Pd/Bi2O3异质结构强金属-载体相互作用增强生物质电氧化升级转化性能

doi:10.1016/S1872-2067(26)65201-1

催化学报 ›› 2026, Vol. 91: 304-314.DOI: 10.1016/S1872-2067(26)65201-1

Pd/Bi₂O₃异质结构强金属-载体相互作用增强生物质电氧化升级转化性能

杨涵越, 温家家, 肖雪^*(), 陈煜^*()

陕西师范大学材料科学与工程学院, 应用表面与胶体化学教育部重点实验室, 陕西省大分子科学重点实验室, 陕西省先进能源器件重点实验室, 陕西省先进能源技术工程实验室, 陕西西安 710062

收稿日期:2026-04-07 接受日期:2026-05-27 出版日期:2026-12-18 发布日期:2026-10-13
通讯作者: ^*电子信箱: tiffanyxx110@gmail.com (肖雪),
ndchenyu@gmail.com (陈煜).
基金资助:
国家自然科学基金(22272103);陕西师范大学材料科学与工程学院“青年科学家”研究生创新基金项目(2023YSIP-MSE-SNNU008);陕西省科技创新领军人才计划

Interfacial charge transfer via SMSI in heterostructured Pd/Bi₂O₃: A paradigm for sustainable electrochemical biomass upcycling

Han-Yue Yang, Jia-Jia Wen, Xue Xiao^*(), Yu Chen^*()

Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), Key Laboratory of Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Lab for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710062, Shaanxi, China

Received:2026-04-07 Accepted:2026-05-27 Online:2026-12-18 Published:2026-10-13
Supported by:
National Natural Science Foundation of China(22272103);Young Scientist Initiative Project of School of Materials Science and Engineering at Shaanxi Normal University(2023YSIP-MSE-SNNU008);Technology Innovation Leading Program of Shaanxi in China

摘要/Abstract

摘要：

乙二醇(EG)是一种重要的平台分子, 既可通过废弃聚对苯二甲酸乙二醇酯(PET)的解聚获得，也可由生物质资源转化制得. 通过电催化乙二醇氧化反应(EGOR)将EG选择性转化为乙醇酸(GA), 不仅能够实现废弃塑料和可再生碳资源的高值化利用, 还可以在阴极耦合析氢反应, 实现高附加值化学品与绿色氢气的协同生产. 与传统热催化氧化工艺相比, 电催化转化过程具有反应条件温和、能源输入可由可再生电力提供、产物调控灵活以及环境负荷较低等优势. 然而, EGOR涉及多电子转移和复杂的C-H/C-OH键活化过程, 反应过程中易生成强吸附中间体并造成催化剂表面中毒. 同时, 过度氧化或C-C键断裂也会降低目标产物GA的选择性. 因此, 开发兼具高活性、高选择性和良好稳定性的EGOR电催化剂, 是实现EG绿色高值化转化的关键.
本文合成了一种新型0D/2D异质结构电催化剂, 即将Pd纳米晶均匀锚定于超薄Bi₂O₃纳米片上, 制备得到Pd-NCs/Bi₂O₃-NSs催化剂, 利用金属-载体强相互作用(SMSI)实现EGOR反应活性与选择性的协同优化. 物理表征结果表明, 超薄Bi₂O₃纳米片能够为Pd纳米晶提供丰富的锚定位点, 有效抑制金属纳米颗粒的团聚, 并构筑紧密接触的Pd-O-Bi异质界面. 光谱分析和密度泛函理论计算显示Pd与Bi₂O₃之间的界面耦合作用能够诱导电子由Bi₂O₃载体向Pd活性位点转移, 从而形成富电子Pd位点并调节其d带电子结构. 电子结构优化有助于促进EG分子的吸附与C-OH键活化, 同时削弱反应中间体在Pd表面的过强吸附, 降低中间体毒化对催化过程的影响. 此外, 亲氧性的Bi₂O₃载体可促进水分子活化并生成OH*物种, 进一步加速含氧中间体的转化过程. Pd活性位点与Bi₂O₃载体之间的协同作用可有效优化关键反应步骤的能垒和中间体吸附行为, 从而提高了EG向GA选择性氧化的反应效率. 电化学测试显示Pd-NCs/Bi₂O₃-NSs表现出优异的EG电氧化性能, 质量活性达到5.81 A mg_Pd^-1, 较单金属Pd提升3.8倍, 生成GA法拉第效率高达92.1%, 并在连续运行过程中保持了良好的稳定性. 技术经济分析表明, 其GA生产成本低至2.625美元/公斤; 生命周期评估结果显示, 相较传统工艺, 其全球变暖潜能值可降低70%, 证明其在经济性和环境可持续性方面均具有明显优势.
综上, 本文通过构筑Pd-NCs/Bi₂O₃-NSs异质结构催化剂, 实现了PET衍生EG向GA的高效、高选择性电催化转化. 实验测试和理论计算均显示, 利用SMSI调控金属活性位点电子结构, 结合亲氧氧化物载体促进OH*生成, 是提升EGOR反应活性、选择性和稳定性的有效策略. 本工作不仅为塑料废弃物和生物质衍生小分子的绿色高值化利用提供了高效催化体系, 也为金属/氧化物异质结构催化剂的理性设计提供了新的思路.

关键词: 强金属-载体相互作用, 乙二醇电氧化反应, 生物质增值, 聚对苯二甲酸乙二酯升级回收, 异质结构催化剂

Abstract:

The electrochemical oxidation of ethylene glycol (EG) to glycolic acid (GA) represents a promising route for valorizing plastic waste and biomass-derived feedstocks while co-producing hydrogen. However, existing catalysts are limited by low selectivity, rapid deactivation, and high overpotentials. Herein, we report a 0D/2D heterostructured catalyst, Pd-NCs/Bi₂O₃-NSs, in which Pd nanocrystals are uniformly anchored on ultrathin Bi₂O₃ nanosheets. Spectroscopic studies and density functional theory calculations reveal that the strong Pd-O-Bi interfacial interactions induce charge transfer from Bi₂O₃ to Pd, generating electron-rich Pd sites with a downshifted d-band center. Together with the effect of oxophilic Bi₂O₃, this optimizes reaction energetics and suppresses intermediate poisoning. As a result, the catalyst delivers 5.81 A mg_Pd^-1 mass activity, 92.1% Faradaic efficiency for GA, and excellent durability. Techno-economic and life-cycle analyses further confirm its cost competitiveness and environmental benefits.

Key words: Strong metal-support interaction, Ethylene glycol electrooxidation, Biomass valorization, Polyethylene terephthalate upcycling, Heterostructured catalysts

杨涵越, 温家家, 肖雪, 陈煜. Pd/Bi₂O₃异质结构强金属-载体相互作用增强生物质电氧化升级转化性能[J]. 催化学报, 2026, 91: 304-314.

Han-Yue Yang, Jia-Jia Wen, Xue Xiao, Yu Chen. Interfacial charge transfer via SMSI in heterostructured Pd/Bi₂O₃: A paradigm for sustainable electrochemical biomass upcycling[J]. Chinese Journal of Catalysis, 2026, 91: 304-314.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(26)65201-1

https://www.cjcatal.com/CN/Y2026/V91/I12/304

图/表 6

Scheme 1. Formation and SMSI of Pd nanoclusters anchored on ultrathin Bi2O3 nanosheets via Galvanic Replacement.

Fig. 1. (a) TEM image of Bi NSs. TEM image (b), HAADF-STEM image (c), AFM image (d), HR-TEM (e), lattice strain measured from GPA (f), and STEM-EDX elemental mapping images (g) of Pd-NCs/Bi2O3-NSs.

Fig. 2. (a) XRD pattern of Pd-NCs/Bi2O3-NSs. (b) Pd 3d XPS spectra of Pd-NCs/Bi2O3-NSs and Pd NCs. (c) Bi 4f XPS spectra of Pd-NCs/Bi2O3-NSs and Bi2O3 NSs. (d) WT-EXAFS spectra of Pd foil, Pd-NCs/Bi2O3-NSs, and PdO. (e) FT-EXAFS spectra of Pd foil, Pd-NCs/Bi2O3-NSs, and PdO. (f) FT-EXAFS spectra of Bi foil, Pd-NCs/Bi2O3-NSs and Bi2O3. (g) PDOS (d-band) of Pd and Pd-NCs/Bi2O3-NSs. (h) WT-EXAFS spectra of Bi foil, Pd-NCs/Bi2O3-NSs and Bi2O3. (i) COHP curve of the Pd bond in the Pd. (j) COHP curve of the Pd-Bi bond in the Pd-NCs/Bi2O3-NS.

Fig. 3. (a) CV curves of Pd-NCs/Bi2O3-NSs and Pd NCs in 1 mol L-1 KOH + 1 mol L-1 EG. (b) Corresponding Tafel slopes. Nyquist plots (c) and Arrhenius plots (d) of Pd-NCs/Bi2O3-NSs and Pd NCs. (e) FEGA of EGOR by Pd-NCs/Bi2O3-NSs and Pd NCs at different potentials. Data are presented as mean ± SD. Error bars (SD) represent the standard deviation of three separate measurements. (f) Comparison of the EGOR performance between this work and that of reported catalysts.

Fig. 4. (a) Open circuit potentials (OCPs) of Pd-NCs/Bi2O3-NSs in 1 mol L-1 KOH solution before and after 1 mol L-1 EG was added, and 1 mol L-1 KOH before and after 1 mol L-1 GA was added. (b) Corresponding Bode phase plots of Pd-NCs/Bi2O3-NSs electrode at varied potentials in 1 mol L-1 KOH with 1 mol L-1 EG. (c) In-situ Raman spectra of Pd-NCs/Bi2O3-NSs. (d) In-situ electrochemical FTIR spectra of EGOR catalyzed by Pd-NCs/Bi2O3-NSs. Calculated adsorption energies of EG* and OH* (e), and GA* and CO* (f), on the surfaces of Pd and Pd-NCs/Bi2O3-NSs. (g) Reaction Gibbs free energy of EGOR on Pd and Pd-NCs/Bi2O3-NSs.

Fig. 5. (a) The flow cell setup for paired HER (-) || EG oxidation (+) of Pt mesh and Pd-NCs/Bi2O3-NSs. (b) LSV curves for water splitting and EG electrolysis in the flow cell reactor. (c) Faradaic efficiency as function of current density for EG oxidation. (d) Sankey diagram for the mass flow of PET upcycling. (e) Subdivided the cost of the process. (f,g) LCOP for processing PET as function of current density, electrolysis energy, and faradic efficiency. (h) GWP of the conventional path and the system to produce GA powered by renewable power and thermal power.

参考文献

[1]	A. S. Pottinger, R. Geyer, N. Biyani, C. C. Martinez, N. Nathan, M. R. Morse, C. Liu, S. Hu, M. de Bruyn, C. Boettiger, E. Baker, D. J. McCauley, Science, 2024, 386, 1168-1173.
[2]	K. L. Law, N. Starr, T. R. Siegler, J. R. Jambeck, N. J. Mallos, G. H. Leonard, Sci. Adv., 2020, 6, eabd0288.
[3]	Q. Lu, Z. Wang, J. Guan, J. Catal., 2026, 453, 116462.
[4]	X. Zhu, Y. Ding, S. Li, Y. Jiang, Y. Chen, Sci. Bull., 2024, 69, 483-491.
[5]	R. Xia, R. Wang, B. Hasa, A. Lee, Y. Liu, X. Ma, F. Jiao, Nat. Commun., 2023, 14, 4570.
[6]	Y. Lum, J. E. Huang, Z. Wang, M. Luo, D.-H. Nam, W. R. Leow, B. Chen, J. Wicks, Y. C. Li, Y. Wang, C.-T. Dinh, J. Li, T.-T. Zhuang, F. Li, T.-K. Sham, D. Sinton, E. H. Sargent, Nat. Catal., 2020, 3, 14-22.
[7]	K. Liu, X. Gao, C.-X. Liu, R. Shi, E. C. M. Tse, F. Liu, Y. Chen, Adv. Energy Mater., 2024, 14, 2304065.
[8]	S. Bhattacharjee, M. Rahaman, V. Andrei, M. Miller, S. Rodríguez-Jiménez, E. Lam, C. Pornrungroj, E. Reisner, Nat. Synth., 2023, 2, 182-192.
[9]	F. L. Liu, X. T. Gao, R. Shi, Z. X. Guo, E. C. M. Tse, Y. Chen, Angew. Chem. Int. Ed., 2023, 62, e202300094.
[10]	M. Li, T. Xia, M. Wang, Y. Peng, S. Zhang, X. Jiang, H. Yang, Chin. J. Struct. Chem., 2025, 44, 100627.
[11]	X. Zhou, M. Zha, J. Cao, H. Yan, X. Feng, D. Chen, C. Yang, ACS Sustainable Chem. Eng., 2021, 9, 10948-10962.
[12]	W. Jiang, C. Zhu, H.-G. Xu, J.-K. Liu, Y.-X. Wu, S. Cao, H.-Y. Yuan, P.-F. Liu, Y. Zhou, Chem. Eng. J., 2025, 515, 163804.
[13]	H. Kang, D. He, X. Yan, B. Dao, N. B. Williams, G. I. Elliott, D. Streater, J. Nyakuchena, J. Huang, X. Pan, X. Xiao, J. Gu, ACS Catal., 2024, 14, 5314-5325.
[14]	Y. Qin, W. Zhang, F. Wang, J. Li, J. Ye, X. Sheng, C. Li, X. Liang, P. Liu, X. Wang, X. Zheng, Y. Ren, C. Xu, Z. Zhang, Angew. Chem. Int. Ed., 2022, 61, e202200899.
[15]	J. Lai, F. Lin, Y. Tang, P. Zhou, Y. Chao, Y. Zhang, S. Guo, Adv. Energy Mater., 2019, 9, 1800684.
[16]	A. Zalineeva, A. Serov, M. Padilla, U. Martinez, K. Artyushkova, S. Baranton, C. Coutanceau, P. B. Atanassov, Appl. Catal. B, 2015, 176-177, 429-435.
[17]	X.-L. Xing, Y.-F. Zhao, H. Li, C.-T. Wang, Q.-X. Li, W.-B. Cai, J. Electrochem. Soc., 2018, 165, J3259-J3265.
[18]	R. Kannan, A. R. Kim, D. J. Yoo, J. Appl. Electrochem., 2014, 44, 893-902.
[19]	N. Zhang, J. Li, W. Liang, Y. Zhang, Z. Wu, Y. Du, Inorg. Chem., 2024, 63, 7063-7070.
[20]	H. Xu, P. Song, C. Fernandez, J. Wang, M. Zhu, Y. Shiraishi, Y. Du, ACS Appl. Mater. Interfaces, 2018, 10, 12659-12665.
[21]	S. Li, J. Lai, R. Luque, G. Xu, Energy Environ. Sci., 2016, 9, 3097-3102.
[22]	Y. Guan, J. Liu, P. Liu, J. Zhang, Y. Liu, J. Zhang, Z. Xia, X. Liu, J. He, Nano Res. Energy, 2025, 4, e9120167.
[23]	F. Zhao, Q. Yuan, S. Nie, L. Wu, X. Wang, J. Energy Chem., 2024, 92, 142-150.
[24]	M. K. Debe, Nature, 2012, 486, 43-51.
[25]	X. Bai, T. Tang, J. Sun, F. Bai, J. Hu, J. Guan, Chin. J. Catal., 2026, 80, 248-257.
[26]	Y. T. Yu, Z. J. Zhu, H. W. Huang, Adv. Mater., 2024, 36, 2311148.
[27]	Y. C. Huang, J. J. Xiong, Z. G. Zou, Z. X. Chen, Adv. Mater., 2025, 37, 2312182.
[28]	S. Chen, C. Pei, J. Gong, Energy Environ. Sci., 2019, 12, 3473-3495.
[29]	J. Zhang, F. K. Busari, Y. Zhang, S. Guo, Y. Zhao, B. Wang, Q. Zeng, Z. Zhao, G. Li, Nano Res. Energy, 2025, 4, e9120140.
[30]	J. C. Matsubu, S. Zhang, L. DeRita, N. S. Marinkovic, J. G. Chen, G. W. Graham, X. Pan, P. Christopher, Nat. Chem., 2017, 9, 120-127.
[31]	S. Li, Y. Xu, Y. Chen, W. Li, L. Lin, M. Li, Y. Deng, X. Wang, B. Ge, C. Yang, S. Yao, J. Xie, Y. Li, X. Liu, D. Ma, Angew. Chem. Int. Ed., 2017, 56, 10761-10765.
[32]	W. Wang, C. Li, C. Zhou, X. Xiao, F. Li, N.-Y. Huang, L. Li, M. Gu, Q. Xu, Angew. Chem. Int. Ed., 2024, 63, e202406947.
[33]	C. Dong, R. Li, Z. Qu, Y. Fan, J. Wang, X. Du, C. Liu, X. Feng, Y. Ning, R. Mu, Q. Fu, X. Bao, J. Am. Chem. Soc., 2025, 147, 13210-13219.
[34]	N. H. M. Dostagir, R. Rattanawan, M. Gao, J. Ota, J.-Y. Hasegawa, K. Asakura, A. Fukouka, A. Shrotri, ACS Catal., 2021, 11, 9450-9461.
[35]	M. Tang, S. Li, S. Chen, Y. Ou, M. Hiroaki, W. Yuan, B. Zhu, H. Yang, Y. Gao, Z. Zhang, Y. Wang, Angew. Chem. Int. Ed., 2021, 60, 22339-22344.
[36]	J. Zhang, J. Ma, T. S. Choksi, D. Zhou, S. Han, Y.-F. Liao, H.-B. Yang, D. Liu, Z. Zeng, W. Liu, X. Sun, T. Zhang, B. Liu, J. Am. Chem. Soc., 2022, 144, 2255-2263.
[37]	H. C. Zhang, H. M. Xu, C. J. Huang, H. R. Zhu, G. R. Li, Inorg. Chem., 2025, 64, 4713-4748.
[38]	F. Polo-Garzon, T. F. Blum, Z. Bao, K. Wang, V. Fung, Z. Huang, E. E. Bickel, D.-E. Jiang, M. Chi, Z. Wu, ACS Catal., 2021, 11, 1938-1945.
[39]	Z. Li, Y. Yan, S.-M. Xu, H. Zhou, M. Xu, L. Ma, M. Shao, X. Kong, B. Wang, L. Zheng, H. Duan, Nat. Commun., 2022, 13, 147.
[40]	Y. Wen, H. Abe, K. Mitsuishi, A. Hashimoto, Nanoscale, 2021, 13, 18987-18995.
[41]	H. Xie, Z. Li, L. Cheng, A. Ali Haidry, J. Tao, Y. Xu, K. Xu, J.-Z. Ou, IScience, 2022, 25, 103598.
[42]	B.-Q. Miao, W.-S. Fang, B. Sun, F.-M. Li, X.-C. Wang, B.-Y. Xia, Y. Chen, Chin. J. Struct. Chem., 2023, 42, 100095.
[43]	Y. Liu, Z. Zhuang, Y. Liu, N. Liu, Y. Li, Y. Cheng, J. Yu, R. Yu, D. Wang, H. Li, Angew. Chem. Int. Ed., 2024, 63, e202411396.
[44]	Z. Yang, Y. Ding, W. Chen, S. Luo, D. Cao, X. Long, L. Xie, X. Zhou, X. Cai, K. Liu, X.-Z. Fu, J.-L. Luo, Adv. Mater., 2025, 37, 2417777.
[45]	L. Lin, X. Y. He, X. G. Zhang, W. C. Ma, B. Zhang, D. Y. Wei, S. J. Xie, Q. H. Zhang, X. D. Yi, Y. Wang, Angew. Chem. Int. Ed., 2023, 62, e202214959.
[46]	A. A. Dubale, Y. Zheng, H. Wang, R. Hübner, Y. Li, J. Yang, J. Zhang, N. K. Sethi, L. He, Z. Zheng, W. Liu, Angew. Chem. Int. Ed., 2020, 59, 13891-13899.
[47]	S. Xie, J. Fu, Q. Huang, W. Yang, A. Yu, Y. Yan, Z. Li, P. Peng, Y. Yin, H. Wang, L. Echegoyen, F.-F. Li, Angew. Chem. Int. Ed., 2025, 64, e202506044.
[48]	D. Si, B. Xiong, L. Chen, J. Shi, Chem. Catal., 2021, 1, 941-955.
[49]	C. He, Y. Yan, Y. Fu, C. Ma, J. Xia, S. Han, H. Zhang, X. Ma, G. Lin, F. Feng, X. Meng, W. Cao, L. Zhu, Z. Li, Q. Lu, Adv. Mater., 2025, 37, 2418959.
[50]	Y. Yan, H. Zhou, S.-M. Xu, J. Yang, P. Hao, X. Cai, Y. Ren, M. Xu, X. Kong, M. Shao, Z. Li, H. Duan, J. Am. Chem. Soc., 2023, 145, 6144-6155.
[51]	D. Si, K. Shi, B. Huang, L. Chen, J. Shi, CCS Chem., 2025, 7, 1722-1730.
[52]	D. Jang, M. Park, J. Maeng, J. Ha, S. Choi, N. Kim, M. H. Seo, W. B. Kim, Small, 2024, 20, 2404540.
[53]	F. Ma, C. Zhang, W. Li, R. Hu, Z. Wang, J. Wang, J. Li, Y. Nie, Z. Zheng, X. Jiang, ACS Catal., 2025, 15, 4759-4769.
[54]	T. Ren, Z. Duan, H. Wang, H. Yu, K. Deng, Z. Wang, H. Wang, L. Wang, Y. Xu, ACS Catal., 2023, 13, 10394-10404.
[55]	J. L. Chen, M. M. Jiang, F. Z. Zhang, L. Wang, J. P. Yang, Adv. Mater., 2024, 36, 2401867.
[56]	X. Hu, W. Qiao, Y. Hu, F. Li, Y. Yang, Z. Jiang, Y. Yu, J. Fang, P. Li, Green Chem., 2025, 27, 6512-6524.
[57]	H. Wu, H. Tian, W. S. Luo, Y. F. Huang, X. Z. Cui, J. L. Shi, J. Am. Chem. Soc., 2026, 148, 24074-24083.
[58]	L. Xiao, Z. Wang, J. Guan, Chin. J. Catal., 2026, 80, 59-91.
[59]	S. Han, L. Sun, D. Fan, B. Liu, Nat. Commun., 2025, 16, 3426.
[60]	X. Wang, W. Wang, B. Liu, Z. Song, Z. Ren, H. Fu, Small, 2023, 19, 2304084.
[61]	G. R. Xu, Z. M. Dong, Y. X. Zhao, W. Zhang, Q. Y. Sun, D. X. Ju, L. Wang, Small, 2023, 20, 2306341.
[62]	L. Wang, W. Yan, Q. Yu, L. Liu, C.-W. Kao, Y.-C. Huang, T.-S. Chan, Z. Hu, H. Lin, D. Shen, X. Huang, Y. Li, Small, 2024, 20, 2403448.
[63]	J. Li, L. Li, X. Ma, X. Han, C. Xing, X. Qi, R. He, J. Arbiol, H. Pan, J. Zhao, J. Deng, Y. Zhang, Y. Yang, A. Cabot, Adv. Sci., 2023, 10, 2300841.
[64]	H. Wang, B. Jiang, T.-T. Zhao, K. Jiang, Y.-Y. Yang, J. Zhang, Z. Xie, W.-B. Cai, ACS Catal., 2017, 7, 2033-2041.
[65]	W. Li, Q. Bao, F. Ma, W. Xie, J. Song, X. Xu, Z. Liu, Z. Wang, P. Wang, H. Cheng, Y. Liu, Y. Dai, Y. Li, B. Huang, Z. Zheng, Appl. Catal. B, 2025, 374, 125375.
[66]	Y. R. Zuo, C. Wei, Y. Y. Fang, C. Y. Tang, J. L. Chen, D. Y. Wu, Z. H. Liu, X. W. Yin, Z. N. Bian, Y.F. Wang, X. Y. Du, L. Jiang, Q. Y. He, G. M. Wang, Adv. Mater., 2026, 38, e73610.
[67]	Y. Li, Q. Liao, P. Ji, S. Jie, C. Wu, K. Tong, M. Zhu, C. Zhang, H. Li, JACS Au, 2025, 5, 714-726.
[68]	J. Cheng, Y. Tu, Y. Xiang, J. Ni, T. Guo, X. Huang, B. Liu, Z. Wei, Chem. Sci., 2025, 16, 4303-4310.
[69]	J. Chen, J. Li, Z. Wei, Chin. J. Catal., 2025, 73, 79-98.
[70]	Y. Lin, Y. Chen, H. Ren, Y. Sun, J. Chen, M. Wu, Z. Li, Adv. Funct. Mater., 2024, 34, 2404594.
[71]	I. Vollmer, M. J. F. Jenks, M. C. P. Roelands, R. J. White, T. van Harmelen, P. de Wild, G. P. van der Laan, F. Meirer, J. T. F. Keurentjes, B. M. Weckhuysen, Angew. Chem. Int. Ed., 2020, 59, 15402-15423.
[72]	Y. Kratish, J. Li, S. Liu, Y. Gao, T. J. Marks, Angew. Chem. Int. Ed., 2020, 59, 19857-19861.
[73]	Z. Mao, L. Jia, X. Mao, X. Ding, B. Pan, T. Yan, J. Xu, L. Zhang, L. Wang, N. Han, Y. Li, J. Mater. Chem. A, 2024, 12, 24136-24143.

Pd/Bi₂O₃异质结构强金属-载体相互作用增强生物质电氧化升级转化性能

Interfacial charge transfer via SMSI in heterostructured Pd/Bi₂O₃: A paradigm for sustainable electrochemical biomass upcycling

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 6

参考文献

相关文章 2

编辑推荐

Metrics

[1]	李正, 曾影, 董媛媛, 吕红金, 杨国昱. 十钨酸盐+Pd/C催化体系中金属/H⁺位点的调控用于光催化生成糠基乙醚[J]. 催化学报, 2025, 75(8): 137-146.
[2]	陈朝辉, 邓军, 郑燕梅, 张文君, 董琳, 陈祖鹏. 通过调节碳自由基的反应活性调控偶联反应产物和羰基化合物的选择性合成[J]. 催化学报, 2024, 61(6): 135-143.