钴配位共价有机框架用于染料敏化光电化学水分解

doi:10.1016/S1872-2067(26)65196-0

催化学报 ›› 2027, Vol. 92: 248-261.DOI: 10.1016/S1872-2067(26)65196-0

钴配位共价有机框架用于染料敏化光电化学水分解

梁子展^a,1, 王晓林^a,1, 洪智林^a, 李鑫奥^a, 彭新邦^a, 谭礼林^b,*, 肖利民^c, 周业成^a,*, 刘军民^a,*

^a中山大学材料科学与工程学院, 广东省低碳化学与节能重点实验室, 广东广州 510275;
^b汕头市绿色精密制造高值化学品工程技术研究中心, 化学与精细化工广东省实验室, 广东汕头 515031;
^c北京航空航天大学计算机科学与工程学院, 北京 100191

收稿日期:2026-02-26 接受日期:2026-04-02 出版日期:2027-01-18 发布日期:2026-10-30
通讯作者: *电子信箱: tanll@ccelab.com.cn (谭礼林), zhouych29@mail.sysu.edu.cn (周业成), liujunm@mail.sysu.edu.cn (刘军民).
作者简介:¹共同第一作者.
基金资助:
国家自然科学基金(22275214, 21975291); 广东省自然科学基金(2024A1515012076, 2022A1515011949); 广东特支计划青年拔尖人才项目(2024TQ08C327).

Cobalt-coordinated covalent organic framework as a versatile water oxidation catalyst in dye-sensitized photoelectrochemical cells for solar water splitting

Zizhan Liang^a,1, Xiaolin Wang^a,1, Zhilin Hong^a, Xinao Li^a, Xinbang Peng^a, Lilin Tan^b,*, Limin Xiao^c, Yecheng Zhou^a,*, Junmin Liu^a,*

^aThe Key Laboratory of Low-Carbon Chemistry & Energy Conservation of Guangdong Province, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510275, Guangdong, China;
^bShantou Engineering Technology Research Center for Green and Precise Manufacturing of High-value Chemicals, Chemistry and Chemical Engineering Guangdong Laboratory, Shantou 515031, Guangdong, China;
^cSchool of Computer Science and Engineering, Beihang University, Beijing 100191, China

Received:2026-02-26 Accepted:2026-04-02 Online:2027-01-18 Published:2026-10-30
Contact: *E-mail: tanll@ccelab.com.cn (L.-L. Tan), zhouych29@mail.sysu.edu.cn (Y. Zhou), liujunm@mail.sysu.edu.cn (J.-M. Liu).
About author:¹ Contributed equally to this work.
Supported by:
National Natural Science Foundation Project of China (22275214, 21975291), the Natural Science Foundation Project of Guangdong Province (2024A1515012076, 2022A1515011949), and the Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program (2024TQ08C327).

摘要/Abstract

摘要： 太阳能驱动的光催化水分解是实现可再生能源转化的重要途径, 其中染料敏化光电化学电池(DSPEC)因结构可调、成本可控而备受关注. 然而, DSPEC的实际应用受限于高效、稳定的水氧化催化剂(WOC)的缺乏. 共价有机框架(COFs)是一类具有高比表面积、可预先设计结构和周期性孔道的晶态多孔聚合物, 在催化领域展现出巨大潜力, 但将其作为WOC集成到DSPEC中的研究目前仍未见报道. 本研究合成了一种高结晶度的钴配位共价有机框架(TFPP-Co-COF), 并将其成功应用于DSPEC光阳极, 实现了高效、稳定的光驱动水氧化. 该工作不仅为DSPEC提供了一种新型高性能WOC, 也为COFs在太阳能燃料生产中的进一步应用开辟了新方向.
本文利用COFs的晶态结构与可功能化特性, 通过钴原子与卟啉环的配位引入催化活性中心, 构建具有高结晶度、大比表面积和均匀钴位点的TFPP-Co-COF. 同时, 制备无定形对照物(TFPP-Co-polymer)和无金属对照物(TFPP-COF), 系统对比晶态结构、钴位点以及界面电子转移对光阳极性能的影响. 通过溶剂热法合成TFPP-Co-COF, 傅里叶变换红外光谱证实亚胺键的形成及钴-氮配位; 粉末X-射线衍射显示其在3.3°处有尖锐衍射峰, Pawley精修验证高结晶性; 氮气吸附测试表明比表面积为730.3 m²/g, 平均孔径2.56 nm; 扫描电镜和透射电镜观察到清晰的晶格条纹(晶面间距2.60 nm), 像差校正透射电镜显示钴原子均匀分布(间距约2.5 nm). 将TFPP-Co-COF与N719光敏剂共负载于TiO₂/FTO光阳极. 光电化学测试表明: 在0 V vs. Ag/AgCl偏压下, 光阳极初始光电流密度达800 μA/cm², 200 s后仍保持700 μA/cm²; 在无偏压(0 V vs. NHE)条件下, 光电流密度为450 μA/cm², 25 min后保持400 μA/cm². 电化学阻抗谱显示TFPP-Co-COF具有最高的复合电阻和最低的电荷转移电阻. 发生器-收集器装置测得有偏压下析氧法拉第效率为88.8%, 无偏压下为71.6%. 此外, TFPP-Co-COF与纯有机染料C4BTP和DT1也表现出良好兼容性, 进一步证明其普适性. 在机理研究方面, 固体荧光光谱表明N719与TFPP-Co-COF混合后荧光显著猝灭, 证实从COF到光敏剂的高效电子转移; 荧光滴定得猝灭常数为–7.14 μL^–1, 远高于TFPP-COF的–5.67 μL^–1, 表明钴位点增强电子给体能力; X-射线光电子能谱显示光照后Co 2p峰正移0.20 eV, 直接证明钴作为电子给体. 密度泛函理论计算表明,水氧化通过钴位点的亲核水进攻路径进行, 最大吉布斯自由能垒在染料存在下从1.59降至0 eV, 而金属-free路径能垒更高.
综上, 本研究将晶态钴配位COF作为高效水氧化催化剂应用于DSPEC, 其优异性能源于高结晶度、高比表面积、均匀分散的钴活性位点及高效电子转移, 展示了COFs在太阳能水分解中的巨大潜力, 为太阳能驱动水分解提供了新的催化剂设计思路.

关键词: 染料敏化光电化学电池, 共价有机框架, 光敏剂, 水氧化催化剂, 太阳能水分解

Abstract: The development of efficient water oxidation catalysts is crucial for advancing dye-sensitized photoelectrochemical cells toward practical solar-driven water splitting. Herein, we synthesize a cobalt-coordinated covalent organic framework, TFPP-Co-COF, and integrate it with photosensitizers to construct high-performance photoanodes. The optimized electrode achieves an initial photocurrent density of 800 μA/cm² at 0 V vs. Ag/AgCl, maintaining 700 μA/cm² after 200 s with a Faradaic efficiency of 88.8%. Even under unbiased conditions (0 V vs. NHE), it delivers 450 μA/cm² (71.6% FE) and retains 400 μA/cm² over 25 min. Mechanistic studies confirm efficient electron transfer from TFPP-Co-COF to the photosensitizer. Theoretical calculations further reveal that water oxidation proceeds through a water nucleophilic attack pathway at cobalt sites, exhibiting a lower energy barrier than metal-free alternatives. The superior performance over amorphous analogs originates from enhanced crystallinity, high surface area, and abundant cobalt active sites that collectively promote charge separation and catalytic activity. TFPP-Co-COF also demonstrates excellent compatibility with pure organic dyes C4BTP and DT1, highlighting its versatility. This work pioneers COF application in DSPECs, providing a promising pathway for efficient solar fuel production.

Key words: Dye-sensitized photoelectrochemical cells, Covalent organic frameworks, Photosensitizers, Water oxidation catalysts, Solar water splitting

梁子展, 王晓林, 洪智林, 李鑫奥, 彭新邦, 谭礼林, 肖利民, 周业成, 刘军民. 钴配位共价有机框架用于染料敏化光电化学水分解[J]. 催化学报, 2027, 92: 248-261.

Zizhan Liang, Xiaolin Wang, Zhilin Hong, Xinao Li, Xinbang Peng, Lilin Tan, Limin Xiao, Yecheng Zhou, Junmin Liu. Cobalt-coordinated covalent organic framework as a versatile water oxidation catalyst in dye-sensitized photoelectrochemical cells for solar water splitting[J]. Chinese Journal of Catalysis, 2027, 92: 248-261.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(26)65196-0

https://www.cjcatal.com/CN/Y2027/V92/I1/248

参考文献

[1] Y. Li, B. Guan, J. Guo, Y. Chen, Z. Ma, Z. Zhuang, C. Zhu, H. Dang, L. Chen, K. Shu, K. Shi, Z. Guo, C. Yi, J. Hu, X. Hu, Z. Huang,J. Clean. Prod., 2024, 450, 141849.
[2] D. F. Bruggeman, A. A. H.Laporte, R. J. Detz, S. Mathew, J. N. H. Reek,Angew. Chem. Int. Ed., 2022, 61, e202200175.
[3] A. Tan, F. Zhao, Y. Zhang, G. Li, C. Wu, Z. Liu, J. Li, J. Liu,Chem. Eng. Sci., 2025, 302, 120814.
[4] X.-L. Wang, J.-F. Huang, J.-M. Liu, P. Tsiakaras,Coord. Chem. Rev., 2025, 522, 216143.
[5] A. Tan, J. Song, X. Qiu, Z. Liu, L. Xia, C. Ju, F. Zhao, G. Li, X. Shi, T. Li, P. Liu, J. Liu,Nat. Commun., 2025, 16, 9115.
[6] S. Kim, H. C. Kang, C. Chu, S. Li, K. Yoo, U. K. Wijethunga, W. Zheng, C. G. Yoo, B. D. Sherman, J.-J. Lee, G. Leem,Sustain. Energy Fuels, 2023, 7, 2339-2348.
[7] M. Grätzel,Nature, 2001, 414, 338-344.
[8] S. Chen, Y. Qi, T. Hisatomi, Q. Ding, T. Asai, Z. Li, S. S. K.Ma, F. Zhang, K. Domen, C. Li,Angew. Chem. Int. Ed., 2015, 54, 8498-8501.
[9] Y. Zhu, G. Liu, R. Zhao, H. Gao, X. Li, L. Sun, F. Li,Chem. Sci., 2022, 13, 4955-4961.
[10] C. Decavoli, C. L. Boldrini, F. Faroldi, L. Baldini, F. Sansone, A. Ranaudo, C. Greco, U. Cosentino, G. Moro, N. Manfredi, A. Abbotto,Eur. J. Org. Chem., 2022, 2022, e202200649.
[11] H. Huang, R. Cao, S. Yu, K. Xu, W. Hao, Y. Wang, F. Dong, T. Zhang, Y. Zhang,Appl. Catal. B, 2017, 219, 526-537.
[12] C. Decavoli, C. L. Boldrini, V. Trifiletti, S. Luong, O. Fenwick, N. Manfredi, A. Abbotto,RSC Adv., 2021, 11, 5311-5319.
[13] A. Dey, S. Chakraborty, A. Singh, F. A. Rahimi, S. Biswas, T. Mandal, T. K. Maji,Angew. Chem. Int. Ed., 2024, 63, e202403093.
[14] P. Zhao, Y. Zhang, B. Sun, R. Qiao, C. Li, P. Hai, Y. Wang, F. Liu, J. Song,Angew. Chem. Int. Ed., 2024, 63, e202317016.
[15] T. Kitano, S. Goto, X. Wang, T. Kamihara, Y. Sei, Y. Kondo, T. Sannomiya, H. Uekusa, Y. Murakami,Nat. Commun., 2025, 16, 280.
[16] B.-B. Luan, X. Chu, Y. Wang, X. Qiao, Y. Jiang, F.-M. Zhang,Adv. Mater., 2024, 36, 2412653.
[17] A. P.Côté, A. I. Benin, N. W. Ockwig, M. O’Keeffe, A. J. Matzger, O. M. Yaghi,Science, 2005, 310, 1166-1170.
[18] K.-T. Tan, S. Ghosh, Z. Wang, F. Wen, D. Rodríguez-San-Miguel, J. Feng, N. Huang, W. Wang, F. Zamora, X. Feng, A. Thomas, D. Jiang,Nat. Rev. Meth. Primers, 2023, 3, 1.
[19] B. An, B. Zheng, Z. Liu, Z. Wu, M. Wu, W. Wu,Curr. Opin. Green Sustain. Chem., 2023, 41, 100798.
[20] X. Zhan, Y. Jin, C. Qu, H. Liu, R. Jiang, Q. Zhi, D. Qi, K. Wang, B. Han, H. Pan, J. Jiang,Adv. Funct. Mater., 2025, 35, 2415629.
[21] J. Bai, M. Zhang, F. Si, Y. Li, G. Liang, T. Hou, Y. Li,Adv. Funct. Mater., 2025, 35, 2420218.
[22] B. Zhang, H. Li, Y. Kang, K. Yang, H. Liu, Y. Zhao, S. Qiao,Adv. Funct. Mater., 2025, 35, 2416958.
[23] J. Alemán, R. Mas-Ballesté,Front. Chem., 2021, 9, 708312.
[24] M. Lu, S.-B. Zhang, M.-Y. Yang, Y.-F. Liu, J.-P. Liao, P. Huang, M. Zhang, S.-L. Li, Z.-M. Su, Y.-Q. Lan,Angew. Chem. Int. Ed., 2023, 62, e202307632.
[25] Z. Xiao, H. Wu, L. Jiao, X. Zhang, Y. Wang,J. Mater. Chem. A, 2024, 12, 7515-7521.
[26] N. Lalaoui, M. Abdellah, K. L. Materna, B. Xu, H. Tian, A. Thapper, J. Sa, L. Hammarström, S. Ott,Dalton Trans., 2022, 51, 15716-15724.
[27] F. Li, R. Xu, C. Nie, X. Wu, P. Zhang, L. Duan, L. Sun,Chem. Commun., 2019, 55, 12940-12943.
[28] C. D. Windle, H. Kumagai, M. Higashi, R. Brisse, S. Bold, B. Jousselme, M. Chavarot-Kerlidou, K. Maeda, R. Abe, O. Ishitani, V. Artero,J. Am. Chem. Soc., 2019, 141, 9593-9602.
[29] B. Shan, M. K. Brennaman, L. Troian-Gautier, Y. Liu, A. Nayak, C. M. Klug, T.-T. Li, R. M. Bullock, T. J. Meyer,J. Am. Chem. Soc., 2019, 141, 10390-10398.
[30] K. Tang, J.-Y. Shao, Y. Yan, Y.-W. Zhong,Langmuir, 2024, 40, 6244-6252.
[31] X.-L. Wang, X.-A. Li, M.-P. Tan, Z.-Z. Liang, Q.-Z. Chen, J.-F. Huang, L.-M. Xiao, J.-M. Liu,J. Mater. Chem. A, 2024, 12, 22101-22111.
[32] X.-L. Wang, L.-L. Tan, Y. Liu, J.-X. Liu, X.-A. Li, Z.-Z. Liang, J.-F. Huang, J.-M. Liu,ChemSusChem, 2025, 18, e202402395.
[33] Y. Liu, Y. Ma, Y. Zhao, X. Sun, F. Gándara, H. Furukawa, Z. Liu, H. Zhu, C. Zhu, K. Suenaga, P. Oleynikov, A. S. Alshammari, X. Zhang, O. Terasaki, O. M. Yaghi,Science, 2016, 351, 365-369.
[34] S. Xie, R. Liu, N. Liu, H. Xu, X. Chen, X. Wang, D. Jiang,Angew. Chem. Int. Ed., 2025, 64, e202416771.
[35] W.-K. Han, Y. Liu, J.-D. Feng, X. Yan, H. Pang, Z.-G. Gu,Chem. Sci., 2023, 14, 11768-11774.
[36] M. Sicignano, T. Gobbato, R. Bonetto, P. Centomo, B. Di Vizio, F. De Biasi, D. Rosa-Gastaldo, C. Pierantoni, A. Bonetto, A. Glisenti, P. Costa,Adv. Sustain. Syst., 2025, 9, 2400653.
[37] T. Luo, X.-A. Li, C.-J. Bai, C.-Y. Lv, J.-F. Huang, J.-M. Liu,ACS Appl. Energy Mater., 2021, 4, 14671-14680.
[38] J.-F. Huang, Y. Lei, L.-M. Xiao, X.-L. Chen, Y.-H. Zhong, S. Qin, J.-M. Liu,ChemSusChem, 2020, 13, 1037-1043.
[39] D. Antón-García, J. Warnan, E. Reisner,Chem. Sci., 2020, 11, 12769-12776.
[40] T. Luo, J. Huang, J. Liu,Chem. Res. Chin. Univ., 2020, 36, 1091-1096.
[41] G. Kresse, J. Furthmüller,Phys. Rev. B, 1996, 54, 11169-11186.
[42] G. Kresse, J. Furthmüller,Comput. Mater. Sci., 1996, 6, 15-50.
[43] J. P. Perdew, K. Burke, M. Ernzerhof,Phys. Rev. Lett., 1997, 78, 1396-1396.
[44] J. P. Perdew, K. Burke, M. Ernzerhof,Phys. Rev. Lett., 1996, 77, 3865-3868.
[45] S. Grimme, J. Antony, S. Ehrlich, H. Krieg,J. Chem. Phys., 2010, 132, 154104.
[46] K. Momma, F. Izumi,J. Appl. Crystallogr., 2011, 44, 1272-1276.
[47] R. M. Hanson, J. Prilusky, R. Zhou, T. Nakane, J. L. Sussman,Isr. J. Chem., 2013, 53, 207-216.
[48] A. Laemont, G. Matthys, R. Lavendomme, P. Van Der Voort,Angew. Chem. Int. Ed., 2024, 63, e202412420.
[49] M. Lu, M. Zhang, J. Liu, T.-Y. Yu, J.-N. Chang, L.-J. Shang, S.-L. Li, Y.-Q. Lan,J. Am. Chem. Soc., 2022, 144, 1861-1871.
[50] Z. Pu, B. Xiao, S. Mao, Y. Sun, D. Ma, H. Wang, J. Zhou, Y. Cheng, J.-W. Shi,J. Colloid Interface Sci., 2022, 628, 477-487.
[51] J.-N. Chang, Q. Li, J.-W. Shi, M. Zhang, L. Zhang, S. Li, Y. Chen, S.-L. Li, Y.-Q. Lan,Angew. Chem. Int. Ed., 2023, 62, e202218868.
[52] Z. Tariq, S. U. Rehman, X. Zhang, F. K. Butt, S. Feng, B. U. Haq, B. Cheng, C. Li,Int. J. Hydrogen Energy, 2021, 46, 28110-28120.
[53] Y. Yusran, H. Li, X. Guan, D. Li, L. Tang, M. Xue, Z. Zhuang, Y. Yan, V. Valtchev, S. Qiu, Q. Fang,Adv. Mater., 2020, 32, 1907289.
[54] Q. Wang, Z. Yu, X. Sun, J. Lan,Micro Nano Lett., 2017, 12, 974-977.
[55] A. Natraj, I. R. Landman, C. E. Pelkowski, D. W. Burke, S. Kewalramani, W. R. Dichtel,J. Am. Chem. Soc., 2024, 146, 16775-16786.
[56] D. Inácio, A. L. Pinto, A. B. Paninho, L. C. Branco, S. K. S.Freitas, H. Cruz,Nanomaterials, 2023, 13, 1204.
[57] J. Li, C. Ren, L. Zhang, W. Jiang, H. Liu, J. Su, M. Li,J. Energy Chem., 2022, 65, 205-209.
[58] R. Yang, Q. Chen, G. Huang, J. Bi,Environ. Res., 2023, 216, 114541.
[59] Y. Liu, H. Cheng, M. Lyu, S. Fan, Q. Liu, W. Zhang, Y. Zhi, C. Wang, C. Xiao, S. Wei, B. Ye, Y. Xie,J. Am. Chem. Soc., 2014, 136, 15670-15675.
[60] R. Zhang, Z. Yuan, X. Qiu, Z. Rui, X. Shi, J. Li, A. Tan, J. Liu,J. Mater. Chem. A, 2025, 13, 32416-32426.
[61] W. Yang, L. Si, C. Cheng, Y. Cui, X. Yan, M. Liu, D. Jing, J. Shi, L. Guo,Adv. Funct. Mater., 2026, 36, e12738.
[62] F. Xue, J. Zhang, Z. Wang,ACS Catal., 2024, 14, 5377-5388.
[63] X. Kang, J. Shi, Y. Liu, L. Mao, B. Zhai, Y. Jiang, W. Xiao, H. Jin, L. Guo,J. Mater. Sci. Technol., 2026, 269, 24-32.
[64] F. T. Krauss, I. Pantenburg, V. Lehmann, M. Stich, J. O. Weiershäuser, A. Bund, B. Roling,J. Am. Chem. Soc., 2024, 146, 19009-19018.
[65] S. A. Badawy, E. Abdel-Latif, A. A. Fadda, M. R. Elmorsy,Sci. Rep., 2022, 12, 12885.
[66] T. Nakazono, A. R. Parent, K. Sakai,Chem. Eur. J., 2015, 21, 6723-6726.
[67] S. R. Raga, E. M. Barea, F. Fabregat-Santiago,J. Phys. Chem. Lett., 2012, 3, 1629-1634.
[68] J. Zhang, J. Zhang, C. Dong, Y. Xia, L. Jiang, G. Wang, R. Wang, J. Chen,Small, 2023, 19, 2208049.
[69] Z. Bai, Y. Liu, P. Zhang, J. Guo, Y. Ma, X. Yun, X. Zhao, R. Zhong, F. Zhang,Luminescence, 2016, 31, 688-693.
[70] X. Zhang, H. Zhong, Q. Zhang, Q. Zhang, C. Wu, J. Yu, Y. Ma, H. An, H. Wang, Y. Zou, C. Diao, J. Chen, Z.-G. Yu, S. Xi, X. Wang, J. Xue,Nat. Commun., 2024, 15, 1383.
[71] X. Cui, H. Bai, J. Zhang, R. Liu, H. Yu, Y. Wang, T. Kong, M.-Y. Gao, Z. Lu, Y. Xiong,Nat. Commun., 2024, 15, 9048.
[72] T. Nakazono, A. R. Parent, S. Ken,Chem. Commun., 2013, 49, 6325.

钴配位共价有机框架用于染料敏化光电化学水分解

Cobalt-coordinated covalent organic framework as a versatile water oxidation catalyst in dye-sensitized photoelectrochemical cells for solar water splitting

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	张养鹏, 吴优, 顾钱锋, 高玥, 蔡陈枨, 刘浩宇, 赵悦含, 李中华, 张凤鸣, 刘扬, 张其春. 同构共价有机框架局域电子不对称促进电荷分离用于高效光合成H₂O₂[J]. 催化学报, 2027, 92(1): 130-144.
[2]	李东珀, 毛倩倩, 熊超, 系璐颖, 聂宇, 徐啸天, 纪红兵. 构建钌卟啉共价有机框架催化金刚烷C-H键空气氧化接力实现烯烃环氧化[J]. 催化学报, 2026, 88(9): 442-456.
[3]	张可可, 张富林, 王月欣, 黄凤伟, 熊康慧, 顾向奎, 郎贤军. 调控亚乙烯基连接的噻吩并噻吩共价有机框架的电子推拉效应以增强选择性光催化[J]. 催化学报, 2026, 87(8): 206-216.
[4]	李晗溪, 罗振东, 薛强, 支云飞, 杜骏, 周旭凯. 基于Povarov环化的共价有机框架孔道与电荷动力学调控及其光催化产氢增强[J]. 催化学报, 2026, 86(7): 363-374.
[5]	刘家英, 方煜. 揭示二维共价有机框架光催化的结构-活性关系: 从分子工程到高性能优化[J]. 催化学报, 2026, 85(6): 47-87.
[6]	孙冉, 张雨琦, 侯琨格, 谭钰杰, 刘新刚, 侯剑源, 赵玮璇, Andrew E. H. Wheatley, 张仁熙. 共价有机框架中氢键的构筑: 加速质子耦合电子转移以提升光催化合成过氧化氢性能[J]. 催化学报, 2026, 84(5): 274-287.
[7]	吴静尧, 吕昱静, 赵强, 王朔, 汪颖, 温娜, 丁正新, 张子重, 龙金林. 共价有机框架的电子-质子双重奏: 高效催化氧气直接还原生成过氧化氢[J]. 催化学报, 2026, 84(5): 288-300.
[8]	谢文奥, 贾治芳, 舒畅, 王婷霞, 席建红, 蔡佳轩, 宋向阳, 车瑜, 王笑颜, 王科伟, 谭必恩. 氰基功能化的共价有机框架通过微环境调节增强光催化性能制备过氧化氢[J]. 催化学报, 2026, 83(4): 282-293.
[9]	魏滔, 梁展鹏, 张博心, 徐赟浩, 孙兆雪, 多名昊, 陈铭晖, 张生, 张宝. 基于4-二甲氨基吡啶(DMAP)亲核催化剂构建结晶性聚金属酞菁基共价有机框架用于高效电催化CO₂还原[J]. 催化学报, 2026, 83(4): 319-329.
[10]	李宫, 柏景森, 王丹, 梁亮, 汝春宇, 宫雪, 邵敏华, 刘长鹏, 肖梅玲, 邢巍. 空心共价有机框架衍生碳载体提升PtCo合金催化剂在燃料电池氧还原反应中的活性与稳定性[J]. 催化学报, 2026, 83(4): 294-307.
[11]	李冬华, 胡洪寅, 周锦烨, 缪涵韵, 武宇, 王金艳, 郭宝春, 杜明亮, 陆双龙. 切换卟啉基共价有机框架中金属位点调控电催化亚硝酸盐还原反应的产物选择性[J]. 催化学报, 2026, 83(4): 258-270.
[12]	谢可慧, 刘从学, 耿琰, 阚京兰, 王广博, 董育斌. 苯并三噻吩基共价有机框架连接结构调控实现高效光合成H₂O₂[J]. 催化学报, 2026, 83(4): 271-281.
[13]	张如梦, 林沐珂, 焦奕木, 陈诚, 胡孟良, 周昊, 夏德华. Fe(III)介导的无金属吡啶基COF自维持光芬顿系统: 界面电子转移驱动水净化[J]. 催化学报, 2026, 82(3): 225-237.
[14]	陆家平, 林超, 李超, 石泓杰, 刘能益, 邢万东, 汪思波, 张贵刚, 陈藤藤, 陈雄. 联吡啶整合的双恶唑基给体-受体共价有机框架用于增强光催化过氧化氢合成[J]. 催化学报, 2026, 81(2): 185-194.
[15]	文忠梁, 邓茂君, 冯潇, Pascal Van der Voort. 非共轭连接三维共价有机框架维持高还原电位用于光催化氧化反应[J]. 催化学报, 2026, 91(12): 386-395.