2D materials modulating layered double hydroxides for electrocatalytic water splitting

doi:10.1016/S1872-2067(21)63987-6

Abstract

Abstract:

Exploring highly efficient electrochemical water splitting catalysts has recently attracted extensive research interest from both fundamental researches and practical applications. Transition metal-based layered double hydroxides (LDHs) have been proved to be one of the most efficient materials for oxygen evolution reaction (OER), however, still suffered from low conductivity and sluggish kinetics for hydrogen evolution reaction (HER), which largely inhibited the overall water splitting efficiency. To address this dilemma, enormous approaches including doping regulation, intercalation tuning and defect engineering are therefore rationally designed and developed. Herein, we focus on the recent exciting progress of LDHs hybridization with other two-dimensional (2D) materials for water splitting reactions, not barely for enhancing OER efficiency but also for boosting HER activity. Particularly, the structural features, morphologies, charge transfer and synergistic effects for the heterostructure/heterointerface that influence the electrocatalytic performance are discussed in details. The hybrid 2D building blocks not only serve as additional conductivity and structural supported but also promote electron transfer at the interfaces and further enhance the electrocatalytic performance. The construction and application of the nanohybrid materials will guide a new direction in developing multifunctional materials based on LDHs, which will contribute to energy conversion and storage.

Key words: Layered double hydroxide, 2D materials, Hybridization, Synergistic effect, Electrocatalytic water splitting

Jinling Cheng, Dingsheng Wang. 2D materials modulating layered double hydroxides for electrocatalytic water splitting[J]. Chinese Journal of Catalysis, 2022, 43(6): 1380-1398.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(21)63987-6

https://www.cjcatal.com/EN/Y2022/V43/I6/1380

Figures/Tables 15

Scheme 1. Hybridization of LDH with other 2D materials.

Scheme 2. Typical structure of LDHs.

Fig. 1. In situ growth of a secondary 2D material onto LDH sheets. (a) MoS2 onto NiFeCr-LDH. Reprinted with permission from Ref. [62]. Copyright 2021, Elsevier. (b) MOF nanosheets grow on NiFe-LDH by SVPT methodology. Reprinted with permission from Ref. [63]. Copyright 2019, Wiley-VCH.

Fig. 2. In situ growth of LDH on the other 2D material. (a) The synthesis process of CoMn-LDH@g-C3N4 nanohybrid and corresponding TEM pictures and XPS spectra. Reprinted with permission from Ref. [65]. Copyright 2018, Wiley VCH. (b) The synthesis process of 2D hierarchical FeNi-LDH/Ti3C2 by in-situ assembling ultrathin FeNi-LDH nanosheets on exfoliated Ti3C2 MXene nanoplates and corresponding DOS data. Reprinted with permission from Ref. [66]. Copyright 2019, Elsevier. (c) The synthesis of ZIF-67 derived NiFe-LDH on ultrathin Mxene Nanosheets and corresponding HRTEM and N2 adsorption isotherms. Reprinted with permission from Ref. [67]. Copyright 2018, the American Chemical Society.

Fig. 3. (a) Schematic illustration of synthesis of hybridization by s electrostatic-assembly of two kinds of unilamellar nanosheets with oppositely charged. (b) LDH@G. (c) MoS2@G. (d) MoS2@LDH. Reprinted with permission from Ref. [70]. Copyright 2019, American Chemical Society.

Fig. 4. (a) Schematic illustration of the synthesis processing of (Co,Ni)Se2@NiFe LDH. Reprinted with permission from Ref. [71]. Copyright 2019, American Chemical Society. (b) Schematic illustration of the synthesis procedure of NiCo-LDH/Co4S3 on the nickel foam via a two-step process. Reprinted with permission from Ref. [72]. Copyright 2021, Elsevier.

Fig. 5. The synthesis, characterization and electrochemical application for hybridization between LDH and the GO/rGO sheets. (a) A schematic diagram of the electrostatic flocculation of NiFe-LDH@GO (rGO) hybrid. (b) XRD pattern hybrid composites for NiFe-LDH hybrid GO (i) and rGO (ii). (c,d) TEM and HRTEM of alternately stacked NiFe-LDH and GO. (e-h) Electrocatalytic performance of NiFe-LDH@rGO, NiFe-LDH@GO, NiFe-LDH. (i) Home-built water-splitting cell. Reprinted with permission from Ref. [79]. Copyright 2015, the American Chemical Society.

Fig. 6. N-doped graphene framework anchored onto NiFe-LDH nanosheets (a,b) and the application for electrochemical catalysts (c). Reprinted with permission from Ref. [80]. Copyright 2015, Royal Society of Chemistry.

Fig. 7. The hybridization based on LDH@graphdiyne and their application for water splitting. (a-e). The sandwiched graphdiyne@FeCo-LDH. Reprinted with permission from Ref. [84]. Copyright 2018, Springer Nature. (f-i) Superhydrophilic graphdiyne@CoAl-LDH. Reprinted with permission from Ref. [85]. Copyright 2018, Wiley VCH.

Fig. 8. Synthetic strategy, structure characterizations and electrocatalytic activities for MoS2-LDH composite. (a-d) NiCo-LDH@MoS2. Reprinted with permission from Ref. [99]. Copyright 2017, Cell Press. (e-h) NiFe-LDH@MoS2. Reprinted with permission from Ref. [100]. Copyright 2018, American Chemical Society. (i and j) Comparison between MoS2/G, NiFe-LDH/G and MoS2/NiFe-LDH. Reprinted with permission from Ref. [70]. Copyright 2019, American Chemical Society.

Fig. 9. Structure characterizations and electrocatalytic activities for MXenes@LDH nanohybrids. (a) SEM image of integrated Ti3C2@FeNi-LDH electrode. (b,c) XPS spectra of Ni 2p and Fe 2p for Ti3C2@FeNi-LDHs. (d-f) Electrocatalytic activity and stability for Ti3C2@FeNi-LDH. (a-f) Reprinted with permission from Ref. [66]. Copyright 2018, Elsevier. (g-j) The synthesis strategy, construction and overall oxygen electrocatalysis performance for FeNi-LDH@V2C. (g-j) Reprinted with permission from Ref. [123] Copyright 2021, Elsevier.

Fig. 10. Structure and electrocatalytic activities of cMOF/LDH hybrids. (a) Schematic illustration showing construction for cMOF/LDH hybrids. (b) TEM image at the interface of cMOF/LDH-48. (c-j) Electrocatalytic performance of cMOF/LDH hybrids. (k) XRD pattern of cMOF/LDH-48 after OER testing. Reprinted with permission from Ref. [131] Copyright 2021, Wiley VCH.

Fig. 11. Structure and electrocatalytic activities of N,S-rGO/WSe2/NiFe-LDH hybrids. (a) Schematic illustration showing construction for N,S-rGO/WSe2/NiFe-LDH hybrids. (b,c) SEM image and HRTEM image for N,S-rGO/WSe2/NiFe-LDH. (d-i) Electrocatalytic performance of N,S-rGO/WSe2/NiFe-LDH hybrids. Reprinted with permission from Ref. [132]. Copyright 2017, the American Chemical Society.

Fig. 12. (a) Schematic diagram of the construction process of Sb-Graphene hybridization. Reprinted with permission from Ref. [136]. Copyright 2017, Wiley VCH. (b) The characterization and HER performance for metal free COF. Reprinted with permission from Ref. [137]. Copyright 2018, Wiley VCH.

Table 1 Summary of electrocatalytic performance of most-active hybrid LDH materials for overall water splitting.

Catalyst	Preparation methods	Performance		Ref.
Catalyst	Preparation methods	OER	HER	Ref.
NiFe-LDH/r-Go	Hydro/solvothermal	0.21V@10 mA cm^-2	unknown	[65,74]
NiFe-LDH/DG	In situ hydrothermal	0.21V@10 mA cm^-2	0.115V@20 mA cm^-2	[67]
FeCo-LDH/Graphdiyne	Electrostatic flocculation	0.216V@10 mA cm^-2	0.043V@10 mA cm^-2	[64]
NiFe-LDH/g-C₃N₄	Electrostatic self-assemble	0.288V@10 mA cm^-2	0.406V@10 mA cm^-2	[53,63,69]
NiFe-LDH/Ti₃C₂	Hydro/solvothermal	0.27V@10 mA cm^-2	unknown	[103,106]
NiFePS3-LDH/Ti₃C₂	Electrostatic self-assemble	0.282V@10 mA cm^-2	0.196V@10 mA cm^-2	[54,55]
NiFe-LDH/V₂C	In situ distorting	0.25V@10 mA cm^-2	unknown	[56]
NiCo-LDH/MoS₂	Hydro/solvothermal	unknown	0.078V@10 mA cm^-2	[82]
NiFe-LDH/MoS₂	In situ hydrothermal	0.156V@10 mA cm^-2	0.11V@10 mA cm^-2	[58,87,112]
NiFe-LDH/Co_0.85Se	Electrostatic self-assemble	1.5V@150 mA cm^-2	unknown	[66]
CoFe-LDH@NiFe-LDH	Electrodeposition	0.160V@10 mA cm^-2	0.24V@10 mA cm^-2	[115,116]

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