催化学报 ›› 2013, Vol. 34 ›› Issue (4): 641-650.DOI: 10.1016/S1872-2067(12)60531-2

• 综述 • 上一篇    下一篇

HZSM-5上生物质催化裂解的近期研究进展

谭顺a, 张志军a, 孙剑平a,b, 王清文a   

  1. a 东北林业大学生物质材料科学与技术教育部重点实验室, 黑龙江哈尔滨150040;
    b 沈阳建筑大学市政与环境工程学院, 辽宁沈阳110168
  • 收稿日期:2012-11-10 修回日期:2013-01-07 出版日期:2013-04-23 发布日期:2013-04-24
  • 通讯作者: 王清文
  • 基金资助:

    国家自然科学基金(31010103905).

Recent progress of catalytic pyrolysis of biomass by HZSM-5

TAN Shuna, ZHANG Zhijuna, SUN Jianpinga,b, WANG Qingwena   

  1. a Key Laboratory of Bio-based Material Science and Technology, Ministry of Education, Northeast Forestry University, Harbin 150040, Heilongjiang, China;
    b School of Municipal and Environmental Engineering, Shenyang Jianzhu University, Shenyang 110168, Liaoning, China
  • Received:2012-11-10 Revised:2013-01-07 Online:2013-04-23 Published:2013-04-24
  • Supported by:

    This work was supported by the National Natural Science Foundation of China (31010103905).

摘要:

概述了近期的HZSM-5对生物质和生物油催化裂解的研究进展,重点介绍了催化剂的应用、生物油提质的方法和反应机理.

关键词: 生物质, 生物油, 提质, 裂解, 热解, HZSM-5

Abstract:

Biomass can be converted into a variety of fuels and chemicals using different technologies. One such process is fast pyrolysis, which is convenient for the conversion of biomass primarily into liquid products known as bio-oils. These bio-oils, however, must be upgraded if they are to be used as a replacement for diesel and gasoline fuels. At present, when improving the quality of bio-oils, catalytic vapor cracking is generally considered superior to other catalytic upgrading technologies, such as hydrotreating and esterification. This review summarizes the current status of research concerning both the catalytic pyrolysis of biomass and the catalytic cracking of bio-oil using the zeolite HZSM-5, focusing on the specific catalysts employed, as well as the upgrading methods and reaction mechanisms.

Key words: Biomass, Bio-oil, Upgrading, Cracking, Pyrolysis, HZSM-5