核壳型SAPO-34/AlPO-18 分子筛的制备及生长机理

doi:10.3724/SP.J.1088.2012.20650

催化学报 ›› 2012, Vol. 33 ›› Issue (10): 1724-1729.DOI: 10.3724/SP.J.1088.2012.20650

核壳型SAPO-34/AlPO-18 分子筛的制备及生长机理

张琳1, 田鹏1, 苏雄1,2, 樊栋1,2, 王德花1,2, 刘中民1,*

1中国科学院大连化学物理研究所洁净能源国家实验室 (筹), 甲醇制烯烃国家工程实验室, 辽宁大连 116023; 2中国科学院研究生院, 北京 100049

收稿日期:2012-06-26 修回日期:2012-07-26 出版日期:2012-09-28 发布日期:2012-09-28

Synthesis and Growth Mechanism of the Core-Shell SAPO-34/AlPO-18 Molecular Sieves

ZHANG Lin1, TIAN Peng1, SU Xiong1,2, FAN Dong1,2, WANG Dehua1,2, LIU Zhongmin1,*

1Dalian National Laboratory for Clean Energy, National Engineering Laboratory for Methanol-to-Olefins, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 2Graduate University of Chinese Academy of Sciences, Beijing100049, China

Received:2012-06-26 Revised:2012-07-26 Online:2012-09-28 Published:2012-09-28

摘要/Abstract

摘要： 采用水热法制备了核壳型 SAPO-34/AlPO-18 分子筛, 并运用 X 射线衍射、扫描电镜和超高分辨场发射扫描电镜等方法对样品进行了表征. 结果表明, 通过改变实验条件可有效调控壳层 AlPO-18 纳米晶在 SAPO-34 晶体表面的生长, 从而得到具有不同生长区域、生长取向及紧密度的核壳型 SAPO-34/AlPO-18 分子筛. 超高分辨场发射扫描电镜结果发现, 核相 SAPO-34 晶体的外表面结构与壳层 AlPO-18 纳米晶的生长性质紧密相关, 从而推测出核相晶体外表面微细结构诱导壳层分子筛生长的晶化机理.

关键词: 核壳分子筛, SAPO-34, AlPO-18, 生长机理, 超高分辨场发射扫描电镜

Abstract: The core-shell molecular sieves comprised of SAPO-34 as core and AlPO-18 as shell were hydrothermally synthesized and characterized by X-ray diffraction, scanning electron microscopy (SEM), and ultra-high resolution field-emission scanning electron microscopy (FE-SEM) techniques. The SEM results show that the growth of the shell AlPO-18 nanocrystals with different orientations and compactness can be controlled by adjustment of the synthesis conditions such as core pretreatment, liquid to solid ratio, and growth number. The ultra-high resolution FE-SEM images confirm that the growth performance of the shell AlPO-18 is closely related to the surface microstructure of SAPO-34, indicating the mechanism that the microstructure on the external surface of the core directs the growth of the shell.

Key words: core-shell molecular sieve, SAPO-34, AlPO-18, growth mechanism, ultra-high resolution field-emission scanning electron microscopy

张琳, 田鹏, 苏雄, 樊栋, 王德花, 刘中民. 核壳型SAPO-34/AlPO-18 分子筛的制备及生长机理[J]. 催化学报, 2012, 33(10): 1724-1729.

ZHANG Lin, TIAN Peng, SU Xiong, FAN Dong, WANG De-Hua, LIU Zhong-Min. Synthesis and Growth Mechanism of the Core-Shell SAPO-34/AlPO-18 Molecular Sieves[J]. Chinese Journal of Catalysis, 2012, 33(10): 1724-1729.

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参考文献

1 de Vos Burchart E, Jansen J C, van Bekkum H. Zeolites, 1989, 9: 432
2 Van Vu D, Miyamoto M, Nishiyama N, Egashira Y, Ueyama K. J Catal, 2006, 243: 389
3 Van Vu D, Miyamoto M, Nishiyama N, Ichikawa S, Egashira Y, Ueyama K. Microporous Mesoporous Mater, 2008, 115: 106
4 Goossens A M, Wouters B H, Buschmann V, Martens J A. Adv Mater, 1999, 11: 561
5 Goossens A M, Wouters B H, Grobet P J, Buschmann V, Fiermans L, Martens J A. Eur J Inorg Chem, 2001: 1167
6 Brent R, Stevens S M, Terasaki O, Anderson M W. Cryst Growth Des, 2010, 10: 5182
7 Jeong H K, Krohn J, Sujaoti K, Tsapatsis M. J Am Chem Soc, 2002, 124: 12966
8 Miyamoto M, Kamei T, Nishiyama N, Egashira Y, Ueyama K. Adv Mater, 2005, 17: 1985
9 Bouizi Y, Rouleau L, Valtchev V P. Chem Mater, 2006, 18: 4959
10 Bouizi Y, Rouleau L, Valtchev V P. Microporous Mesoporous Mater, 2006, 91: 70
11 Bouizi Y, Diaz I, Rouleau L, Valtchev V P. Adv Funct Mater, 2005, 15: 1955
12 张哲, 宗保宁. 催化学报 (Zhang Zh, Zong B N. Chin J Catal), 2003, 24: 856
13 张强, 李春义, 山红红, 杨朝合. 催化学报 (Zhang Q, Li Ch Y, Shan H H, Yang Ch H. Chin J Catal), 2007, 28: 541
14 孔德金, 童伟益, 郑均林, 刘志城, 邹薇, 祁晓岚, 房鼎业. 化学通报 (Kong D J, Tong W Y, Zheng J L, Liu Zh Ch, Zou W, Qi X L, Fang D Y. Chemistry Online), 2008, 4: 249
15 Okubo T, Wakihara T, Plevert J, Nair S, Tsapatsis M, Ogawa Y, Komiyama H, Yoshimura M, Davis M E. Angew Chem, Int Ed, 2001, 40: 1069
16 Wakihara T, Yamakita S, Iezumi K, Okubo T. J Am Chem Soc, 2003, 125: 12388
17 Tian D Y, Yan W F, Wang Zh X, Wang Y Y, Li Zh B, Yu J H, Xu R R. Cryst Growth Des, 2009, 9: 1411
18 李金哲, 齐越, 刘中民, 刘广宇, 常福祥. 催化学报 (Li J Zh, Qi Y, Liu Zh M, Liu G Y, Chang F X. Chin J Catal), 2008, 29: 660
19 Li J Zh, Wei Y X, Liu G Y, Qi Y, Tian P, Li B, He Y L, Liu Zh M. Catal Today, 2011, 171: 221
20 Liang J, Li H Y, Zhao S Q, Guo W G, Wang R H, Ying M L. Appl Catal, 1990, 64: 31
21 Liu G Y, Tian P, Li J Zh, Zhang D Zh, Zhou F, Liu Zh M. Microporous Mesoporous Mater, 2008, 111: 143
22 Wei Y X, Li J Zh, Yuan C Y, Xu Sh T, Zhou Y, Chen J R, Wang Q Y, Zhang Q, Liu Zh M. Chem Commun, 2012, 48: 3082
23 王仰东, 王传明, 刘红星, 谢在库. 催化学报 (Wang Y D, Wang Ch M, Liu H X, Xie Z K. Chin J Catal), 2010, 31: 33
24 袁翠峪, 魏迎旭, 李金哲, 徐舒涛, 陈景润, 周游, 王全义, 许磊, 刘中民. 催化学报 (Yuan C Y, Wei Y X, Li J Zh, Xu Sh T, Chen J R, Zhou Y, Wang Q Y, Xu L, Liu Zh M. Chin J Catal), 2012, 33: 367
25 Hu H, Ying W Y, Fang D Y. J Nat Gas Chem, 2010, 19: 409
26 Baerlocher Ch, McCusker L B, Olson D H. Atlas of Zeolite Framework Types. 6th Ed. Amsterdam: Elsevier, 2007. 18
27 Vilaseca M, Mintova S, Valtchev V, Metzger T H, Bein T. J Mater Chem, 2003, 13: 1526
28 Cimek A, Komunjer L, Subotic B, Siroki M, Roncevic S. Zeolites, 1991, 11: 258
29 Meza L I, Anderson M W, Agger J R. Chem Commun, 2007: 2473
30 Meza L I, Anderson M W, Slater B, Agger J R. Phys Chem Chem Phys, 2008, 10: 5066
31 Yan Y G, Chaudhuri S R, Sarkar A. Chem Mater, 1996, 8: 473

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核壳型SAPO-34/AlPO-18 分子筛的制备及生长机理

Synthesis and Growth Mechanism of the Core-Shell SAPO-34/AlPO-18 Molecular Sieves

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