关键词: 铜, 钴, 堇青石, 整体式催化剂, 甲苯, 催化燃烧

Abstract: A series of Cu_xCo_1-x/Al₂O₃/cordierite (x = 0~1) catalysts were prepared using cordierite as a support, a boehmite primer sol as the first washcoat layer and copper as well as cobalt oxides as the activity washcoat layer. The structure of the catalysts was characterized using X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and temperature-programmed reduction. Toluene was chosen as a model compound to evaluate the catalytic activity in a conventional fixed-bed quartz reactor. The results indicate that Cu-Co-O was present when the Cu content was low. CuO diffraction peaks were observed when the Cu content was high. Both Co²⁺ and Co³⁺ exist on the surface of the obtained monolithic catalysts while Cu²⁺ is the main Cu species. The addition of a certain amount of copper oxide improved the reducibility of the cobalt oxide, which enhanced the catalytic activity of the catalysts. All the obtained catalysts showed good activity for the catalytic combustion of toluene. The Cu_0.5Co_0.5/Al₂O₃/cordierite catalyst showed the best catalytic activity. Toluene was completely oxidized at 315 °C.

Key words: copper, cobalt, cordierite, monolithic catalyst, toluene, catalytic combustion