二次法（同晶取代）快速合成Sn-β沸石用于葡萄糖异构制果糖

doi:10.1016/S1872-2067(14)60071-1

催化学报 ›› 2014, Vol. 35 ›› Issue (5): 723-732.DOI: 10.1016/S1872-2067(14)60071-1

二次法（同晶取代）快速合成Sn-β沸石用于葡萄糖异构制果糖

刘民^a, 贾松岩^b, 李常增^a, 张安峰^a, 宋春山^a,c,d, 郭新闻^a

a 大连理工大学精细化工国家重点实验室, 化工学院催化化学与工程系, 辽宁大连116012;
b 中国科学院大连化学物理研究所洁净能源国家实验室(筹), 辽宁大连116023;
c 宾州州立大学能源研究所, 宾州-大连联合能源研究中心, 能源与矿物工程系, 美国宾州16802;
d 宾州州立大学化学工程系, 美国宾州16802

收稿日期:2014-02-27 修回日期:2014-03-10 出版日期:2014-04-18 发布日期:2014-04-24
通讯作者: 刘民，郭新闻
基金资助:
国家自然科学基金（20803005，21306186）.

Facile preparation of Sn-β zeolites by post-synthesis (isomorphous substitution) method for isomerization of glucose to fructose

Min Liu^a, Songyan Jia^b, Changzeng Li^a, Anfeng Zhang^a, Chunshan Song^a,c,d, Xinwen Guo^a

a State Key Laboratory of Fine Chemicals, Department of Catalysis Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, Liaoning, China;
b Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
c EMS Energy Institute, PSU-DUT Joint Center for Energy Research and Department of Energy & Mineral Engineering, Pennsylvania State University, University Park, Pennsylvania 16802, United States;
d Department of Chemical Engineering, Pennsylvania State University, University Park, Pennsylvania 16802, United States

Received:2014-02-27 Revised:2014-03-10 Online:2014-04-18 Published:2014-04-24
Supported by:
This work was supported by the National Natural Science Foundation of China (20803005, 21306186).

摘要/Abstract

摘要：

采用二次法快速合成了Sn-β沸石. 该方法包含杂原子脱除和与SnCl₄的同晶取代两个步骤，合成时间从水热法的约40 d缩短为少于1 d，且Sn含量更高. 将该沸石用于水相催化葡萄糖异构化制果糖反应，详细考察了反应温度、时间、催化剂用量、溶剂以及卤盐添加物对反应性能的影响. 在优化的反应条件下，果糖收率最高可达约43%. 催化剂可以通过焙烧再生.

关键词: Sn-β, 同晶取代, 葡萄糖, 异构化, 果糖

Abstract:

Sn-β zeolites were facilely synthesized by a post-synthesis method consisting of two steps, i.e., heteroatom removal and isomorphous substitution by reaction with SnCl₄. This significantly shortened the Sn-β zeolite preparation time from the previously reported 40 d to less than 1 d. It was shown that Sn-β samples prepared using the post-synthesis method had higher Sn contents than that prepared using a hydrothermal method. The as-synthesized Sn-β zeolites were tested in the isomerization of glucose to fructose in aqueous media. The effects of reaction temperature, reaction time, catalyst amount, solvent, and halide additive on the isomerization reaction over Sn-Al-β zeolites were studied in detail. Under the optimized conditions, the yield of fructose reached a maximum of ~43%. The catalysts can be reused without loss of activity after regeneration by calcination.

Key words: Sn-β, Isomorphous substitution, Glucose, Isomerization, Fructose

刘民, 贾松岩, 李常增, 张安峰, 宋春山, 郭新闻. 二次法（同晶取代）快速合成Sn-β沸石用于葡萄糖异构制果糖[J]. 催化学报, 2014, 35(5): 723-732.

Min Liu, Songyan Jia, Changzeng Li, Anfeng Zhang, Chunshan Song, Xinwen Guo. Facile preparation of Sn-β zeolites by post-synthesis (isomorphous substitution) method for isomerization of glucose to fructose[J]. Chinese Journal of Catalysis, 2014, 35(5): 723-732.

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二次法（同晶取代）快速合成Sn-β沸石用于葡萄糖异构制果糖

Facile preparation of Sn-β zeolites by post-synthesis (isomorphous substitution) method for isomerization of glucose to fructose

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