Catalytic Performance of Layered Double Hydroxides Co-Mn-Al for Ozonation of Organic Pollutants in Water

doi:10.1016/S1872-2067(11)60392-6

Abstract

Abstract: The catalytic activity of layered double hydroxides containing Co, Mn, and Al for the ozonation of organic pollutants in water was investigated. The Co-Mn-Al layered double hydroxides were prepared by coprecipitation. Nitrobenzene was used as a model compound, and it was shown that the degradation and mineralization of nitrobenzene was increased by the presence of Co-Mn-Al layered double hydroxides as compared to ozonation alone. Both an indirect method of adding a scavenger (tert-butanol) of the hydroxyl radical chain reaction and direct electron spin resonance using 5,5-dimethyl-1-pyrroline-N-oxide as a spin trapping agent were used to investigate the generation of hydroxyl radicals in the ozonation by the Co-Mn-Al layered double hydroxides. The inhibiting effect of tert-butanol on the degradation of nitrobenzene and the detection of the stronger 5,5-dimethyl-1-pyrroline-N-oxide/hydroxyl radical adduct showed that the Co-Mn-Al layered double hydroxides catalyzed the generation of hydroxyl radicals.

Key words: layered double hydroxide, catalytic ozonation, nitrobenzene, tert-butanol, electron spin resonance, hydroxyl radical

SUI Ming-Hao, DUAN Biao-Biao, SHENG Li, HUANG Shu-Hang, SHE Lei. Catalytic Performance of Layered Double Hydroxides Co-Mn-Al for Ozonation of Organic Pollutants in Water[J]. Chinese Journal of Catalysis, 2012, 33(8): 1284-1289.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60392-6

https://www.cjcatal.com/EN/Y2012/V33/I8/1284

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