十钨酸盐+Pd/C催化体系中金属/H+位点的调控用于光催化生成糠基乙醚

doi:10.1016/S1872-2067(25)64746-2

催化学报 ›› 2025, Vol. 75: 137-146.DOI: 10.1016/S1872-2067(25)64746-2

十钨酸盐+Pd/C催化体系中金属/H⁺位点的调控用于光催化生成糠基乙醚

李正^a, 曾影^a, 董媛媛^a^,^*(), 吕红金^a^,^b^,^*(), 杨国昱^a

^a北京理工大学化学与化工学院, 光电转换材料北京市重点实验室, 原子分子簇科学教育部重点实验室, 北京 102488
^b北京理工大学唐山研究院, 河北唐山 063000

收稿日期:2025-01-05 接受日期:2025-04-24 出版日期:2025-08-18 发布日期:2025-07-22
通讯作者: *电子信箱: dyy1111@bit.edu.cn (董媛媛), hlv@bit.edu.cn (吕红金).
基金资助:
河北省自然科学基金(B2024105003);国家自然科学基金(22471019);国家自然科学基金(21831001);北理工高层次人才科研启动计划项目;国家海外高层次人才引进计划青年项目(Young Talents)

Metal/H⁺ sites modulation in the decatungstate+Pd/C catalytic system for photocatalytic generation of furfuryl ethyl ether

Li Zheng^a, Zeng Ying^a, Dong Yuanyuan^a^,^*(), Lv Hongjin^a^,^b^,^*(), Yang Guo-Yu^a

^aMOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectric/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China
^bTangshan Research Institute, Beijing Institute of Technology, Tangshan 063000, Hebei, China

Received:2025-01-05 Accepted:2025-04-24 Online:2025-08-18 Published:2025-07-22
Contact: *E-mail: dyy1111@bit.edu.cn (Y. Dong), hlv@bit.edu.cn (H. Lv).
Supported by:
Hebei Natural Science Foundation(B2024105003);National Natural Science Foundation of China(22471019);National Natural Science Foundation of China(21831001);BIT Excellent Young Scholars Research Fund;Recruitment Program of Global Experts(Young Talents)

摘要/Abstract

摘要：

由于化石燃料的过度消耗导致了全球的能源危机和严重的环境污染, 对可再生资源的勘探和有效转化引起了人们的更多关注. 纤维素衍生的平台化学品作为典型的可再生资源, 其增值转化是获取可再生碳化学品的可靠途径. 其中, 糠醛(FF)可由五碳糖脱水获得, 由其制备的糠基醚因其高的稳定性和高辛烷值可作为生物燃油引起了人们的极大兴趣; 然而, 绿色高效地将FF转化为糠基醚在工业和学术上仍是一项巨大的挑战. 目前, 从FF到糠基醚有两种转化路线: (1) FF通过氢化和醚化两步法转化为糠基醚, 该方法不仅操作复杂且产物的收率较低;(2) 在加氢/酸双功能催化体系下, 使用H₂或者牺牲剂作为氢源, FF通过还原醚化途径一锅法转化为糠基醚, 该方法虽然操作简便、高效,但是仍需高压/高温条件来活化H₂或者牺牲剂. 鉴于此, 开发绿色温和、高效的催化体系将FF转化为糠基醚具有重要的基础研究意义和潜在应用价值.

基于光催化剂优异的光致氢原子转移(HAT)活性所设计的光诱导催化转移氢化(CTH)体系是有前景的解决方案. 本文成功构建光诱导CTH催化体系用于FF还原醚化制备糠基乙基醚(FEE), 该体系使用廉价的十钨酸钠盐(NaDT)作为光催化剂和氢转移催化剂, Pd/C为加氢催化剂, 乙醇为反应物和氢源, 溴代苯(PhBr)为原位质子酸添加剂, 在365 nm光的激发下, 在室温下FF可高效的转化为FEE, 产率为92.7%. 对FF转化路径研究发现, 不添加PhBr时, FF主要氢化为糠醇(FA), 产率最高为91.4%; 添加PhBr时, FF通过关键的糠醛缩二乙醇(DOF)中间体高效地转化为FEE. PhBr的转化时间曲线与回收的Pd/C一系列表征结果表明, 在PhBr氢解后, 除了生成HBr外, 部分Br原子会以PdBr₂物种附着在Pd纳米颗粒表面, PhBr的氢解过程以及附着在Pd纳米颗粒表面的PdBr₂物种抑制FF氢化为FA, 促使FF在H⁺的催化下与乙醇高效地转化为DOF中间体, 即PhBr可调节该光诱导CTH中的Pd位点和H⁺位点, 这对FF通过关键DOF中间体转化为FEE至关重要. 随着反应的进行, Br原子逐渐脱落使Pd位点重新暴露, 促进了DOF氢化成FEE. 该催化体系对正丙醇和多种呋喃醛底物表现出良好的普适性.

综上, 本文构建的光诱导CTH策略在温和条件下实现了FF向FEE的高效转化. 该催化策略为纤维素衍生平台分子的温和、高效增值转化开辟了一种创新途径. 未来研究工作拟围绕非贵金属基光诱导CTH策略的开发, 以推动糠基醚生物燃料的低成本、规模化生产及应用进程.

关键词: 糠基醚, 十钨酸, 光催化, 催化转移氢化, 生物质增值

Abstract:

Furfuryl ethyl ether (FEE) is considered as one of the most important candidates for biofuels due to its high-octane number. However, it is still challenging to produce FEE via the biomass-based route under mild conditions. Here, we developed a photoinduced catalytic transfer hydrogenation (CTH) process for the efficient production of FEE through the reduction etherification of furfural (FF) using Na₄W₁₀O₃₂ (NaDT), Pd/C, and ethanol as the hydrogen atom transfer (HAT) catalyst, hydrogenation catalyst, and the H donor, respectively. Notably, the introduction of brominated benzene (PhBr) as an additive significantly promoted the yield of FEE to 92.7%. A series of experiments and characterization results indicated that the attachment and detachment of Br atoms on Pd/C catalyst surface effectively regulate the balance between H⁺ sites and Pd sites in the NaDT+Pd/C catalytic system. The balance facilitates the preferential acetalization of FF catalyzed by H⁺ sites, followed by hydrogenation to efficiently produce FEE catalyzed by Pd sites. This photoinduced CTH process exhibits good stability and recyclability as well as universality for the transformation of various organic substrates under mild conditions.

Key words: Furfuryl ether, Decatungstate, Photocatalysis, Catalytic transfer hydrogenation, Biomass valorization

李正, 曾影, 董媛媛, 吕红金, 杨国昱. 十钨酸盐+Pd/C催化体系中金属/H⁺位点的调控用于光催化生成糠基乙醚[J]. 催化学报, 2025, 75: 137-146.

Li Zheng, Zeng Ying, Dong Yuanyuan, Lv Hongjin, Yang Guo-Yu. Metal/H⁺ sites modulation in the decatungstate+Pd/C catalytic system for photocatalytic generation of furfuryl ethyl ether[J]. Chinese Journal of Catalysis, 2025, 75: 137-146.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(25)64746-2

https://www.cjcatal.com/CN/Y2025/V75/I8/137

图/表 9

Scheme 1. The transformation of FF into FEE via hydrogenation and etherification pathway (a), reductive etherification pathway (b), and photoinduced CTH pathway (c).

Table 1 Screening of reaction conditions for this photoinduced CTH system a.

Entry	Catalyst	FF Conv. (%)	FA yield (%)	FEE yield (%)	2-MF yield (%)	DOF yield (%)	H_abs^b (μmol)	S_FF^c (%)	S_H2^d (%)
1	NaDT + Pd/C	99.9	85.3	2.4	9.7	2.5	869.2	49.2	50.8
2	NaDT + Pt/C	64.2	2.3	0.3	0.6	61.4	724	2.1	97.9
3	NaDT + Ru/C	66.8	0	0	0	66.8	112	0	100
4^e	NaDT + Pd/C	0	0	0	0	0	—	—	—
5	Na₂WO₄ + Pd/C	3.4	0	0	0	0	—	—	—
6	Pd/C	5.4	0	0	0	0	—	—	—
7	NaDT	10.6	0	0	0	10.5	—	—	—

Fig. 1. (a) The effects of the NaDT amount on the photocatalytic activities. (b) The plots of the SFF and the transfer amount of H species (Htransfer) as function of the NaDT amount.

Fig. 2. (a) The common paths for the transformation of furan aldehydes into furan ethers. (b) The influences of the aryl halide additives on the photocatalytic activities. (c) The optimization of PhBr dosage. (d) Recycling experiments of this photoinduced CTH system.

Fig. 3. (a) The kinetic behaviors of the transformation of FF without PhBr additive. (b) The total abstracted amount and the utilization efficiency of H species without PhBr additive. (c) The proposed transformation routes of FF via photoinduced CTH method. (d) The kinetic behaviors of the transformation of FF with PhBr additive. (e) The total abstracted amount and the utilization efficiency of H species with PhBr additive. Habs here is the total amount of H species abstracted from ethanol, calculated by the sum of the H species using for H2 evolution, the hydrogenation of FF, and the hydrogenolysis of PhBr.

Table 2 Screening of Br sources for the conversion of FF into FEE via photoinduced CTH method a.

Entry	Br source	FF Conv. (%)	FEE yield (%)	Br chemical environment	Conversion of Br sources^b (%)
1		99.9	92.7	C(sp²)-Br	100
2		99.8	69.0	C(sp³)-Br (benzyl Br)	65.9
3		94.8	5.0	C(sp³)-Br	21.8
4		99.9	3.4	C(sp³)-Br	17.9
5	HBr	99.9	54.5	—	—
6	NaBr	99.8	3.0	—	—
7^c	—	99.8	33.2	—	—

Fig. 4. (a) The dynamic behavior of PhBr during photocatalysis. (b) The high-resolution Pd 3d XPS spectra of the isolated Pd/C after reaction for 0.5 h. (c) TEM image and line scan profiles of the isolated Pd/C after reaction for 0.5 h. (d) The amount of CO adsorbed on the isolated Pd/C as the prolonging time.

Scheme 2. Proposed reaction mechanism of the reduction etherification of FF via photoinduced CTH method.

Table 3 The photocatalytic activities of other substrates catalyzed by TBADT.

参考文献

[1]	Y. Pang, Z. Zhang, W. Qiu, N. Chen, J. Wei, X. Li, L. Lin, H. Huang, Sustainable Energy Fuels, 2022, 6, 4845-4859.
[2]	Z. Fan, W. Zhang, L. Li, Y. Wang, Y. Zou, S. Wang, Z. Chen, Green Chem., 2022, 24, 7818-7868.
[3]	M. Yang, Z. Yuan, R. Peng, S. Wang, Y. Zou, Energy Environ. Mater., 2022, 5, 1117-1138.
[4]	C. Xiouras, N. Radacsi, G. Sturm, G. D. Stefanidis, ChemSusChem, 2016, 9, 2159-2166.
[5]	J.-P. Lange, E. Van der Heide, J. Van Buijtenen, R. Price, ChemSusChem, 2012, 5, 150-166.
[6]	J. Van Buijtenen, J.-P. Lange, L. Espinosa Alonso, W. Spiering, R. F. Polmans, R. J. Haan, ChemSusChem, 2013, 6, 2132-2136.
[7]	D. Scholz, C. Aellig, I. Hermans, ChemSusChem, 2014, 7, 268-275.
[8]	K. Wang, S. Liu, J. Zhang, Z. Hu, Q. Kong, Y. Xu, X. Huang, ACS Nano, 2022, 16, 15008-15015.
[9]	Z. Ren, Y. Yang, S. Wang, X. Li, H. Feng, L. Wang, Y. Li, X. Zhang, M. Wei, Appl. Catal. B, 2021, 295, 120290.
[10]	Z. Tong, X. Li, J. Dong, R. Gao, Q. Deng, J. Wang, Z. Zeng, J.-J. Zou, S. Deng, ACS Catal., 2021, 11, 6406-6415.
[11]	R. Mariscal, P. Maireles-Torres, M. Ojeda, I. Sádaba, M. López Granados, Energy Environ. Sci., 2016, 9, 1144-1189.
[12]	Y. Wang, Q. Cui, Y. Guan, P. Wu, Green Chem., 2018, 20, 2110-2117.
[13]	W. Fang, J. Egebo, L. Schill, H. Chen, A. Riisager, Green Chem., 2022, 24, 7346-7349.
[14]	A. Hassine, A. Iben Ayad, A. Ould Dris, D. Luart, E. Guénin, Catalysts, 2024, 14, 617.
[15]	A. M. Ajeebi, H. S. Alghamdi, M. A. Sanhoob, M. Aktary, M. Abdul Aziz, A. S. Alzahrani, A. Q. Alsayoud, M. Nasiruzzaman Shaikh, J. Ind. Eng. Chem., 2024, 137, 572-582.
[16]	M. Stucchi, S. Alijani, M. Manzoli, A. Villa, R. Lahti, M. G. Galloni, U. Lassi, L. Prati, Catal. Today, 2020, 357, 122-131.
[17]	L. Hu, B. Sha, Y. Shi, N. Shen, M. Yang, K. Chen, Z. Wu, X. Tang, A. He, L. Lin, Chem. Eng. J., 2024, 498, 155725.
[18]	F. Zaccheria, F. Bossola, N. Scotti, C. Evangelisti, V. Dal Santo, N. Ravasio, Catal. Sci. Technol., 2020, 10, 7502-7511.
[19]	T. Yang, J. Wang, Z. Wang, J. Zhang, K. Dai, Chin. J. Catal., 2024, 58, 157-167.
[20]	M. Ren, T. Liu, Y. Dong, Z. Li, J. Yang, Z. Diao, H. Lv, G.-Y. Yang, Chin. J. Catal., 2024, 61, 312-321.
[21]	M. Zhang, H. Li, J. Zhang, H. Lv, G.-Y. Yang, Chin. J. Catal., 2021, 42, 855-871.
[22]	Y. Feng, L. Qin, J. Zhang, F. Fu, H. Li, H. Xiang, H. Lv, Chin. J. Catal., 2022, 43, 442-450.
[23]	Z. Liu, J. Tian, C. Yu, Q. Fan, X. Liu, Chin. J. Catal., 2022, 43, 472-484.
[24]	H. Li, Z. Gao, L. Lei, H. Liu, J. Han, F. Hong, N. Luo, F. Wang, Green Chem., 2020, 22, 3802-3808.
[25]	Z. Yuan, M. B. Nodwell, H. Yang, N. Malik, H. Merkens, F. Bénard, R. E. Martin, P. Schaffer, R. Britton, Angew. Chem. Int. Ed., 2018, 57, 12733-12736.
[26]	T. Wan, L. Capaldo, G. Laudadio, A. V. Nyuchev, J. A. Rincón, P. García-Losada, C. Mateos, M. O. Frederick, M. Nuño, T. Noël, Angew. Chem. Int. Ed., 2021, 60, 17893-17897.
[27]	L. Wang, T. Wang, G.-J. Cheng, X. Li, J.-J. Wei, B. Guo, C. Zheng, G. Chen, C. Ran, C. Zheng, ACS Catal., 2020, 10, 7543-7551.
[28]	L. Capaldo, R. Riccardi, D. Ravelli, M. Fagnoni, ACS Catal., 2018, 8, 304-309.
[29]	D. Ravelli, M. Fagnoni, T. Fukuyama, T. Nishikawa, I. Ryu, ACS Catal., 2018, 8, 701-713.
[30]	D. Dondi, M. Fagnoni, A. Albini, Chem. Eur. J., 2006, 12, 4153-4163.
[31]	M. Bonchio, M. Carraro, G. Scorrano, E. Fontananova, E. Drioli, Adv. Synth. Catal., 2003, 345, 1119-1126.
[32]	I. Texier, J. A. Delaire, C. Giannotti, Phys. Chem. Chem. Phys., 2000, 2, 1205-1212.
[33]	C. Tanielian, I. N. Lykakis, R. Seghrouchni, F. Cougnon, M. Orfanopoulos, J. Mol. Catal. A, 2007, 262, 170-175.
[34]	A. Molinari, A. Maldotti, A. Bratovcic, G. Magnacca, Catal. Today, 2013, 206, 46-52.
[35]	T. Yamase, T. Usami, J. Chem. Soc., alton Trans., 1988, 183-190.
[36]	I. Moriguchi, K. Orishikida, Y. Tokuyama, H. Watabe, S. Kagawa, Y. Teraoka, Chem. Mater., 2001, 13, 2430-2435.
[37]	V. De Waele, O. Poizat, M. Fagnoni, A. Bagno, D. Ravelli, ACS Catal., 2016, 6, 7174-7182.
[38]	S. Shinde, C. Rode, ChemSusChem, 2017, 10, 4090-4101.
[39]	D. Wu, W. Y. Hernández, S. Zhang, E. I. Vovk, X. Zhou, Y. Yang, A. Y. Khodakov, V. V. Ordomsky, ACS Catal., 2019, 9, 2940-2948.
[40]	Y. Long, Y. Wang, H. Wu, T. Xue, P. Wu, Y. Guan, RSC Adv., 2019, 9, 25345-25350.
[41]	Z. Li, Y. Dong, Y. Zeng, M. Zhang, H. Lv, G.-Y. Yang, Chin. J. Catal., 2024, 66, 282-291.
[42]	Y. Tan, Y. Yin, S. Cao, X. Zhao, G. Qu, Z. Jiang, Chin. J. Catal., 2022, 43, 558-563.
[43]	D.-M. Yan, C. Xiao, J.-R. Chen, Chem, 2018, 4, 2496-2498.
[44]	I. B. Perry, T. F. Brewer, P. J. Sarver, D. M. Schultz, D. A. DiRocco, D. W. C. MacMillan, Nature, 2018, 560, 70-75.
[45]	D. C. Duncan, T. L. Netzel, C. L. Hill, Inorg. Chem., 1995, 34, 4640-4646.
[46]	L. Shuai, M. T. Amiri, Y. M. Questell-Santiago, F. Héroguel, Y. Li, H. Kim, R. Meilan, C. Chapple, J. Ralph, J. S. Luterbacher, Science, 2016, 354, 329-333.
[47]	W. Liu, W. You, Y. Gong, Y. Deng, Energy Environ. Sci., 2020, 13, 917-927.
[48]	W. Liu, W. You, W. Sun, W. Yang, A. Korde, Y. Gong, Y. Deng, Nat. Energy, 2020, 5, 759-767.
[49]	L. Jiao, Y. Dong, X. Xin, R. Wang, H. Lv, J. Mater. Chem. A, 2021, 9, 19725-19733.
[50]	T. Yamase, N. Takabayashi, M. Kaji, J. Chem. Soc., alton Trans., 1984, 793-799.
[51]	D. Wu, S. Zhang, W. Y. Hernández, W. Baaziz, O. Ersen, M. Marinova, A. Y. Khodakov, V. V. Ordomsky, ACS Catal., 2021, 11, 19-30.
[52]	D. Wu, Q. Wang, O. V. Safonova, D. V. Peron, W. Zhou, Z. Yan, M. Marinova, A. Y. Khodakov, V. V. Ordomsky, Angew. Chem. Int. Ed., 2021, 60, 12513-12523.
[53]	Z. Zhang, X. Ma, C. Yue, X. Wei, B. Liu, React. Kinet. Mech. Catal., 2022, 135, 1541-1552.
[54]	M. Song, C. Qiu, P. Ma, J. Zhong, Z. Zhang, W. Fang, W. Song, J. Fan, W. Lai, Renewable Energy, 2023, 212, 468-477.
[55]	K. Yang, R. Wang, D. Xu, X. Ma, D. Ding, M. Zhang, L. Zhang, Z. Bai, Z. Zhu, H. Lü, J. Catal., 2023, 425, 170-180.
[56]	S. Xu, H. Chen, Z. Zhou, W. Kong, Angew. Chem. Int. Ed., 2021, 60, 7405-7411.
[57]	D. M. Schultz, F. Lévesque, D. A. DiRocco, M. Reibarkh, Y. Ji, L. A. Joyce, J. F. Dropinski, H. Sheng, B. D. Sherry, I. W. Davies, Angew. Chem. Int. Ed., 2017, 56, 15274-15278.
[58]	H. Wang, L. Li, X.-F. Bai, J.-Y. Shang, K.-F. Yang, L.-W. Xu, Adv. Synth. Catal., 2013, 355, 341-347.
[59]	A. Volkov, K. P. J. Gustafson, C.-W. Tai, O. Verho, J.-E. Bäckvall, H. Adolfsson, Angew. Chem. Int. Ed., 2015, 54, 5122-5126.

十钨酸盐+Pd/C催化体系中金属/H⁺位点的调控用于光催化生成糠基乙醚

Metal/H⁺ sites modulation in the decatungstate+Pd/C catalytic system for photocatalytic generation of furfuryl ethyl ether

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 9

参考文献

相关文章 15

编辑推荐

Metrics

[1]	王啟航, 孟利, 李卓, 杨卓然, 汤意南, 余浪, 李志君, 孙建辉, 井立强. 钴单原子-磷酸功能化还原氧化石墨烯/苝四羧酸纳米片异质结用于高效光催化生产过氧化氢[J]. 催化学报, 2025, 75(8): 192-203.
[2]	陈鸿境, 李月英, 陈敏, 解仲凯, 施伟东. 硫电子桥介导CuInS₂/CuS异质结构实现高选择性CO₂光还原为C₂H₄[J]. 催化学报, 2025, 75(8): 180-191.
[3]	熊祺, 史全全, 王彬力, 李杲. 晶面诱导还原导向的AgBr/Ag⁰/TiO₂{100} Z型异质结用于四环素去除[J]. 催化学报, 2025, 75(8): 164-179.
[4]	高文婧, 刘玉婵, 陈琛瑶, 练梓棋, 叶融凯, 戚朝荣, 胡建强. 可定量调控的双助催化剂协同电子-空穴传输体系的构筑及其增强的光催化性能[J]. 催化学报, 2025, 74(7): 319-328.
[5]	张自豪, 张家铭, 王海峰, 刘梦, 许垚, 刘铠玮, 张博杨, 史珂, 张继方, 马贵军. 基于Sm₂Ti₂O₅S₂纳米片各向异性电荷迁移性质提升光催化分解水产氢活性[J]. 催化学报, 2025, 74(7): 341-351.
[6]	张鹏坤, 吴秦汉, 王昊昱, 郭东昊, 赖雨洁, 陆东芳, 李吉庆, 林金国, 袁占辉, 陈孝云. Z型异质结Zn₃(OH)₂(V₂O₇)(H₂O)₂/V-Zn(O,S): 钒异价态与氧空位缺陷协同增强可见光催化固氮性能[J]. 催化学报, 2025, 74(7): 279-293.
[7]	张琳, 张慧, 方敬红, 崔嘉琳, 刘洁, 刘辉, 孙立水, 孙琼, 董立峰, 赵英杰. 高共轭和化学稳定的三维共价有机框架材料用于高效光催化CO₂还原[J]. 催化学报, 2025, 74(7): 144-154.
[8]	郑馨龙, 宋一铭, 王崇太, 高奇志, 邵钟鋆, 林佳鑫, 翟佳迪, 李静, 史晓东, 吴道雄, 刘维峰, 黄玮, 陈琦, 田新龙, 刘雨昊. 铜/锌体系多元过渡金属硫化物光催化剂的半导体特性及其光催化制氢的应用与挑战[J]. 催化学报, 2025, 74(7): 22-70.
[9]	吴崇备, 楚飞鸿, 郝永超, 李璇, 贾晓月, 孙伊钒, 谷佳璇, 加鹏飞, 王傲冰, 江吉周. 共价有机框架的双氧气还原中心促进光催化合成H₂O₂[J]. 催化学报, 2025, 74(7): 329-340.
[10]	李存军, 何杰, 蔡天乐, 陈贤雷, 陶亨聪, 周英棠, 朱明山. 溴氧铋表面氧空位调控压电性质用于提升光催化CO₂还原反应效率与产物选择性[J]. 催化学报, 2025, 74(7): 130-143.
[11]	张云超, 潘劲康, 倪响, 莫非奇, 徐远国, 董鹏玉. 有机/无机杂化FS-COF/WO₃ S型异质结电荷载流子动力学及其光催化析氢性能[J]. 催化学报, 2025, 74(7): 250-263.
[12]	李亚慧, 陈宇, 郭锦瑜, 王锐, 赵淑娜, 李纲, 臧双全. 调控COF共价连接的多吡啶镍催化剂微环境促进光催化二氧化碳还原[J]. 催化学报, 2025, 74(7): 155-166.
[13]	周正宇, 靳治良. 自定义暴露晶面: 最佳晶面各向异性和欧姆异质结的协同效应促进光催化析氢[J]. 催化学报, 2025, 74(7): 294-307.
[14]	李睿, 冯鹏飞, 李柏男, 朱佳玉, 张雅丽, 张泽, 张江威, 丁勇. 具有氧空位的多孔超薄NiO纳米片用于光催化CO₂还原[J]. 催化学报, 2025, 73(6): 242-251.
[15]	孙雪萌, 刘佳男, 李琪, 汪成, 蒋保江. 肖特基结与金属尺寸效应协同增强光催化硝酸还原[J]. 催化学报, 2025, 73(6): 358-367.

十钨酸盐+Pd/C催化体系中金属/H+位点的调控用于光催化生成糠基乙醚

Metal/H+ sites modulation in the decatungstate+Pd/C catalytic system for photocatalytic generation of furfuryl ethyl ether

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 9

参考文献

相关文章 15

编辑推荐

Metrics

十钨酸盐+Pd/C催化体系中金属/H⁺位点的调控用于光催化生成糠基乙醚

Metal/H⁺ sites modulation in the decatungstate+Pd/C catalytic system for photocatalytic generation of furfuryl ethyl ether