Low Cost Synthesis of 3D Flowerlike Co3O4 Nanostructures as Active Catalyst for CO Oxidation

doi:10.1016/S1872-2067(11)60408-7

Abstract

Abstract: 3D flowerlike Co₃O₄ nanostructures were prepared by a microwave-assisted hydrothermal method, which is a rapid, template-free, and low cost method. The product is obtained in two minutes using all inorganic precursors. The precursor concentration and gradual hydrolysis of urea determine the morphology of Co₃O₄ nanostructures. These flowerlike Co₃O₄ nanostructures have high surface area and expose largely active (110) planes, leading to relative high catalytic activity in CO oxidation.

Key words: carbon monoxide, oxidation, cobaltosic oxide, nanostructure, microwave

CAO Chang-Yan, DOU Zhi-Feng, LIU Hua, SONG Wei-Guo. Low Cost Synthesis of 3D Flowerlike Co₃O₄ Nanostructures as Active Catalyst for CO Oxidation[J]. Chinese Journal of Catalysis, 2012, 33(8): 1334-1339.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60408-7

https://www.cjcatal.com/EN/Y2012/V33/I8/1334

References

1 Hu L H, Peng Q, Li Y D. J Am Chem Soc, 2008, 130: 16136
2 Xie X W, Li Y, Liu Z Q, Haruta M, Shen W J. Nature, 2009, 458: 746
3 Xie X W, Shang P J, Liu Z Q, Lv Y G, Li Y, Shen W J. J Phys Chem C, 2010, 114: 2116
4 Xie R Y, Li D B, Hou B, Wang J A, Jia L T, Sun Y H. Catal Commun, 2010, 12: 380
5 Cao A M, Hu J S, Liang H P, Song W G, Wan L J, He X L, Gao X G, Xia S H. J Phys Chem B, 2006, 110: 15858
6 Wang X, Wu X L, Guo Y G, Zhong Y T, Cao X Q, Ma Y, Yao J N. Adv Funct Mater, 2010, 20: 1680
7 Li W Y, Xu L N, Chen J. Adv Funct Mater, 2005, 15: 851
8 Barakat M N A, Khil M S, Sheikh F A, Kim H Y. J Phys Chem C, 2008, 112: 12225
9 Wang G X, Shen X P, Horvat J, Wang B, Liu H, Wexler D, Yao J. J Phys Chem C, 2009, 113: 4357
10 Jansson J, Palmqvist A E C, Fridell E, Skoglundh M, Osterlund L, Thormahlen P, Langer V. J Catal, 2002, 211: 387
11 Yu Y, Takei T, Ohashi H, He H, Zhang X, Haruta M. J Catal, 2009, 267: 121
12 Benjaramtg M R, Katta L. Chin J Catal (催化学报), 2011, 32: 800
13 Kim M H, Kim D W, Gode T. Chin J Catal (催化学报), 2011, 32: 762
14 Qiao B, Wang A, Lin J, Li L, Su D, Zhang T. Appl Catal B, 2011, 105: 103
15 Hu L H, Sun K Q, Peng Q, Xu B Q, Li Y D. Nano Res, 2010, 3: 363
16 Tian B Z, Liu X Y, Yang H F, Xie S H, Yu C Z, Tu B , Zhao D Y. Adv Mater, 2003, 15: 1370
17 Yang L X, Zhu Y J, Li L, Zhang L, Tong H, Wang W W, Cheng G F, Zhu J F. Eur J Inorg Chem, 2006, 2006: 4787
18 Zhao Z G, Geng F X, Bai J B, Cheng H M. J Phys Chem C, 2007, 111: 3848
19 Qiao R, Zhang X L, Qiu R, Kim J C, Kang Y S. Chem Eur J, 2009, 15: 1886
20 Zheng J, Liu J, Lv D P, Kuang Q, Jiang Z Y, Xie Z X, Huang R B, Zheng L S. J Solid State Chem, 2010, 183: 600
21 Chen A, Peng X, Koczkur K, Miller B. Chem Commun, 2004: 1964
22 Zhang H, Yang D, Ji Y J, Ma X Y, Xu J, Que D L. J Phys Chem B, 2004, 108: 3955
23 Sun C W, Sun J, Xiao G L, Zhang H R, Qiu X P, Li H, Chen L Q. J Phys Chem B, 2006, 110: 13445
24 Zhong L S, Hu J S, Liang H P, Cao A M, Song W G, Wan L J. Adv Mater, 2006, 18: 2426
25 Zhong L S, Hu J S, Cao A M, Liu Q, Song W G, Wan L J. Chem Mater, 2007, 19: 1648
26 Bain S W, Ma Z, Cui Z M, Zhang L S, Niu F, Song W G. J Phys Chem C, 2008, 112: 11340
27 Cao C Y, Cui Z M, Chen C Q, Song W G, Cai W. J Phys Chem C, 2010, 114: 9865
28 Cao C Y, Guo W, Cui Z M, Song W G, Cai W. J Mater Chem, 2011, 21: 3204
29 Zeng S, Tang K, Li T, Liang Z, Wang D, Wang Y, Qi Y, Zhou W. J Phys Chem C, 2008, 112: 4836
30 Long M, Cai W M, Cai J, Zhou B X, Chai X Y, Wu Y H. J Phys Chem B, 2006, 110: 20211
31 Guttel R, Paul M, Schuth F. Chem Commun, 2010, 46: 895

[1]	Jing Shi, Yu-Hua Guo, Fei Xie, Ming-Tian Zhang, Hong-Tao Zhang. Electronic effects of redox-active ligands on ruthenium-catalyzed water oxidation [J]. Chinese Journal of Catalysis, 2023, 52(9): 271-279.
[2]	Lijuan Sun, Xiaohui Yu, Liyong Tang, Weikang Wang, Qinqin Liu. Hollow dodecahedron K₃PW₁₂O₄₀/CdS core-shell S-scheme heterojunction for photocatalytic synergistic H₂ evolution and benzyl alcohol oxidation [J]. Chinese Journal of Catalysis, 2023, 52(9): 164-175.
[3]	Sikai Wang, Xiang-Ting Min, Botao Qiao, Ning Yan, Tao Zhang. Single-atom catalysts: In search of the holy grails in catalysis [J]. Chinese Journal of Catalysis, 2023, 52(9): 1-13.
[4]	Zhipeng Guan, Dongfeng Yang, Zhao Liu, Shuxiang Zhu, Xingxing Zhong, Huamin Wang, Xiangwei Li, Xiaotian Qi, Hong Yi, Aiwen Lei. Regioselective electrochemical oxidative radical ortho-(4 + 2)/ipso-(3 + 2) cyclization [J]. Chinese Journal of Catalysis, 2023, 52(9): 144-153.
[5]	Wen Zhang, Cai-Cai Song, Jia-Wei Wang, Shu-Ting Cai, Meng-Yu Gao, You-Xiang Feng, Tong-Bu Lu. Bidirectional host-guest interactions promote selective photocatalytic CO₂ reduction coupled with alcohol oxidation in aqueous solution [J]. Chinese Journal of Catalysis, 2023, 52(9): 176-186.
[6]	Bowen Liu, Jiajie Cai, Jianjun Zhang, Haiyan Tan, Bei Cheng, Jingsan Xu. Simultaneous benzyl alcohol oxidation and H₂ generation over MOF/CdS S-scheme photocatalysts and mechanism study [J]. Chinese Journal of Catalysis, 2023, 51(8): 204-215.
[7]	Xiao-Juan Li, Ming-Yu Qi, Jing-Yu Li, Chang-Long Tan, Zi-Rong Tang, Yi-Jun Xu. Visible light-driven dehydrocoupling of thiols to disulfides and H₂ evolution over PdS-decorated ZnIn₂S₄ composites [J]. Chinese Journal of Catalysis, 2023, 51(8): 55-65.
[8]	Yinqi Wu, Qianqian Chen, Qi Chen, Qiang Geng, Qiaoyu Zhang, Yu-Cong Zheng, Chen Zhao, Yan Zhang, Jiahai Zhou, Binju Wang, Jian-He Xu, Hui-Lei Yu. Precise regulation of the substrate selectivity of Baeyer-Villiger monooxygenase to minimize overoxidation of prazole sulfoxides [J]. Chinese Journal of Catalysis, 2023, 51(8): 157-167.
[9]	Lu Cheng, Xuning Chen, P. Hu, Xiao-Ming Cao. Advantages and limitations of hydrogen peroxide for direct oxidation of methane to methanol at mono-copper active sites in Cu-exchanged zeolites [J]. Chinese Journal of Catalysis, 2023, 51(8): 135-144.
[10]	Chun Yin, Fulin Yang, Shuli Wang, Ligang Feng. Heterostructured NiSe₂/MoSe₂ electronic modulation for efficient electrocatalysis in urea assisted water splitting reaction [J]. Chinese Journal of Catalysis, 2023, 51(8): 225-236.
[11]	Lijuan Sun, Weikang Wang, Ping Lu, Qinqin Liu, Lele Wang, Hua Tang. Enhanced photocatalytic hydrogen production and simultaneous benzyl alcohol oxidation by modulating the Schottky barrier with nano high-entropy alloys [J]. Chinese Journal of Catalysis, 2023, 51(8): 90-100.
[12]	Haifeng Liu, Xiang Huang, Jiazang Chen. Surface electronic state modulation promotes photoinduced aggregation and oxidation of trace CO for lossless purification of H₂ stream [J]. Chinese Journal of Catalysis, 2023, 51(8): 49-54.
[13]	Bo Zhou, Jianqiao Shi, Yimin Jiang, Lei Xiao, Yuxuan Lu, Fan Dong, Chen Chen, Tehua Wang, Shuangyin Wang, Yuqin Zou. Enhanced dehydrogenation kinetics for ascorbic acid electrooxidation with ultra-low cell voltage and large current density [J]. Chinese Journal of Catalysis, 2023, 50(7): 372-380.
[14]	Guoqing An, Xiaowei Zhang, Canyang Zhang, Hongyi Gao, Siqi Liu, Geng Qin, Hui Qi, Jitti Kasemchainan, Jianwei Zhang, Ge Wang. Metal-organic-framework-based materials as green catalysts for alcohol oxidation [J]. Chinese Journal of Catalysis, 2023, 50(7): 126-174.
[15]	Mengistu Tulu Gonfa, Sheng Shen, Lang Chen, Biao Hu, Wei Zhou, Zhang-Jun Bai, Chak-Tong Au, Shuang-Feng Yin. Research progress on the heterogeneous photocatalytic selective oxidation of benzene to phenol [J]. Chinese Journal of Catalysis, 2023, 49(6): 16-41.

Low Cost Synthesis of 3D Flowerlike Co₃O₄ Nanostructures as Active Catalyst for CO Oxidation

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics