H. Wang, S. Wang, Z. Qin, M. Dong, W. Fan, J. Wang, ACS Catal., 2024, 14, 271-282.
[56]	Q. Chen, J. Liu, B. Yang, Nat. Commun., 2021, 12, 3725.
[57]	Y. Zhang, W. Zhang, C. Zhang, L. He, S. Lin, S. Xu, Y. Wei, Z. Liu, Chin. J. Catal., 2025, 71, 169-178.
[58]	Z. Wen, D. Yang, X. He, Y. Li, X. Zhu, J. Mol. Catal. A, 2016, 424, 351-357.
[59]	S. A. F. Nastase, P. Cnudde, L. Vanduyfhuys, K. De Wispelaere, V. Van Speybroeck, C. R. A. Catlow, A. J. Logsdail, ACS Catal., 2020, 10, 8904-8915.
[60]	S. Wang, Y. Chen, Z. Qin, T.-S. Zhao, S. Fan, M. Dong, J. Li, W. Fan, J. Wang, J. Catal., 2019, 369, 382-395.
[61]	Y. Chen, X. Zhao, Z. Qin, S. Wang, Z. Wei, J. Li, M. Dong, J. Wang, W. Fan, J. Phys. Chem. C, 2020, 124, 13789-13798.
[62]	C.-M. Wang, Y.-D. Wang, Z.-K. Xie, J. Catal., 2013, 301, 8-19.
[63]	Y. Gu, J. Liang, Y. Wang, K. Huo, M. Li, W. Wang, R. He, S. Yasuda, X. Gao, G. Yang, M. Wu, N. Tsubaki, Appl. Catal. B, 2024, 349, 123842.
[64]	S. Müller, Y. Liu, F. M. Kirchberger, M. Tonigold, M. Sanchez-Sanchez, J. A. Lercher, J. Am. Chem. Soc., 2016, 138, 15994-16003.
[65]	K. Cheng, W. Zhou, J. Kang, S. He, S. Shi, Q. Zhang, Y. Pan, W. Wen, Y. Wang, Chem, 2017, 3, 334-347.
[66]	J. Zuo, W. Chen, J. Liu, X. Duan, L. Ye, Y. Yuan, Sci. Adv., 2020, 6, eaba5433.
[67]	Z. Xiao, H. Huang, C. Cao, J. Xu, Z. Yang, Fuel, 2022, 319, 123848.
[68]	L. Zhang, T. Fu, K. Ren, Y. Han, R. Wang, G. Zhan, Z. Li, Appl. Catal. B, 2023, 321, 122047.
[69]	Z. Lai, N. Sun, J. Jin, J. Chen, H. Wang, P. Hu, ACS Catal., 2021, 11, 12977-12988.
[70]	F. Jiao, J. Li, X. Pan, J. Xiao, H. Li, H. Ma, M. Wei, Y. Pan, Z. Zhou, M. Li, S. Miao, J. Li, Y. Zhu, D. Xiao, T. He, J. Yang, F. Qi, Q. Fu, X. Bao, Science, 2016, 351, 1065-1068.

H-ZSM-5分子筛内C1催化过程中芳烃生成的选择性控制机制

Selectivity control mechanism of aromatics formation in C1 catalysis within H-ZSM-5 zeolites

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 7

参考文献

相关文章 10

编辑推荐

Metrics

[1]	李荣坦, 杜相泽, 冯小辉, 王建洋, 塔娜, 傅强, 包信和. 氧化物表面覆盖层稳定活性氧化铁催化苛刻高温水气变换反应[J]. 催化学报, 2026, 82(3): 327-336.
[2]	钟百灵, 胡俊蝶, 杨晓刚, 舒银颖, 蔡亚辉, 李长明, 曲家福. 金属有机框架中限域金属物种用于CO₂加氢: 合成方法、催化机理及未来展望[J]. 催化学报, 2025, 68(1): 177-203.
[3]	张晓敏, 蔡凯, 李媖, 戚暨, 王悦, 刘云铎, 王美岩, 黄守莹, 马新宾. SSZ-13分子筛在二甲醚羰基化反应中的机理研究和空间限域效应[J]. 催化学报, 2024, 61(6): 301-311.
[4]	雷琦锋, 王畅, 戴卫理, 武光军, 关乃佳, Michael Hunger, 李兰冬. 双功能TiSn-Beta分子筛限域的串联Lewis酸催化烯烃生成1,2-二醇[J]. 催化学报, 2021, 42(7): 1176-1184.
[5]	王森, 李志凯, 秦张峰, 董梅, 李俊汾, 樊卫斌, 王建国. H-ZSM-5分子筛不同孔道处的酸位在甲醇制烯烃反应中的催化作用[J]. 催化学报, 2021, 42(7): 1126-1136.
[6]	楚卫锋, 刘晓娜, 杨志强, Nakata Hiroya, 谭兴智, 刘雪斌, 徐龙伢, 郭鹏, 李秀杰, 朱向学. FER分子筛中铝原子的受限落位[J]. 催化学报, 2021, 42(11): 2078-2087.
[7]	杨灵志, 刘志远, 刘智, 彭文永, 柳云骐, 刘晨光. 不同晶粒尺寸H-ZSM-5催化剂上甲醇芳构化反应性能[J]. 催化学报, 2017, 38(4): 683-690.
[8]	崔华楠, 赵振华, 梁业如, 石建英, 吴丁财, 刘鸿, 符若文. 炭气凝胶孔结构对其负载的 TiO₂光催化降解甲基橙性能的影响[J]. 催化学报, 2011, 32(2): 321-324.
[9]	张佳;周丹红;倪丹. H-ZSM-5分子筛上的乙烯二聚反应机理的理论计算研究[J]. 催化学报, 2008, 29(8): 715-719.
[10]	成艳;李钢;马书启;王祥生;陈永英. 负载型金催化剂催化乙醇选择氧化反应[J]. 催化学报, 2008, 29(10): 1009-1014.